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The character of the structure formation of model alloys of the Fe-Cr-(Zr, Zr-B) system synthesized by powder metallurgy

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The purpose of the work is to synthesize and investigate the character of structure formation, phase composition and properties of model alloys Fe75Cr25, Fe70Cr25Zr5, and Fe69Cr25Zr5B1. Design/methodology/approach: Model alloys are created using traditional powder metallurgy approaches. The sintering process was carried out in an electric arc furnace with a tungsten cathode in a purified argon atmosphere under a pressure of 6·104 Pa on a water cooled copper anode. Annealing of sintered alloys was carried out at a temperature of 800°C for 3 h in an electrocorundum tube. The XRD analysis was performed on diffractometers DRON-3.0M and DRON-4.0M. Microstructure study and phase identification were performed on a REMMA-102-02 scanning electron microscope. The microhardness was measured on a PMT-3M microhardness meter. Findings: When alloying a model alloy of the Fe-Cr system with zirconium in an amount of up to 5%, it is possible to obtain a microstructure of a composite type consisting of a mechanical mixture of a basic Fe2(Cr) solid solution, solid solutions based on Laves phases and dispersive precipitates of these phases of Fe2Zr and FeCrZr compositions. In alloys of such systems or in coatings formed based on such systems, an increase in hardness and wear resistance and creep resistance at a temperature about 800°C will be reached. Research limitations/implications: The obtained results were verified during laser doping with powder mixtures of appropriate composition on stainless steels of ferrite and ferrite-martensitic classes. Practical implications: The character of the structure formation of model alloys and the determined phase transformations in the Fe-Cr, Fe-Cr-Zr, and Fe-Cr-B-Zr systems can be used to improve the chemical composition of alloying plasters during the formation of ferrite and ferrite-martensitic stainless steel coatings. Originality/value: The model alloys were synthesized and their phase composition and microstructure were studied; also, their microhardness was measured. The influence of the chemical composition of the studied materials on the character of structure formation and their properties was analysed.
Rocznik
Strony
49--57
Opis fizyczny
Bibliogr. 28 poz., rys., tab., wykr.
Twórcy
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
  • The John Paul II Catholic University of Lublin, 14 Racławickie Av., 20-950 Lublin, Poland
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
autor
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
Bibliografia
  • [1] V.V. Shyrokov, Kh.B. Vasyliv, Z.A. Duryahina, H.V. Laz'ko, N.B. Rats'ka, Effect of laser microalloying with niobium on the wear resistance of stainless steels, Materials Science 45/4 (2009) 473-480. DOI: https://doi.org/10.1007/s11003-010-9204-5
  • [2] V.V. Kulyk, S.Ya. Shipitsyn, O.P. Ostash, Z.A. Duriagina, V.V. Vira, The joint effect of vanadium and nitrogen on the mechanical behaviour of railroad wheels steel, Journal of Achievements in Materials and Manufacturing Engineering 89/2 (2018) 56-63. DOI: https://doi.org/10.5604/01.3001.0012.7109
  • [3] S. Ghosh, J. Basu, D. Ramachandran, E. Mohandas, M. Vijayalakshmi, A unified approach to phase and microstructural stability for Fe-ETM alloys through Miedema’s model, Intermetallics 23 (2012) 148-157. DOI: https://doi.org/10.1016/j.intermet.2011.11.016
  • [4] J. Basu, S. Ranganathan, Glass forming ability and stability: Ternary Cu bearing Ti, Zr, Hf alloys, Intermetallics 17/3 (2009) 128-135. DOI: https://doi.org/10.1016/j.intermet.2008.10.006
  • [5] V. Pokhmurs’kyi, M. Student, B. Formanek, V. Serivka, Yu. Dz’oba, V. Dovhunyk, I. Sydorak, Heat resistance of electric arc coatings made of Fe-Cr-B-Al powder wire, Materials Science 39/6 (2003) 829-834. DOI: https://doi.org/10.1023/B:MASC.0000031647.29176.61
  • [6] Z.A. Duriagina, Physics and chemistry of the surface, Publishing House of Lviv Polytechnic National University, Lviv, 2009 (in Ukrainian).
  • [7] V. Efremenko, K. Shimizu, T. Pastukhova, Y. Chabak, M. Brykov, K. Kusumoto, A. Efremenko, Three-body abrasive wear behaviour of metastable spheroidal carbide cast irons with different chromium contents, International Journal of Materials Research 109/2 (2018) 147-156. DOI: https://doi.org/10.3139/146.111583
  • [8] L. Ropyak, V. Ostapovych, Optimization of process parameters of chrome plating for providing quality indicators of reciprocating pumps parts, Eastern-European Journal of Enterprise Technologies 2/5(80) (2016) 50-62. (in Ukrainian). DOI: https://doi.org/10.15587/1729-4061.2016.65719
  • [9] О. Sukhova, Yu. Syrovatko, Features of structurization of composite materials of the solution-and-diffusion type, Metallofizika i Noveishie Tekhnologii 33/Spec. Iss. (2011) 371-378 (in Russian).
  • [10] I.M. Spiridonova, E.V. Sukhovaya, S.B. Pilyaeva, О.G. Bezrukavaya, The use of composite coatings during metallurgical equipment parts repair, Metallurgicheskaya i Gornorudnaya Promyshlennost 3 (2002) 58-61 (in Russian).
