Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution

• Autorzy: Stoch A. , Maurin J. , Stoch P. , Kulawik J. , Szwagierczak D.

Identyfikatory

DOI

10.1515/nuka-2017-0027

• Konferencja: All-Polish Seminar on Mössbauer Spectroscopy OSSM 2016 (11th ; 19-22 June 2016 ; Radom-Turno, Poland)
• Języki publikacji: EN

Abstrakty

EN

Multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution is a material that exhibits ferroelectric and antiferromagnetic orderings in ambient temperature. The solid solution was obtained as a result of a conventional reaction in a solid state. The obtained material is a dense, fine-grained sinter whose surface was observed by scanning electron microscopy (SEM) and stoichiometry was confirmed by energy dispersive X-ray spectroscopic (EDS) analysis. According to the X-ray powder diffraction (XRD) measurements, the main phase is R3c space group with admixture of Pm-3m regular phase. Small contribution of pyrochlore-like phase was also observed. Mössbauer spectroscopy suggested random distribution of Fe3+/Ta5+ cations in the B sites of ABO3 compound. Reduction of the magnetic hyperfine field with an increase in the substitution of Ta5+ in Fe3+ neighbourhood was also observed.

Słowa kluczowe

EN

BiFeO3; crystal structure; hyperfine interactions; multiferroics; solid solution

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2017
• Tom: Vol. 62, No. 2
• Strony: 177--181
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Stoch A.

• Institute of Electron Technology Krakow Division, 39 Zabłocie Str., 30-701 Kraków, Poland, Tel.: [phone] ext. 265, Fax: [phone]

autor

Maurin J.

• National Centre for Nuclear Research, 7 Sołtana Str., 05-400 Otwock/Świerk, Poland and National Medicines Institute, 30/34 Chełmska Str., 00-725 Warsaw, Poland

autor

Stoch P.

• Faculty of Materials Science and Ceramics, AGH University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland

autor

Kulawik J.

• Institute of Electron Technology Krakow Division, 39 Zabłocie Str., 30-701 Kraków, Poland, Tel.: [phone] ext. 265, Fax: [phone]

autor

Szwagierczak D.

• Institute of Electron Technology Krakow Division, 39 Zabłocie Str., 30-701 Kraków, Poland, Tel.: [phone] ext. 265, Fax: [phone]

Bibliografia

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Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).