Removal of copper, nickel and tin from model and real industrial wastewater using sodium trithiocarbonate : the negative impact of complexing compounds

Thomas, M.; Białecka, B.; Zdebik, D.

doi:10.24425/118179

Artykuł - szczegóły

Tytuł artykułu

Removal of copper, nickel and tin from model and real industrial wastewater using sodium trithiocarbonate : the negative impact of complexing compounds

Autorzy

Thomas M. , Białecka B. , Zdebik D.

Treść / Zawartość

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Identyfikatory

DOI

10.24425/118179

Warianty tytułu

Usuwania miedzi, niklu i cyny z syntetycznych i rzeczywistych ścieków przemysłowych przy zastosowaniu tritiowęglanu sodu : negatywny wpływ związków kompleksujących

Języki publikacji

Abstrakty

The possibility of Cu(II), Ni(II) and Sn(II) removal from model solutions and real wastewater from the production of PCBs using Na₂CS₃ for precipitation was presented in this paper. The testing was carried out on a laboratory scale using model and real industrial wastewater containing additives in the form of complexing compounds used in the production of PCBs (Na₂EDTA, NH_3(aq), thiourea) and recommended by the USEPA (Na₃MGDA, Na₄GLDA). Application of Na₂CS₃ in optimal conditions of conducting precipitation process was connected with obtaining wastewater containing low concentrations of metals (Cu 0.02 mg/L, Sn <0.01 mg/L, Ni <0.005 mg/L at pH 9.39 and Cu 0.07 mg/L, Sn <0.01 mg/L, Ni 0.006 mg/L at pH 7.79). Controlled application of Na₂CS₃ by the use of a platinum redox electrode was also connected with obtaining treated wastewater containing low concentrations of metals (Cu 0.019 mg/L, Sn <0.05 mg/L, Ni <0.0098 mg/L at pH 9–9.5 and E= -142 mV in the laboratory scale and Cu 0.058 mg/L, Sn <0.005 mg/L, Ni 0.011 mg/L at pH 9.14 and E= +10 mV in the industrial scale). Changing the value of redox potential of treated wastewater by dosing Na₂CS₃ made it possible to control the precipitation process on laboratory and industrial scale by the use of a platinum redox electrode. Controlled application of Na₂CS₃ can be used to remove Cu(II), Ni(II) and Sn(II) from industrial effluent containing chelating compounds like Na₂EDTA, NH_3(aq), thiourea, Na₃MGDA and Na₄GLDA.

Przedstawiono możliwość usuwania jonów Cu(II), Ni(II) oraz Sn(II) z roztworów modelowych oraz ścieków rzeczywistych pochodzących z produkcji PCB przy zastosowaniu do strącania roztworu Na₂CS₃. Badania prowadzono w skali laboratoryjnej z zastosowaniem roztworów modelowych zwierających dodatki związków kompleksujących stosowanych w produkcji PCB (Na₂EDTA, NH_3(aq), tiomocznik) oraz rekomendowanych przez USEPA (Na₃MGDA, Na₄GLDA). Zastosowanie Na₂CS₃ w optymalnych warunkach prowadzenia procesu strącania, związane było z otrzymaniem ścieków zawierających niskie stężenia metali. Zmiana wartości potencjału redoks oczyszczanych ścieków wskutek dozowania Na₂CS₃ umożliwiła kontrolowanie procesu strącania w skali przemysłowej przez zastosowanie platynowej elektrody redoks.

Słowa kluczowe

copper EDTA green chelating agents nickel precipitation of heavy metals sodium trithiocarbonate tin

miedź EDTA zielone czynniki chelatujące nikiel wytrącanie metali ciężkich tritiocarbonat sodu cyna

Wydawca

Institute of Environmental Engineering, Polish Academy of Sciences

Czasopismo

Archives of Environmental Protection

Rocznik

2018

Tom

Vol. 44, no. 1

Strony

33--47

Opis fizyczny

Bibliogr. 36 poz., rys., tab., wykr.

Twórcy

autor

Thomas M.

Central Mining Institute, Poland

autor

Białecka B.

Central Mining Institute, Poland

autor

Zdebik D.

dzdebik@gig.eu

Central Mining Institute, Poland

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).

Typ dokumentu

Bibliografia

Identyfikator YADDA

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