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The paper presents the results of an investigation of the gases emission of moulding sands with an inorganic (geopolymer) binder with a relaxation additive, whose main task is to reduce the final (residual) strength and improves knocking-out properties of moulding sand. The moulding sand without a relaxation additive was the reference point. The research was carried out using in accordance with the procedure developed at the Faculty of Foundry Engineering of AGH - University of Science and Technology, on the patented stand for determining gas emissions. Quantification of BTEX compounds was performed involving gas chromatography method (GC).The study showed that the introduction of relaxation additive has no negative impact on gas emissions - both in terms of the total amount of gases generated, as well as emissions of BTEX compounds. Among the BTEX compounds, only benzene is emitted from the tested moulding sands. Its emission is associated with the introduction a small amount of an organic hardener from the group of esters.
Czasopismo
Rocznik
Tom
Strony
19--25
Opis fizyczny
Bibliogr. 33 poz., rys., tab., wykr.
Twórcy
autor
- AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
Bibliografia
- [1] Kubecki, M., Holtzer, M., Bobrowski, A., Dańko, R., Grabowska, B. & Żymankowska-Kumon, S. (2012). Analysis of the Compounds from the BTEX Group, Emitted During Thermal Decomposition of Alkyd Resin. Archives of Foundry Engineering. 12(3), 69-74. DOI: 10.2478/v10266-012-0084-z.
- [2] Żymankowska-Kumon, S., Bobrowski, A. & Grabowska, B. (2016). Comparison of the Emission of Aromatic Hydrocarbonsfrom Moulding Sands with Furfural Resin with the Low Contentof Furfuryl Alcohol and Different Activators. Archives of Foundry Engineering. 16(4), 187-190. DOI: 10.1515/afe-2016-0107.
- [3] Holtzer, M., Grabowska, B., Żymankowska-Kumon, S., Kwaśniewska-Królikowska, D., Dańko, R., Solarski, W. & Bobrowski, A. (2012). Harmfulness of moulding sands with bentonite and lustrous carbon carriers. Metalurgija. 51(4), 437-440.
- [4] Dobosz, S.M., Jelínek, P. & Major-Gabryś, K. (2011). Development tendencies of moulding and core sands. China Foundry. 8(4), 438-446.
- [5] Major-Gabryś, K. (2016). Enironmentally friendly foundry moulding and core sands. Archives of Foundry Engineering. Katowice-Gliwice. (in Polish).
- [6] Manning, R.L. & Zaretskiy, L.S. (1997). New generation of inorganic binders. AFS Transactions. 105, 205-209.
- [7] Löchte, K., Boehm, R. (2006). Inorganic binders: Properties and experience. Word Foundry Congress.
- [8] Izdebska-Szanda, I. & Baliński, A. (2011). New generation of ecological silicate binders. Procedia Engineering. 10. 887-893. DOI:10.1016/j.proeng.2011.04.146.
- [9] Pezarski, F., Izdebska-Szanda, I., Smoluchowska, E., Świder, R., Pysz, A. (2011). Zastosowanie mas formierskich ze spoiwem geopolimerowym do produkcji odlewów ze stopów Al. The Transactions of the Foundry Research Institute LI(2). 23-34. DOI: 10.7356/iod.2011.6.
- [10] Chun-xi, Z. (2007). Recent advances in waterglass sand technologies. China Foundry. 4 (1), 013-017.
- [11] Burian, A., Novotný J. (2008). Production of molds and cores with an ecological binder system. XI Materiały konferencyjne z Konferencji Odlewniczej Technical 2008. 81-91. (in Polish).
- [12] Holtzer, M., Drożyński, D., Bobrowski, A.& Plaza, W. (2014). Influence of binding rates on strength properties of moulding sands with the GEOPOL binder. Archives of Foundry Engineering. 14(1). 37-40. DOI:10.2478/afe-2014-0009.
- [13] Pezarski, F., Smoluchowska, E., Izdebska-Szanda, I. (2008). The use of geopolymer binder for the production of iron alloy castings. The Transactions of the Foundry Research Institute. XLVIII (2), 19-34.
- [14] Stachowicz, M. (2015). Possibilities of waste binder reclamation using the example of moulding sands with water glass hardened by the conventional drying process. The Transactions of the Foundry Research Institute 55(2), 29-41. DOI: 10.7356/iod.2015.06.
- [15] Baliński, A. (2017). Effect of the way of modification of hydrated sodium silicate on the effectiveness of the changes in the residual strength of a moulding sand. The Transactions of the Foundry Research Institute LVII(3). 161-168. DOI: 10.7356/iod.2017.14.
