PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Phase transitions in the borate minerals from the Kłodawa Salt Dome (Central Poland) as the indicators of the temperature processes in salt diapirs

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The diapiric structures of the Polish Lowlands are tectonically deeply seated down to the autochthonous Zechstein strata at a depth of ca. 6 km. In the process of deep burial and halokinetic diapirism, the salt rocks were subjected to diagenetic and metamorphic transformations, with the temperature being an essential factor. Considering the thermal gradient, a temperature of up to ca. 200°C can be achieved in the salt dome within a depth range from several hundred metres to 6 km, which may lead to transformations of the majority of salt minerals. Phase transitions of two borate minerals – boracite and congolite from the Kłodawa salt dome – provide evidence for higher temperatures in the salt dome rocks. The authigenic euhedral crystals of those borate minerals display their external habitus in ambient temperature in the form of regular symmetry (F43c – pseudo-regular polyhedrons), whereas their internal structure is lower: orthorhombic (Pca21) for boracite and rhombohedral (R3C) for congolite. The heating and cooling of boracite and congolite crystals show reversible phase transition. At a temperature of ca. 270°C, boracite crystals change their symmetry: orthorhombic ↔ cubic. In the case of congolite three reversible phase transitions within a temperature range of 50–339°C can be observed: rhombohedral ↔ monoclinic ↔ orthorhombic ↔ cubic symmetry. Those phase transitions, confirmed experimentally in our study, clearly document at least local occurrences of temperatures exceeding 339°C in the Kłodawa salt dome.
Rocznik
Strony
543--554
Opis fizyczny
Bibliogr. 36 poz., rys., wykr.
Twórcy
autor
autor
  • AGH Univer sity of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Al. A. Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
  • 1. Borchert, H., Muir, R.O., 1964. Salt Deposits. The Origin, Metamorphism and Deformation of Evaporites. D. Van Nostrand Company, LTD. London.
  • 2. Braitsch, O., 1971. Salt Deposits Their Origin and Composition. Springer Verlag, NewYork.
  • 3. Braitsch, O., Gunzert, G., Wimmenauer, W., Thiel, R., 1964. Über ein Datolithvorkommen am Basaltkontakt im Kaliwerk Buggingen (Südbaden). Beiträge zur Mineralogie und Petrographie, 10: 111-124.
  • 4. Burliga, S., 2011. The oldest stratigraphic units in the Kłodawa salt dome. In: Storage and disposal in salt workings - present day and future of salt mining. XVI International Salt Symposium “Quo Vadis Sal”, Toruń, Poland: 11-12 (abstract).
  • 5. Burliga, S., Kolonko, P., Misiek, G., Czapowski, G., 1995. Kłodawa salt mine. In: Upper Rotliegend - Zechstein: terrestrial - marine sedimentary succession in Polish Permian Basin (ed. J. Małecka): 45-54. XIII International Congress on Carboniferous-Permian, August 28 - September 2, 1995, Guide to Excursion A3, Kraków, Poland.
  • 6. Burns, P.C., Carpenter, M.A., 1996. Phase transitions in the series boracite-trembathite-congolite: phase relations. Canadian Mineralogist, 34: 881-892.
  • 7. Burns, P.C., Carpenter, M.A., 1997. Phase transitions in the series boracite-trembathite-congolite: an infrared spectroscopic study. Canadian Mineralogist, 35: 189-202.
  • 8. Charysz, W., 1973. Zechstein stage of Younger Salts (Z3) in Kujawy region) (in Polish with English summary). Prace Geologiczne, 75.
  • 9. Dadlez, R., 1997. Epicontinental basins in Poland: Devonian to Cretaceous - relationship between the crystalline basement and sedimentary infill. Geological Quarterly, 41 (4): 419-432.
  • 10. Dadlez, R., Narkiewicz, M., Stephenson, R.A., Visser, M.T.M., Wees, J-D. van, 1995. Tectonic evo l u ti on of the Mid-Polish Trough: modelling implications and significance for central European geology. Tectonophysics, 252: 179-195.
  • 11. Dadlez, R., Marek, S., Pokorski, J., eds., 1998. Palaeogeographic Atlas of epicontinental Permi an and Mesozoic in Poland (1:2 500 000) (in Polish). Państwowy Instytut Geologiczny, Warszawa.
  • 12. Dowty, E., Clark, J.R., 1973. Crystal-structure refinements for orthorhombic boracite, Mg3ClB7O13, and a trigonal, iron-rich analogue. Zeitschrift für Kristallographie, 138: 64-99.
  • 13. Fijał, J., 1970. On the occurrence of ascharite in the Kłodawa salt dome. Mineralogia Polonica, 1: 29-35.
  • 14. Fijał, J., 1973. Accessory minerals of the Kujawy salt deposíts (in Polish with English summary). Prace Mineralogiczne, 33: 1-56.
