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Evaluation of ground pollution by hydrocarbons using Rock-Eval pyrolysis

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The exploration and utilization of petroleum are potential hazards to the environment. Successful determination of petroleum contamination in ground relies on accurate definition of the type, source and quantity of contaminant. For this purpose the Rock-Eval® pyrolysis was applied, which is a rapid quantitative (Bulk Rock method) and qualitative (fractional composition using Multi-Heating Rates method) technique. Results of Rock-Eval analysis of 13 samples of concrete and 2 samples of gravel taken from the different sites of the petrol station indicate the highest concentration of light hydrocarbons (gasoline and naphtha fractions), up to over 5% wt. in the direct proximity of petrol pumps. Similarly high contamination (almost 4%wt.), was found near fuel tanks. Here the highest contribution has lubricating oil fraction and the tankers providing fuels are probably the source of this pollution. In the gravel collected in the vicinity of the fuel tanks high concentration (over 5 wt.%) of non-pyrolyzable carbon (soot) was recorded, the source of which are probably diesel engines of fuel tankers supplying fuel.
Słowa kluczowe
Rocznik
Strony
8--12
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
  • AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. Mickiewicza 30, 30-059 Krakow, Poland
autor
  • Marshal Office of the Małopolska Region, Basztowa 22, 31-156 Kraków, Poland
Bibliografia
  • 1. Alinnor, I.J. & Nwachukwu, M.A. (2013). Determination of total petroleum hydrocarbon in soil and groundwater samples in some communities in Rivers State, Nigeria. J. Environ. Chem. Ecotoxicol. 5(11), 292–297. DOI: 10.5897/JECE2013.0298.
  • 2. Sadler, R. & Connell, D. (2003). Analytical Methods for the Determination of Total Petroleum Hydrocarbons in Soil. In A. Langley, M. Gilbey & B. Kennedy (Eds.) Proceedings of the Fifth National Workshop on the Assessment of Site Contamination pp. 133–150. Environment Protection & Heritage Council, Adelaide, Australia.
  • 3. Sari, G.L., Trihadiningrum, Y. & Ni’matuzahroh, N. (2018). Petroleum Hydrocarbon Pollution in Soil and Surface Water by Public Oil Fields in Wonocolo Sub-district, Indonesia. J. Ecol. Eng. 19(2), 184–193. DOI: 10.12911/22998993/82800
  • 4. Levei, E., Senila, M., Cadar, O., Roman, M. & Tanaselia, C. (2014). Validation of Petroleum Hydrocarbons Determination in Soil by Fourier Transform Infrared Spectroscopy. Bulletin USAMV series Agriculture 71(2), 226–230. DOI: 10.15835/buasvmcn-agr:10432.
  • 5. Paíga, P., Mendes, L., Albergaria, J.T. & Delerue-Matos, C.M. (2012). Determination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatography. Chem. Pap. 66(8), 711–721. DOI: 10.2478/s11696-012-0193-8.
  • 6. Biache, C., Lorgeoux, C., Saada, A., Colombano, S. & Faure, P. (2017). Fast method to quantify PAHs in contaminated soils by direct thermodesorption using analytical pyrolysis. Talanta 166, 241–248. DOI:10.1016/j.talanta.2017.01.055.
  • 7. Lafargue, E., Marquis, F. & Pillot, D. (1998). Rock-Eval 6 applications in hydrocarbon exploration, and soil contamination studies, Revue IFP 53(4), 421–437. DOI: 10.2516/ogst:1998036.
  • 8. Behar, F., Beaumont V. & De B. Penteado, H.L. (2001). Rock – Eval 6 Technology: Performances and developments. Rev. IFP 56(2), 111–134. DOI: 10.2516/ogst:2001013.
  • 9. Dahl, B., Bojesen-Koefoed, J., Holm, A., Justwan, H., Rasmussen, E. & Thomsen, E., (2004). A new approach to interpreting Rock-Eval S2 and TOC data for kerogen quality assessment. Org. Geochem. 35, 1461–1477. DOI: 10.1016/j.orggeochem.2004.07.003.
  • 10. Więcław, D. (2016). Habitat and hydrocarbon potential of the Kimmeridgian strata in the central part of the Polish Lowlands. Geol. Quart. 60(1), 192–210. DOI: 10.7306/gq.1260.
  • 11. Kotarba, M.J., Więcław, D., Bilkiewicz, E., Dziadzio, P. & Kowalski, A. (2017). Genetic correlation of source rocks and natural gas in the Polish Outer Carpathians and Paleozoic–Mesozoic basement east of Kraków (southern Poland). Geol. Quart. 61(4), 795–824. DOI: 10.7306/gq.1367.
  • 12. Baudin, F., Disnar, J.R., Aboussou, A. & Savignac, F. (2015). Guidelines for Rock–Eval analysis of recent marine sediments. Org. Geochem. 86, 71–80. DOI: 10.1016/j.orggeochem. 2015.06.009.
  • 13. Carrie, J., Sanei, H. & Stern, G. (2012). Standardisation of Rock-Eval pyrolysis for the analysis of recent sediments and soils. Org. Geochem. 46, 38–53. DOI: 10.1016/j.orggeochem. 2012.01.011.
  • 14. Hetényi, M. & Nyilas, T. (2014). Soil organic matter characterization using S3 and S4 signals from Rock-Eval pyrolysis. Pedosphere 24(5), 563–574.
  • 15. Hetényi, M., Nyilas, T. & Toth, T.M. (2005). Stepwise Rock-Eval pyrolysis as a tool for typing heterogeneous organic matter in soils. J. Anal. Appl. Pyrolysis 74, 45–54. DOI: 10.1016/j.jaap.2004.11.012.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2c2e241e-9645-4787-a532-cfd45dbc5c43
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