Hydrogen Dilatation of V-Based Composite Membranes

• Autorzy: Panichkin Alexander , Mamaeva Axaule , Kenzhegulov Aidar , Karboz Zhanar

Identyfikatory

DOI

10.24425/amm.2022.137816

• Języki publikacji: EN

Abstrakty

EN

One of the problems limiting the use of vanadium as hydrogen permeable membranes is its high dilatation upon hydrogen dissolution in it. The information available for the dilatation coefficient value (Δυ/Ω) is contradictory, experimental information on the hydrogen solubility in vanadium within 100-1000 kPa at from 250 to 700°С is very limited. It does not enable to calculate the membrane dilatation. The article contains the measuring results for dilatation of strips made of vanadium foil 100 μm thick in a hydrogen atmosphere in the pressure range from 75 to 1000 kPa, temperatures from 250 to 700°С. The dilatation coefficient (Δυ/Ω) of polycrystalline vanadium was calculated based on the data obtained for dilatation and data previously published for the hydrogen concentration in the α-solid solution at 400°С. It is 0.165. Isobars for the temperature dependence of the hydrogen concentration in vanadium are calculated and constructed using the dilatation measuring results and the dilatation coefficient values. These data are agreed with theoretical and experimental data published previously. The limiting change in concentration and linear dimensions over the cross section of a hydrogen-permeable membrane from V was estimated at various temperatures and operating pressures at the membrane outlet based on the isobars plotted for temperature dependences of the CH/V. The conclusions are made on the optimal working conditions of Pd/V/Pd membranes when hydrogen is released from hydrogen-containing gas mixtures in accordance with Fick’s 1st law and data published previously for hydrogen concentration value at which solid hydrogen solutions in vanadium become brittle.

Słowa kluczowe

EN

hydrogen dilatation; vanadium; composite hydrogen permeable membrane; concentration gradient; deformation

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2022
• Tom: Vol. 67, iss. 2
• Strony: 767--772
• Opis fizyczny: Bibliogr. 37 poz., rys., tab., wzory

Twórcy

autor

Panichkin Alexander

• Satbayev University; Engineer of Laboratory Metallurgical Sciences, Institute of Metallurgy and Ore Beneficiation, 050010, Almaty City, Shevchenko str., 29/133, The Republic of Kazakhstan

• https://orcid.org/0000-0002-2403-8949

autor

Mamaeva Axaule

• Satbayev University; Engineer of Laboratory Metallurgical Sciences, Institute of Metallurgy and Ore Beneficiation, 050010, Almaty City, Shevchenko str., 29/133, The Republic of Kazakhstan

• https://orcid.org/0000-0002-9659-8152

autor

Kenzhegulov Aidar

• Satbayev University; Engineer of Laboratory Metallurgical Sciences, Institute of Metallurgy and Ore Beneficiation, 050010, Almaty City, Shevchenko str., 29/133, The Republic of Kazakhstan

• https://orcid.org/0000-0001-7001-2654

autor

Karboz Zhanar

• Satbayev University; Engineer of Laboratory Metallurgical Sciences, Institute of Metallurgy and Ore Beneficiation, 050010, Almaty City, Shevchenko str., 29/133, The Republic of Kazakhstan

• https://orcid.org/0000-0003-2538-8585

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).