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Purpose: The main aim of this work is to present our investigation in the field of photoalignment. In this work we introduce useful photoalignment techniques and discuss in detail the results of photocrosslinking and photodegradation in photosensitive polymer materials. Design/methodology/approach: We describe the new procedure investigated in our laboratory for the following materials: HD-4100, HD-4110 and HD-8820 (DuPont Microsystems) as well as the characteristics obtained for the thin polyimide layers: optical homogeneity, thickness, surface tension. Findings: Polyimide layers obtained on the glass/ITO substrates which were irradiated using linearly polarised ultraviolet light show the aligning properties for liquid crystal layers. The proposed new technology is fairly fine to obtain 2-3 cm2 layers. Research limitations/implications: The liquid crystal material alignment quality is not perfect, but the works are still in progress. In the next step we will try to use silan-derivative adhesion promoters to lower the aligning layers thickness. This solution will probably also have a big influence on the aligning layers homogeneity. Practical implications: We discuss an alternative technique of the rubbing method for composition of liquid crystal displays. Liquid crystal displays are widely used for many industrial and commercial applications. Multimedia and graphics and medical-imaging systems require top quality images. Such an image can be obtained under the condition of good liquid crystal alignment. Rubbing is a method conventionally used for these purposes. Unfortunately this technique has some disadvantages that are particularly visible in new generation displays. The usage of photodephiniable materials opens the route to obtain an appropriate molecular tilt and controlled anchoring energy as well as preparing layers that are suitable to providing diversified optical axes in one liquid crystal cell. Originality/value: Agents investigated in the paper hasn’t been used as the alignment materials in liquid crystal cells preparation so far. The used technology as well as HD-4100, HD-8820 and HD-4110 materials are suitable as the alternative substances for common used aligning chemical substances and technologies.
Słowa kluczowe
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Tom
Strony
7--13
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
- Laboratory of Crystal Physics and Technology, Institute of Applied Physics, Military University of Technology, ul. Sylwestra Kaliskiego 2, 00-908 Warszawa, Poland
autor
- Laboratory of Crystal Physics and Technology, Institute of Applied Physics, Military University of Technology, ul. Sylwestra Kaliskiego 2, 00-908 Warszawa, Poland
autor
- Laboratory of Crystal Physics and Technology, Institute of Applied Physics, Military University of Technology, ul. Sylwestra Kaliskiego 2, 00-908 Warszawa, Poland
autor
- Laboratory of Crystal Physics and Technology, Institute of Applied Physics, Military University of Technology, ul. Sylwestra Kaliskiego 2, 00-908 Warszawa, Poland
- Laboratory of Crystal Physics and Technology, Institute of Applied Physics, Military University of Technology, ul. Sylwestra Kaliskiego 2, 00-908 Warszawa, Poland
Bibliografia
- [1] M.T. Bogert, R.R. Renshaw, 4-amino-0-phthalic acid and some of its derivatives, Journal of the American Chemical Society 30 (1908) 1135-1144.
- [2] V. Šindelář, R. Hobzová, P. Sysel, Modifikované polyimidy, Chem. Listy 98 (2004) 22-28 (in Czech).
- [3] E. Hałasa, Polyimides, Part II, Processing, functional properties and application, Polimery 4 (2003) 254-262.
- [4] M. Okulska-Bożek, T. Prot, J. Szczerba, Polyimides, Part I, Modern synthesis directions, Polymers 39 (1994) 641 (in Polish).
- [5] Product Bulletin, HD-4100 Series Polyimide, HD MicrosystemsTM An Enterprise of Hitachi Chemical and Du Pont Electronics, 2008.
- [6] Product BulleTtMin, HD-8820 Aqueous Positive PBO, HD MicrosystemsTM An Enterprise of Hitachi Chemical and Du Pont Electronics, 2009.
- [7] S. Nakata, M. Kimura, A. Kumano, New photo-alignment technology based on chalcone moieties, Molecular Design and Process Development, SID Symposium Digest of Technical Papers 32/1 (2001) 802-805.
