Chemical looping combustion related processes using solid oxygen carriers oxidized in CO2 atmosphere

• Autorzy: Psiuk Bronisław , Wojsa Józef , Gerle Anna , Pochwała Tamara , Szade Jacek , Podwórny Jacek

Identyfikatory

DOI

10.2478/eces-2020-0036

• Języki publikacji: EN

Abstrakty

EN

Chemical-looping combustion (CLC) is an attractive process in CO2 capture, especially when solid oxygen carriers are used in it. The main requirements for oxygen-transporting materials include appropriate oxidation (in air) and reduction (in the presence of fuel) ability. In the paper a conceptual proposition for CLC-related processes with the application of solid oxygen carriers oxidized in both air and CO2 atmosphere has been presented. The possibility of the “looping” process on the same carriers using both CO2 and air atmosphere as an oxidizing agent allows us to enrich the concept of CLC and related processes by proposing a cyclic recirculation of the produced CO2 back to the installation. The oxidizing of solid oxygen carrier in a CO2 atmosphere is accompanied by CO emission from the plant. This toxic gas could be transformed into a useful product in any chemical process. It is possible to combine the looping processes with manufacturing of any appropriate morphological form of carbon in the cyclic CO disproportionation process. The combined process could lead to a lower CO2 emissions to the environment. SrTiO3 doped by Cr (STO:Cr) and a mixture of TiO2- and Ni-based compounds (TiO2-Ni) were investigated as oxygen transporting materials. The experiment methodology based on thermogravimetric, diffraction and spectroscopic studies was shown. Thermogravimetric (TGA) and Powder Diffraction (XRD) measurements were provided in-situ during a few cycles in a reducing (Ar+3 % H2) and oxidizing environment. Moreover, the STO:Cr powders were characterized ex-situ by the X-ray Photoelectron Spectroscopy (XPS) method. It was found that in tested conditions the cyclic process of the investigated powders’ oxidation and reduction is possible. Satisfactory results considering the oxygen transport capacity was obtained for the TiO2-Ni sample.

Słowa kluczowe

EN

CO2; chemical looping combustion; chemical looping dry reforming; chemical looping gasification; solid oxygen carrier; CO2 decomposition; CO disproportionation

PL

CO2; spalanie w pętli chemicznej; suchy reforming; pętla chemiczna; zgazowanie; stały nośnik tlenu; rozkład CO2; dysproporcjonowanie CO

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. S
• Rocznik: 2020
• Tom: Vol. 27, nr 4
• Strony: 579--589
• Opis fizyczny: Bibliogr. 35 poz., rys., wykr., tab.

Twórcy

autor

Psiuk Bronisław

• Łukasiewicz Research Network, Refractory Materials Division, Institute of Ceramics and Building Materials, ul. Toszecka 99, 44-100 Gliwice, Poland
• The "Edith Stein School with Character" Foundation, ul. Bałtycka 8, 44-100 Gliwice, Poland

autor

Wojsa Józef

• Łukasiewicz Research Network, Refractory Materials Division, Institute of Ceramics and Building Materials, ul. Toszecka 99, 44-100 Gliwice, Poland

autor

Gerle Anna

• Łukasiewicz Research Network, Refractory Materials Division, Institute of Ceramics and Building Materials, ul. Toszecka 99, 44-100 Gliwice, Poland

autor

Pochwała Tamara

• Łukasiewicz Research Network, Refractory Materials Division, Institute of Ceramics and Building Materials, ul. Toszecka 99, 44-100 Gliwice, Poland

autor

Szade Jacek

• A. Chełkowski Institute of Physics, University of Silesia, ul. 75. Pułku Piechoty 1, 41-500 Chorzów, Poland
• Silesian Centre for Education and Interdisciplinary Research, ul. 75. Pułku Piechoty 1A, 41-500 Chorzów, Poland

autor

Podwórny Jacek

• Łukasiewicz Research Network, Refractory Materials Division, Institute of Ceramics and Building Materials, ul. Toszecka 99, 44-100 Gliwice, Poland

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