  • [11] Z.A. Duryagina, S.A. Bespalov, V.Ya. Pidkova, D.Yu. Polockyj, Examination of the dielectric layers on the structural materials formed by hybrid ion-plasma discharge system, Metallofizika i Noveishie Tekhnologii 33/Spec. Iss. (2011) 393-400 (in Ukrainian).
  • [12] Z.A. Duryagina, N.V. Shcherbowskikh, S.A. Bespalov, The effect of laser alloying by powder mixtures on the structure and micromechanical properties of 12X18H10T steel, Metallofizika i Noveishie Tekhnologii 33/7 (2011) 969-975 (in Ukrainian).
  • [13] Z.A. Duryahina, A.K. Borysyuk, S.A. Bespalov, V.Y. Pidkova, Influence of the thermal cyclic treatment on the phase composition of ion-nitrided surface layers of 12Kh18N10T steel, Materials Science 48/3 (2012) 364-368. DOI: https://doi.org/10.1007/s11003-012-9514-x
  • [14] N. Pavlenko, N. Shcherbovskikh, Z.A. Duriagina, Interstitial Fe-Cr alloys: Tuning of magnetism by nanoscale structural control and by implantation of nonmagnetic atoms, The European Physical Journal – Applied Physics 58/1 (2012) 10601. DOI: https://doi.org/10.1051/epjap/2012110002
  • [15] M. Bachhav, G.R. Odette, E.A. Marquis, α′ precipitation in neutron-irradiated Fe-Cr alloys, Scripta Materialia 74 (2014) 48-51. DOI: https://doi.org/10.1016/j.scriptamat.2013.10.001
  • [16] W. Xiong, M. Selleby, Q. Chen, J. Odqvist, Y. Du, Phase equilibria and thermodynamic properties in the Fe-Cr system, Critical Reviews in Solid State and Materials Sciences 35/2 (2010) 125-152. DOI: https://doi.org/10.1080/10408431003788472
  • [17] A. Morley, G. Sha, S. Hirosawa, A. Cerezo, G.D.W. Smith, Determining the composition of small features in atom probe: bcc Cu-rich precipitates in an Fe-rich matrix, Ultramicroscopy 109/5 (2009) 535-540. DOI: https://doi.org/10.1016/j.ultramic.2008.09.010
  • [18] O.A. Bannykh, P.B. Budberg, S.P. Alisova, L.S. Guzey, M.E. Drisch, M.V. Dobatkina, E.V. Lysova, N.I. Nikitina, E.M. Padezhnova, L.L. Rokhlin, O.P. Chernogorova, State diagrams of binary and multicomponent systems based on iron, Ref. publ., Metallurgy, Moskow, 1986 (in Russian).
  • [19] M.F. Ashby, Materials and Sustainable Development, Butterworth-Heinemann, 2016. DOI: https://doi.org/10.1016/C2014-0-01670-X
  • [20] Y. Yang, L. Tan, H. Bei, J.T. Busby, Thermodynamic modeling and experimental study of the Fe-Cr-Zr system, Journal of Nuclear Materials 441/1-3 (2013) 190-202. DOI: https://doi.org/10.1016/j.jnucmat.2013.05.061
  • [21] F. Stain, G. Sauthoff, M. Palm, Experimental determination of intermetallic phases, phase equilibria, and invariant reaction temperatures in the Fe-Zr system, Journal of Phase Equilibria 23 (2002) 480-494. DOI: https://doi.org/10.1361/105497102770331172
  • [22] T.O. Malakhova, Splavy Atomic Energy, in: O.S. Ivanov, Z.M. Alekseeva (eds.), Nauka Moskow, 1979, 123-130 (in Russian).
  • [23] M. Saber, H. Kotan, C.C. Koch, R.O. Scattergood, Thermal stability of nanocrystalline Fe-Cr alloys with Zr additions, Materials Science and Engineering: A 556 (2012) 664-670. DOI: https://doi.org/10.1016/j.msea.2012.07.045
  • [24] J. Weissmüller, Alloy effects in nanostructures, Nanostructured Materials 3/1-6 (1993) 261-272. DOI: https://doi.org/10.1016/0965-9773(93)90088-S
  • [25] I.T.H. Chang, K. Ishii, B. Cantor, Heat treatment of rapidly solidified Fe-Cr-Zr-B alloys, Journal of Thermal Analysis 42 (1994) 667-678. DOI: https://doi.org/10.1007/BF02546741
  • [26] Steel Castings Handbook. Supplement 2, Summary of standard specifications for steel castings, Steel Founders Society of America, Cristal Lake, Illinois, 2017.
  • [27] G. Changqing, W. Caidong, L. Xiaoping, P.M. Kelly, Effect of variable heat treatment modes on microstructures of Fe-Cr-B cast iron alloy, China Foundry 5 (2008) 28-31.
  • [28] K Szymański, M Szpak, The structure of Fe-Cr-B coatings obtained using selected methods of thermal spraying, IOP Conference Series: Materials Science and Engineering 35 (2012) 012001. DOI: https://doi.org/10.1088/1757-899X/35/1/012001
Uwagi
EN
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2ed3ebab-232e-424e-92ed-1aed6299a78a
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