- [8] M. Schadt, H. Seiberle, A. Schuster, Optical patterning of multi-domain liquid crystals with wide viewing angles, Nature 381 (1996) 212-215.
- [9] M. Schadt, K. Schmitt, V. Kozenkov, V. Chigrinov, Surface-induced parallel alignment of liquid crystals by linearly polymerised photopolymers, Japanese Journal of Applied Physics 31 (1992) 2155-2164.
- [10] I. Gerus, A. Glushchenko, Y. Kurioz, Y. Reznikov, O. Tereshchenko, Sticking of liquid crystal on photosensitive polymer layers, Opto-Electronics Review 12/3 (2004) 281-284.
- [11] M. Schadt, H. Seiberle, A. Schuster, S.M. Kelly, Photo-generation of linearly polymerised liquid crystal aligning layers comprising novel, integrated optically patterned retarders and color filters, Japanese Journal of Applied Physics 34 (1995) 3240-3249.
- [12] P.L. Egerton, J. Trigg, E.M. Hyde, A. Reiser, Photocycloaddition at excimer sites in a solid polyester of p-phenylenediacrylic acid, Macromolecules 14 (1981) 100-104.
- [13] K.H. Jung, S.-Y. Hyun, D.-M. Song, D.-M. Shin, The characteristics of polyimide photoalignment layer with chalcone derives produced by linear polarised UV light, Optical Materials 21 (2002) 663.
- [14] C. Nieuwkerk, M. Deurzen, Multidomain vertically aligned nematic LCDs with switchable pixel walls, SID Symposium Digest of Technical Papers 36/1 (2005) 1168-1171.
- [15] M.M. Chrzanowski, J. Zieliński, E. Nowinowski-Kruszelnicki, M. Olifierczuk, Photoalignment - an alternative aligning technique for fast liquid crystal shutter, Bulletin WAT 59/3 (2010) 375-394 (in Polish).
- [16] K. Sakamoto, K. Usami, M. Kikegawa, S. Ushioda, Alignment of polyamic acid molecules containing azobenzene in the backbone structure, Effects of polarised ultraviolet light irradiation and subsequent thermal imidisation, Japanese Journal of Applied Physics 93 (2003) 1039-1043.
- [17] K. Sakamoto, K. Usami, T. Kanayama, M. Kikegawa, S. Ushioda, Photoinduced inclination of polyimide molecules containing azobenzene in the backbone structure, Japanese Journal of Applied Physics 94 (2003) 2302-2308.
- [18] K. Usami, K. Sakamoto, Y. Uehara, S. Ushioda, Transfer of the in-plane molecular orientation of polyimide film surface to liquid crystal monolayer, Applied Physics Letters 86 (2005) 211906-211909.
- [19] K. Usami, K. Sakamoto, J. Yokota, Y. Uehara and S. Ushioda, Polyimide photo-alignment layers for inclined homeotropic alignment of liquid crystal molecules, Thin Solid Films 516 (2008) 2652-2655.
- [20] M. Pluta, Mikrointerferometria in polarized light, WNT, Warsaw, 1990 (in Polish).
- [21] I. Gvozdovskyy, Yu. Kurioz, Yu. Reznikov, Exposure and temperature dependences of contact angle of liquid crystals on photoaligning surface, Opto-Electronics Review 17/2 (2009) 116-119.
- [22] J. Borycki, M. Wilczek, A. Yu. Kolendo, Heat plasticisation of starch by extrusion in the presence of plasticisers, Polymers 51/5 (2006) 333-340.
- [23] A. Rudawska, E. Janicka, Analysis for determining surface free energy uncertainty by the Owen-Wendt metod, International Journal of Adhesion and Adhesives 29 (2009) 451-457.
- [24] M.M. Chrzanowski, J. Zieliński, M. Olifierczuk, J. Kędzierski, M. Zgutka, R. Mazur, W. Piecek, H. Maciejewski, Liquid Crystal aligning ability of photosensitive polymer material, Molecular Crystals and Liquid Crystals, in press (2011).
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Bibliografia
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