New Method for the Antibacterial and Antifungal Modification of Silver Finished Textiles

• Autorzy: Filipowska B. , Rybicki E. , Walawska A. , Matyjas-Zgondek E.

Warianty tytułu

PL

Nowa metoda antybakteryjnej i antygrzybicznej modyfikacji wyrobów włókienniczych za pomocą srebra

• Języki publikacji: EN

Abstrakty

EN

In order to give antimicrobial properties to textiles, silver is more and more often used because of its wide spectrum of activity. Silver can be incorporated into textiles with the use of different methods: in the production process of chemical fibres or in the final product through its chemical modification. In this paper, a new method based on the precipitation of metallic silver on a textile surface as a result of the photochemical reaction of deposited compounds is shown. The results obtained for modified textiles using scanning electron microscopy (SEM), UV-Vis spectroscopy and Laser Induced Breakdown Spectroscopy (LIBS) confirmed the presence of metallic silver on the textile surface. The size of metallic silver particles precipitated on the product surface modified was determined using Dynamic Light Scattering (DLS). The results of microbiological tests (diffusion agar test) confirmed the effectiveness of the method elaborated with respect to microbiological resistance against a wide spectrum of bacteria and fungi. The simplicity of the method elaborated and the possibility of its application in textile plants equipped with a standard finishing device are emphasised.

PL

W celu nadania wyrobom włókienniczym właściwości antybakteryjnych i antygrzybicznych coraz częściej stosowane jest srebro ze względu na szerokie spektrum jego działania. Srebro może być wprowadzane do roztworu przędzalniczego w trakcie wytwarzania włókien chemicznych lub do produktu finalnego poprzez jego chemiczną modyfikację. Przedstawiono nową metodę polegającą na wytrącaniu metalicznego srebra na/w wyrobie włókienniczym w wyniku fotochemicznej reakcji naniesionych związków chemicznych. Obecność metalicznego srebra na powierzchni zmodyfikowanych wyrobów włókienniczych potwierdziły wyniki badań uzyskane za pomocą mikroskopii skaningowej (SEM), spektroskopii UV-Vis oraz spektroskopii emisyjnej wzbudzanej laserem (LIBS). Wielkości cząstek metalicznego srebra wytrąconego na/w zmodyfikowanym produkcie zostały określone metodą dynamicznego rozpraszania światła (DLS). Wyniki badań mikrobiologicznych (test dyfuzyjny na agarze) potwierdziły skuteczność opracowanej metody w zakresie odporności mikrobiologicznej na szerokie spektrum bakterii i grzybów. Podkreślono prostotę opracowanej metody oraz możliwość jej zastosowania z wykorzystaniem istniejącego w zakładach włókienniczych parku maszynowego.

Słowa kluczowe

EN

antibacterial finishing; antifungal finishing; silver; textiles; silver-finished textiles

PL

modyfikacja wyrobów włókienniczych; antybakteryjna powłoka; powłoka antygrzybiczna; wykończenie antybakteryjne; przeciwgrzybicze wykończenie; srebro; tkaniny; tkaniny wykańczone srebrem

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2011
• Tom: Vol. 19, no. 4 (87)
• Strony: 124--128
• Opis fizyczny: Bibliogr. 36 poz., rys., tab., wykr.

Twórcy

autor

Filipowska B.

• Poland, Łódź, Textile Research Institute

autor

Rybicki E.

• Poland, Łódź, Technical University of Lodz, Institute of Architecture of Textile

autor

Walawska A.

• Poland, Łódź, Textile Research Institute

autor

Matyjas-Zgondek E.

• Poland, Łódź, Technical University of Lodz, Institute of Architecture of Textile

