Zastosowanie kubicznych równań stanu w inżynierii procesów gazowniczych

Ciesielczyk, E.

Artykuł - szczegóły

Tytuł artykułu

Zastosowanie kubicznych równań stanu w inżynierii procesów gazowniczych

Autorzy

Ciesielczyk E.

Identyfikatory

Warianty tytułu

Application of cubic equations of state to natural gas process engineering

Języki publikacji

Abstrakty

Kubiczne równania stanu są najczęściej stosowanymi równaniami do wyznaczania stanów równowagi fazowej, ustalającej się w gazie ziemnym. W niniejszym studium przedstawiono: analizę kubicznych równań stanu pod kątem możliwości ich wykorzystania do opracowania modeli termodynamicznych opisujących właściwości składników niepolarnych i polarnych, które wchodzą w skład gazu ziemnego, ■ ocenę kubicznych równań stanu i wybór równania pozwalającego wyznaczyć z zadawalającą dokładnością właściwości czystych składników (prężność pary nasyconej oraz objętość właściwą cieczy i gazu) oraz równowagę fazową ciecz-para ustalającą się w gazie ziemnym, ■ ocenę możliwości wykorzystania kubicznych równań stanu w przemyśle gazowniczym do analizy stanów równowagi fazowej ciecz-para, ustalającej się w wyniku kondensacji węglowodorów ciężkich zawartych w gazie ziemnym, na podstawie wyników obliczeń wykonanych przy wykorzystaniu opracowanych modeli termodynamicznych (programów komputerowych przeznaczonych do wyznaczania temperatury i ciśnienia punktów kondensacji węglowodorów w gazie ziemnym), ■ analizę najważniejszych parametrów termodynamicznych istotnych z punktu widzenia określenia stanu równowagi fazowej ustalającej się w gazie ziemnym (krytyczną temperaturę kondensacji i krytyczne ciśnienie kondensacji), analizę rozpuszczalności węglowodorów ciężkich w metanie i wpływu zawartości węglowodorów ciężkich w gazie ziemnym na krytyczną temperaturę kondensacji gazu i na temperaturę kondensacji węglowodorów wchodzących w skład gazu ziemnego oraz analizę zjawiska zwanego kondensacją wsteczną ■ metody wyznaczania punktu rosy wody, oparte na równaniach korelacyjnych i równaniu stanu Penga-Robinsona, analizę możliwości wykorzystania opracowanego modelu termodynamicznego, opartego na równaniu stanu Penga-Robinsona (programu komputerowego umożliwiającego wyznaczanie temperatury lub ciśnienia punktów rosy wody zawartej w gazie ziemnym).

Cubic equations of state are the most widely used for the prediction of phase equilibrium in natural gas. It is the aim of this study to present: ■ an analysis of cubic equations of state from the point of view of the possibility of using them for developing the thermodynamic model suitable for predicting the properties of polar and nonpolar compounds, contained in natural gas, ■ evaluating of cubic equations of state and selecting an equation of state, which will be accurate for the prediction pure components properties in saturated region (saturated vapour pressure and liquid and gas volume) as well as vapour/liquid equilibrium behaviour of natural gas, ■ an analysis of the possibility of using the cubic equation of state in the gas industry for evaluating the condensation behaviour of natural gas on the base of the results of computations done by using the developed thermodynamic models (computer programmes for predicting the hydrocarbon dew point temperature and pressure of natural gas), ■ an analysis of the main thermodynamic parameters important from the point of view of the phase behaviour of natural gas (critical condensation pressure - cricodenbar point and critical condensation temperature - cricodentherm point), analysis of solubility of hydrocarbons in methane, the dependence of the hydrocarbon dew point temperature and cricodentherm point on the concentration of hydrocarbon with high molecular weight and an analysis of the phenomenon called retrograde condensation, ■ methods for the prediction of water dew point temperature and pressure, ■ Analysis of the predictive capabilities of the developed thermodynamic models based on PengRobinson EOS (computer programmes for the calculating the water dew point of natural gas).

Słowa kluczowe

procesy gazownicze równania stanu inżynieria

cubic equations natural gas engineering

Wydawca

Instytut Nafty i Gazu - Państwowy Instytut Badawczy

Czasopismo

Prace Instytutu Górnictwa Naftowego i Gazownictwa

Rocznik

2001

Tom

nr 112

Strony

1--126

Opis fizyczny

Bibliogr. 133 poz., tab., wykr.

Twórcy

autor

Ciesielczyk E.

Bibliografia

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