The influence of silica functionalized with silanes on migration of heavy metals in soil

• Autorzy: Grzesiak P. , Łukaszyk J. , Gabała E. , Kurczewska J. , Schroeder G.

Identyfikatory

DOI

10.1515/pjct-2016-0009

• Języki publikacji: EN

Abstrakty

EN

3-Mercaptopropyl-trimethoxysilane and [3-(2-aminoethylamino)propyl]trimethoxysilane were used to functionalize the surface of silica from Piotrowice in Poland to stabilize heavy metals (HMs) and arsenic in soil. The soil for the study was sampled from the impact zone of Głogów Copper Smelter and Refinery. The soil samples were exposed to five-step Tessier sequential extraction. The speciation studies were limited to five sequentially defined fractions in which metal content was determined. The addition of unmodified silica did not affect significantly the concentration of metals in individual fractions. Significant changes were noted upon introduction of functionalized silica in the soil. The hybrid formulations obtained significantly reduce the release of heavy metals and arsenic from soil sorption complex. The results indicate the potential use of functional formulations for reduction of metal migration in soil in the areas of exceeded concentration of heavy metals and arsenic in the soil, caused by industrial activity.

Słowa kluczowe

EN

functionalized silica; heavy metals; Soil stabilization

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2016
• Tom: Vol. 18, nr 1
• Strony: 51--57
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Grzesiak P.

• Institute of Plant Protection – National Research Institute, Department of Ecology and Environmental Protection, Władysława Węgorka 20, 60-318 Poznań, Poland

autor

Łukaszyk J.

• Institute of Plant Protection – National Research Institute, Department of Ecology and Environmental Protection, Władysława Węgorka 20, 60-318 Poznań, Poland

autor

Gabała E.

• Institute of Plant Protection – National Research Institute, The Research Centre of Quarantine, Invasive and Genetically Modified Organisms, Władysława Węgorka 20, 60-318 Poznań, Poland

autor

Kurczewska J.

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Umultowska 89b, 61-614 Poznań, Poland

autor

Schroeder G.

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Umultowska 89b, 61-614 Poznań, Poland

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.