Synthesis of a polyester plasticizer from rubber seed oil for polyvinyl chloride

• Autorzy: Li Huabei , Wang Xiaolin , Chu Hongying , Yao Xinding

Identyfikatory

DOI

10.2478/pjct-2022-0023

• Języki publikacji: EN

Abstrakty

EN

A polyester plasticizer (RSOP) for polyvinyl chloride based on rubber seed oil (RSO) was synthesized. Firstly, RSO monoglyceride were synthesized by the transesterifi cation of RSO with glycerol at 220–240 °C. Secondly, RSOP was synthesized from RSO monoglyceride and adipic acid by esterification. The polyester plasticizer was characterized by GPC, FT-IR, ¹H NMR and DSC. Plasticized polyvinyl chloride (PVC) materials with RSOP and dioctyl phthalate (DOP) in varying ratios were prepared via thermal melting process, RSOP was used as a second plasticizer. The properties of the plasticized PVC materials were characterized by a universal testing machine, TGA, DMA and solvent extraction resistance. The obtained PVC materials showed improved thermal stability and lower glass transition temperature than PVC. Solvent extraction resistance and plasticization of plasticized PVC were also improved. This study provides a new strategy for preparing bio-based polyester plasticizer from RSO.

Słowa kluczowe

EN

rubber seed oil; polyester; polyvinyl chloride; plasticizer; leaching test

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2022
• Tom: Vol. 24, nr 4
• Strony: 1--6
• Opis fizyczny: Bibliogr. 29 poz., rys., tab., wz.

Twórcy

autor

Li Huabei

• Yellow River Conservancy Technical Institute, Kaifeng 475004, China
• Henan Engineering Technology Research Center of Green Coating Materials, Kaifeng 475004, China

autor

Wang Xiaolin

• Henan Technical Institute, Kaifeng 475000, China

autor

Chu Hongying

• Yellow River Conservancy Technical Institute, Kaifeng 475004, China
• Henan Engineering Technology Research Center of Green Coating Materials, Kaifeng 475004, China

autor

Yao Xinding

• Yellow River Conservancy Technical Institute, Kaifeng 475004, China
• Henan Engineering Technology Research Center of Green Coating Materials, Kaifeng 475004, China

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).