Catalytic converison of kraft lignin using paper-like Co(salen) as an effective catalyst

• Autorzy: Gao T. T. , Zhou X. F. , Zhu Z. L.

Identyfikatory

DOI

10.12841/wood.1644-3985.130.07

• Języki publikacji: EN

Abstrakty

EN

Co(salen) powders were homogeneously scattered over a ceramic fibre network to give a catalyst paper and the Co(salen) paper was tested for the oxidative degradation of a kraft lignin using H2O2 as an oxidant. Due to the structural effect of the interconnected 3D-network, the catalyst paper exhibited a higher performance in the oxidation of kraft lignin with a oil yield of 23.27 % than the original Co(salen) powder with an oil yield of 10.63 %, along with excellent recycling performance. 2,6-Dimethoxyphenol (2.32 mg/kg kraft lignin), vanillin (3.80 mg/kg kraft lignin), and syringaldehyde (2.63 mg/kg kraft lignin) were found to be the main products in the oil obtained. In addition, the structural changes in the kraft lignin were also studied during the process. The phenolic compounds were formed through side chain oxidation together with the oxidative cleavage of β-O-4 linkage.

Słowa kluczowe

EN

kraft lignin; Co(salen); catalyst paper; phenolic compounds

• Wydawca: Sieć Badawcza Łukasiewicz - Poznański Instytut Technologiczny
• Czasopismo: Drewno : prace naukowe, doniesienia, komunikaty
• Rocznik: 2015
• Tom: vol. 58, nr 195
• Strony: 79--90
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Gao T. T.

• Kunming University of Science and Technology, Kunming, China

autor

Zhou X. F.

• Kunming University of Science and Technology, Kunming, China

autor

Zhu Z. L.