- [16] Lewandowski, J.L. (1997). Materials for foundry molds. Cracow. Akapit Publisher.
- [17] Burian, A., Novotný, J. (2008). Production of molds and cores with an ecological binder system. XI. Conference materials from the Foundry Conference Technical 2008. 81-91. (in Polish).
- [18] Jelinek, P. (2004). Binder systems of discount molding mixtures. Ostrawa. (in Czech).
- [19] Pezarski, F., Izdebska-Szanda, I., Smoluchowska, E. (2008). Research on the improvement of properties and the use of new inorganic binders to production ecological moulding and core sands. The Transactions of the Foundry Research Institute XLVIII(2). 48-56. DOI: 10.7356/iod.2008.10.
- [20] Dobosz, St. M., Major-Gabryś, K. Alternative ester hardener for moulding sands with water glass. Materiały XXXI Konferencji Naukowej z okazji Dnia Odlewnika 2007. 33-38 (in Polish).
- [21] Granat, K., Nowak, D., Pigiel, M., Stachowicz, M. & Wikiera, R. (2008). The influence of microwave heating and water glass kind on the properties of molding sands. Archives of Foundry Engineering. 8(spec.1), 119-122.
- [22] Stachowicz, M., Granat, K. & Nowak, D. (2010). Studies on the possibility of more effective use of water glass thanks to application of selected methods of hardening. Archives of Foundry Engineering. 10(2), 135-140.
- [23] Drożyński, D., Bobrowski, A. & Holtzer, M. (2015). Influence of the reclaim addition on properties of moulding sands with the GEOPOL binder. Archives of Foundry Engineering. 15(1), 138-142. DOI:10.1515/afe-2015-0025.
- [24] Bobrowski, A., Holtzer, M., Żymankowska-Kumon, S. & Dańko, R. (2015). Harmfulness assessment of moulding sands with a geopolymer binder and a new hardener, in an aspect of the emission of substances from the BTEX group. Archives of Metallurgy and Materials. 60(1), 341-344. DOI: 10.1515/amm-2015-0056.
- [25] Huafang, W., Zitian, F., Shaoqiang, Y., Fuchu, L. & Xuejie, L. (2012). Wet reclamation of sodium silicate used sand and biological treatment of its wastewater by Nitzschia palea. China Foundry. 9(1), 34-38.
- [26] Dańko, J., Kamińska, J. & Skrzyński, M. (2013). Reclamation of spent moulding sands with inorganic binders in the vibratory reclaimer Regmas. Archives of Metallurgy and Materials. 58(3), 993-996. 10.2478/amm-2013-0117.
- [27] Fan, Z., Huang, N., Wang, H. & Dong X. (2005). Dry reusing and wet reclaiming of used sodium silicate sand. China Engineering. 2(1), 38-43.
- [28] Pezarski, F., Izdebska-Szanda, I., Smoluchowska, E., Świder, R., Pysz, A. (2011). Model research on the reclamation process of used moulding sands with a new inorganic binder intended for the production of Al alloy castings. P The Transactions of the Foundry Research Institute LI(3). 37-57. DOI: 10.7356/iod.2011.11.
- [29] Dobosz, St.M. & Major-Gabryś, K. (2008). The mechanism of improving the knock-out properties of moulding sands with water glass. Archives of Foundry Engineering. 8(1), 37-42.
- [30] Major-Gabryś, K. & Dobosz, St.M. (2011). The influence of the Glassex additive on technological and knock-out properties of the moulding sands with hydrated sodium silicate and new ester hardeners. Metallurgy and Foundry Engineering. 37(1), 33-40.
- [31] Major-Gabryś, K., Dobosz, St. M. Influence of the glassex addition on selected technological properties and knocking out of moulding sands with water glass and various ester hardeners. Conference materials from the XXXIII Scientific Conference on the occasion of the Polish Foundry Day 2009, 11.12.2009, Krakow.
- [32] Bobrowski, A. (2018). Dehydroxylation phenomenon of selected mineral materials from the group of aluminosilicates as a factor determining of knocking out improvement of moulding sands with an inorganic binder. Archives of Foundry Engineering, Katowice-Gliwice, 2018. (in Polish).
- [33] Holtzer, M, Danko, J., Lewandowski, J.L., Solarski, W., Danko, R., Grabowska, B., Bobrowski, A., Żymankowska-Kumon, S., Sroczynski, A., Rózycki, A., Skrzynski, M. Polish Patent Nr PL 398709 (2013).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2ce63265-b703-42a5-9390-eb1988da11e4