Bibliografia

• 1. Borkow G., Gabby J.; Biocidal textiles can help fight nosocomial infection; Medical Hypotheses Vol. 70 (2008) pp. 990-994.
• 2. Malnick S., Bardenstein R., Huszar M., Gabby J., Borkow G.; Pyjamas and sheets as a potential source of nosocomial pathogens; Journal of Hospital Infections Vol. 70 (2008) pp. 89-92.
• 3. Schindler W. D., Hauser P. J.; Chemical finishing of textiles; Woodhead Publishing Limited, 2004 England.
• 4. Horrock A. R., Anand S. C.; Handbook of Technical Textiles; Woodhead Publishing Limited, 2000 England.
• 5. Allmyr M., Adolfsson-Erici M., McLachlan M. S., Sandborgh-Englund G.; Triclosan in plasma and milk from Swedish nursing mothers and their exposure via personal care products; Science of the Total Envirnoment Vol. 372 (2008) pp. 87-93.
• 6. Takai K, Ohtsuka T, Senda Y, Nakao M, Yamamoto K, Matsuoka J, Hirai Y.; Antibacterial properties of antimicrobial-finished textile products; Microbiol Immunol. Vol. 46 (2002) pp. 75-81.
• 7. Dastjerdi R., Montazer M.; A review on the application of inorganic nano-structured materials in the modification of textiles: Focus on anti-microbial properties; Colloids ans Surfaces B: Biointerfaces Vol. 79 (2010) pp. 5-18.
• 8. Bugała-Płoskońska G., Leszkiewicz A.; Biological activity of silver and its application in medicine; Universe - Problems of Life Sciences Vol. 56 (2007) pp. 274-275 (in Polish).
• 9. Rai M., Yadav A.,Gade A.; Silver nanoparticles as a new generation of antimicrobials; Biotechnology Advances. Vol. 27 (2009) pp. 76-83.
• 10. Bragg P.D., Rainnie D.J.: The effect of silver ions on the respiratory chain of Escherichia coli. Can. J. Microbiol., Vol. 20 (1974) p. 883.
• 11. Lee H. J., Yeo S. Y., Jeong S. H.; Antibacterial effect of nanosized silver colloidal solution on textiles fabric; Journal of Material Science Vol. 38 (2003) pp. 2199-2204.
• 12. Zhang F., Wu X., Chen Y., Lin H.; Application of Silver Nanoparticles to Cotton Fabric as an Antibacterial Textile Finish; Fibres and Polymers Vol. 10 (2009) pp. 496-501.
• 13. Matyjas-Zgondek E., Bacciarelli A., Rybicki E., Szynkowska M. I., Kołodziejczyk M.; Antibacterial Properties of Silver- Finished Textiles; Fibres & Textiles in Eastern Europe Vol. 16 No. 5(70), 2008, pp. 101-107.
• 14. Pollini M., Russo M., Licciulli A., Sannino A., Maffezzoli, Characterization of antibacterial silver coated yarns, J Mater Sci: Mater Med Vol. 20 (2009)pp. 2361-2366.
• 15. Agarwal S., Wendroff J. H., Greiner A., Use of electrospinning technique for biomedical applications, Polymer Vol. 49 (2008) pp. 5603-5621.
• 16. Morent R., Geyter N. De, Verschuren J., Clerck K. De, Kiekens P., Leys C., Non-thermal plasma treatment of textiles, Surface & Coatings Technology Vol. 202 (2008) pp. 3427-3449.
• 17. Matsumura Y., Yoshikata K., Kunisaki S-i, Tsuchido T., Mode of Bactericidal Action of Silver Zeolite and Its Comparison with That of Silver Nitrate, Applied and Environmental Microbiology, Vol. 69 (2003), pp. 4278-4281.
• 18. Sondi I., Salopek-Sondi B., Silver nanoparticles as antimicrobial agent: a case study on E. coli as a model for Gramnegative bacteria, Journal of Colloid and Interface Science Vol. 275 (2004) pp. 177-182.
• 19. Zhang W., Qiao X., Chen J.; Synthesis of silver nanoparticles – Effects of concentrated parameters in water/oil microemulsion; Materials Science and Engineering Vol. B 142 (2007) pp. 1-15.
• 20. Suber L., Sondi I., Matijevic E., Gois D.V.; Preparation and the mechanisms of formation of silver particles of different morphologies in homogeneous solutions; Journal of Colloid Interface Science Vol. 288 (2005) pp. 489-495.
• 21. Nersisyan H. H., Lee J. H., Son H. T., Won C. W., Maeng D. Y.; A new and effective chemical reduction method for preparation of nanosized silver powder and colloid dispersion; Material Research Bulletin Vol. 38 (2003) pp. 949-956.
• 22. Wang H., Qiao X., Chen J., Ding S.; Preparation of silver nanoparticles by chemical reduction method; Colloids an Surfaces A: Physicocehm. Eng. Aspects Vol. 256 (2005) pp. 111-115.
• 23. Chuh-Yean C., Chen-Li C.; Preparation of cotton fibres with antibacterial silver nanoparticles; Material Letters Vol. 62 (2008) pp. 3607-3609.
• 24. Wang H., Wang J., Hong J., Wei Q,. Gao W., Zhu Z.; Preparation and characterization of silver nanocomposite textile; J. Coat. Technol. Res. Vol. 4 (2007) pp. 101-106.
• 25. Ravindra S., Murali Mohan Y., Naryana Reddy N., Mohana Raju K.; Fabrication of antibacterial Otton fibr es loaded with silver nanoparticles via „Green Approach”; Colloids and Surfaces A: Physicochemical and Engineering Aspects Vol. 367 (2010) pp. 31-40.
• 26. El-Rafie M. H., Mohamed A. A., Shaheen Th. I., Hebeish A.; Antimicrobial effect of silver nanoparticles produced by fungal process on cotton textiles; Carbohydrate Polymers Vol. 80 (2010) pp. 779-782.
• 27. Potiyaraj P., Kumlangdudsana P., Dubas S.T.; Synthesis of silver chloride nanocrystal on silk fibres; Materials Letters Vol. 61 (2007) pp. 2464-2466.
• 28. Rybicki E., Grad J., Filipowska B., Walawska A.; Functional finishing of textiles by means of silver compounds. Work of Institute of Textile Architecture, IAT-S4 (2004).
• 29. Non- published study (in Polish). 30. Filipowska B., Walawska A., Ziuko G., Wilk E.; Receiving of metallic silver on the surface of cotton textile fabrics by means of finishing methods. Work of Institute of Textile Architecture, IAT-S4, (2006). Nonpublished study (in Polish).
• 31. Filipowska B., Rymarz T., Ziuko G., Machnikowska – Kiereś E.; Elaboration of modern finishing of plane textiles assigned to biostabilising internal footwear elements. Work of Textile Research Institute, BC 01 58( 2007) Non-published study (in Polish).
• 32. Rybicki E., Filipowska B., Walawska A., Kozicki M., Matyjas-Zgondek E.; Method of antibacterial and antifungal finishing of textile fabrics. Polish Patent Application. P 384484, (2008).
• 33. Jańczyk R., Kossowski Z., Lachowski J., Bem W.; Laboratory radiator UV HF4. Specification sheet. Research and Development Centre of Textile Machinery POLMATEX-CENARO (2007) (in Polish).
• 34. EN ISO 105 – JO3:2000 standard. Calculation of colour differences.
• 35. PSS NICOMP materials: Nicomp 380 User Manual PSS-38.
• 36. Skrzeczanowski W., Filipowska B.; Utilization of laser induced breakdown spectroscopy in studies of the surface of textile products containing silver. XXII International Science and Technology Conference : Ecological and Energy-Efficient Building. Ecomilitaris 2008. Zakopane, Poland (2008) (in Polish).