• Kunming University of Science and Technology, Kunming, China

Bibliografia

• Badamali, S.K., Luque, R., Clark, J.H. and Breeden, S.W. [2011]: Co(salen)/SBA-15 catalysed oxidation of a β-O-4 phenolic dimer under microwave irradiation. Catalysis Communications 12[11]: 993–995
• Bayne, L., Ulijn, R.V. and Halling, P.J. [2013]: Effect of pore size on the performance of immobilised enzymes. Chemical Society Reviews [42]: 9000–9010
• Bortolozzi, J.P., Banús, E.D., Terzaghi, D., Gutierrez, L.B., Milt, V.G. and Ulla, M.A. [2013]: Novel catalytic ceramic papers applied to oxidative dehydrogenation of ethane. Catalysis Today 216[6]: 24–29
• Bozell, J.J. [2014]: Approaches to the selective catalytic conversion of lignin: A grand challenge for biorefinery development. Topics in Current Chemistry [353]: 229–255
• Cedeno, D., Bozell, J.J. [2012]: Catalytic oxidation of para-substituted phenols with cobalt–Schiff base complexes/O2 -selective conversion of syringyl and guaiacyl lignin models to benzoquinones. Tetrahedron Letters 53[19]: 2380–238
• Cozzi, P.G. [2004]: Metal–Salen Schiff base complexes in catalysis: practical aspects. Chemical Society Reviews 33[3]: 410–421
• Erdocia, X., Prado, R., Corcuera, M.n. and Labidi, J. [2014]: Base catalyzed depolymerization of lignin: Influence of organosolv lignin nature. Biomass & Bioenergy 66[7]: 379–386
• Haikarainen, A. [2005]: Metal-salen catalysts in the oxidation of lignin model compounds. Helsingin Yliopisto
• Homma, T., Kitaoka, T. [2014]: Preparation of porous paper composites with ruthenium hydroxide and catalytic alcohol oxidation in a multiphase gas–liquid–solid reaction. Materials Science & Engineering B 184[5]: 7–13
• Hurisso, B.B., Singer, R.D. [2013]: Recyclable ionic liquid tagged Co(salen) catalysts for the oxidation of lignin model compounds. Canadian Journal of Chemistry 91[12]: 1258–1261
• Koga, H., Ishihara, H., Kitaoka, T., Tomoda, A., Suzuki, R. and Wariishi, H. [2010]: NOX reduction over paper-structured fiber composites impregnated with Pt/Al2O3 catalyst for exhaust gas purification. Journal of Materials Science 45[15]: 4151–4157
• Mlekodaj, K., Tarach, K., Datka, J., Góra-Marek, K. and Makowski, W.a. [2014]: Porosity and accessibility of acid sites in desilicated ZSM-5 zeolites studied using adsorption of probe molecules. Microporous & Mesoporous Materials 183[1]: 54–61
• Pineda, A., Balu, A.M., Campelo, J.M., Romero, A.A., Carmona, D., Balas, F., Santamaria, J. and Luque, R. [2011]: A Dry Milling Approach for the Synthesis of Highly Active Nanoparticles Supported on Porous Materials. Chemsuschem 4[11]: 1561–1565
• Pineda, A., Balu, A.M., Campelo, J.M., Luque, R., Romero, A.A. and Serrano-Ruiz, J.C. [2012]: High alkylation activities of ball-milled synthesized low-load supported iron oxide nanoparticles on mesoporous aluminosilicates. Catalysis Today 187[1]: 65–69
• Poltowicz, J., Pamin, K., Tabor, E., Haber, J., Adamski, A. and Sojka, Z. [2006]: Metallosalen complexes immobilized in zeolite NaX as catalysts of aerobic oxidation of cyclooctane. Applied Catalysis A：general 299[1]: 235–242
• Rajagopalan, B., Hu, C., Busch, D.H. and Subramaniam, B. [2008]: The Catalytic Efficacy of Co(salen)(AL) in O2 Oxidation Reactions in CO2-Expanded Solvent Media: Axial Ligand Dependence and Substrate Selectivity. Catalysis Letters 123[1-2]: 46–50
• Sagiri, S.S., Pal, K., Basak, P., Rana, U.A., Shakir, I. and Anis, A. [2014]: Encapsulation of sorbitan ester-based organogels in alginate microparticles. Aaps Pharmscitech 15[5]: 1197–1208
• Santos, P.S.B.d., Erdocia, X., Gatto, D.A. and Labidi, J. [2014]: Characterisation of Kraft lignin separated by gradient acid precipitation. Industrial Crops and Products [55]: 149–154
• Toledano, A., Serrano, L., Pineda, A., Romero, A.A., Luque, R. and Labidi, J. [2012]: Microwave-assisted depolymerisation of organosolv lignin via mild hydrogen-free hydrogenolysis: Catalyst screening. Applied Catalysis B Environmental 145[2]: 43–55
• ZakrajSek, N. [2014]: Influence of Inorganic Salts on the Adsorption of Cationically Modified Starch to Fibers. Food\s&\snutrition Sciences 2014[3]: 245–249
• Zhang, J., Jiang, P., Shen, Y., Zhang, W. and Li, X. [2015]: Molybdenum(VI) complex with a tridentate Schiff base ligand immobilized on SBA-15 as effective catalysts in epoxidation of alkenes. Microporous & Mesoporous Materials [206]: 161–169
• Zhang, N., Zhou, X.F. [2012]: Salen copper (II) complex encapsulated in Y zeolite: An effective heterogeneous catalyst for TCF pulp bleaching using peracetic acid. Journal of Molecular Catalysis A Chemical 36[4]: 66–72
• Zhou, X.F. [2014a]: Application of zeolite-encapsulated Cu(II) [H4]salen derived from [H2]salen in oxidative delignification of pulp. Rsc Advances 4[53]: 28029–28035
• Zhou, X.F. [2014b]: Conversion of kraft lignin under hydrothermal conditions. Bioresource Technology [170]:583–586
• Zhou, X.F. [2014c]: Selective oxidation of kraft lignin over zeolite–encapsulated Co(II) [H4]salen and [H2]salen complexes. Journal of Applied Polymer Science 131[18]: 9594–9602