  • 15. Garlicki, A., Szybist, A., 1986. Saline deposits of Polish Zechstein with potash salt (in Polish with English summary). Gospodarka Surowcami Mineralnymi, 2: 391-404.
  • 16. Grishina, S., Dubessy, J., Kontorovich, A., Pironon, J., 1992. Inclusions in salt beds resulti ng from thermal metamorphism by dolerite sills (eastern Siberia, Russia). European Journal of Mineralogy, 4: 1187-1202.
  • 17. Grube, G., Bräuning, W., 1938. Über die Entwässerung von Magnesium chloridhexahydrat und Carnallit. Elektrochemie, 44: 134-143.
  • 18. Hanczke, T., 1969. Mineralogy and petrography of the Zechstein salt in Kłodawa mine (in Polish with English summary). Prace Muzeum Ziemi, 16: 3-52.
  • 19. Ito, T., Morimoto, N., Sadanaga, R., 1951. The crystal structure of boracite. Acta Crystallographica, 4: 310-316.
  • 20. Kern, H., Franke, J.H., 1986. Carnallit - Thermisches und thermochemisches Verhalten in Endlagersalzstöcken. Zeitschrift der Deutschen Geologischen Gesellschaft., 137: 1-27.
  • 21. Knipping, B., 1989. Basalt Intrusions in Evaporites. Lecture Notes in Earth Sciences, 24. Springer, Berlin-Heidelberg-New York-Tokyo.
  • 22. Krzywiec, P., 2004. Triassic evolution of the Kłodawa salt structure: basement-controlled salt tectonics within the Mid-Polish Trough (Central Poland). Geological Quarterly, 48 (2): 123-134.
  • 23. Krzywiec, P., 2006. Structural inversion of the Pomeranian and Kuiavian segments of the Mid-Polish Trough - lateral variations in timing and structural style. Geological Quarterly, 50 (1): 151-168.
  • 24. Łaszkiewicz, A., Langier-Kuźniarowa, A., 1966. The application of the thermal analysis to the investigation of salt rocks (in Polish with English summary). Archiwum Mineralogiczne, 26: 131-160.
  • 25. Schmid, H., Tippmann, H., 1978. Spontaneous birefringence in boracites - measurements and applications. Ferroelectrics, 20: 21-36.
  • 26. Stańczyk-Stasik, I., 1976. Les dépots ěpigénétiques dans les mines de sel de la région de Kujawy (in Polish with French summary). Prace Geologiczne, 90: 1-64.
  • 27. Sueno, S., Clark, J.R., Papike, J.J., Konnert, J.A., 1973. Crystal-structure refinement of cubic boracite. American Mineralogist, 58: 691-697.
  • 28. Tarka, R., 1992. Tectoni cs of some salt depos í ts in Poland based on mesostructural analyses (in Polish with English summary). Prace Państwowego Instytutu Geologicznego, 137: 1-47.
  • 29. Toboła, T., Natkaniec-Nowak, L., ed., 2008. Sole niebieskie w wysadzie kłodawskim (in Polish). Uczelniane Wyd. Nauk.-Dydaktyczne AGH: 1-136.
  • 30. Trusheim, F., 1960. Mechanism of salt migration in northern Germany. AAPG Bulletin, 44: 1519-1540.
  • 31. Wachowiak, J., 1998. Studium mineralogiczne skał chemicznych i silikoklastycznych wysadu solnego Kłodawa (in Polish). Ph.D. thesis. Arch. AGH, Kraków.
  • 32. Wachowiak, J., 2010. Mineral levels in Upper Permi an (Zechstein) salts of the Kłodawa salt diaper as a tool for lithostratigraphic correlation (in Polish with English summary). Geologia, 36: 367-393.
  • 33. Wachowiak, J., Pieczka, A., 2012. Congolite and trembathite from the Kłodawa Salt Mine, Central Poland: records of the thermal history of the parental salt dome. Canadian Mineralogist, 50: 1387-1399.
  • 34. Werner, Z., Poborski, J., Orska, J., Bąkowski, J., 1960. A geological and mining outilne of the Kłodawa salt deposit (in Polish with English summary). Prace Instytutu Geologicznego, 30:467-512.
  • 35. Yarzhemskiy, J.J., 1984. Boronosnyye galogiennyye porody (in Russian). Izdatielstwo „Nauka“ Akademia Nauk SSSR, Novosibirsk: 1-80.
  • 36. Znosko, J., 1957. Uplift of the Kłodawa salt dome during the Jurassic, and its influence upon the formation of the lumachel rocks (in Polish with English summary). Geological Quarterly, 1 (1): 90-103.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2ff20e41-6de3-4700-ba5e-b3829c17d176
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.