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Valorization of Tropical Almond (Terminalia catappa) Leaves into Iron-Containing Activated Carbon for Rapid Catalytic Degradation of Methylene Blue with Hydrogen Peroxide

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This study sought to use tropical almond leaves (TALs) for the simple fabrication of iron-containing activated carbon (IAC). Iron precursor (FeCl3 ) and activating agent (KOH) were sequentially preloaded in TALs. One-pot pyrolysis then generated iron-based particles (8.7 wt%), mainly metallic iron crystals, within AC support. The specific saturation magnetization of IAC was measured to be 48.9 emu/g, highlighting its ability to be efficiently separated using external magnetic fields. Moreover, the activation process yielded IAC with a large total volume of 0.28 cm3/g and a high specific surface area of 463 m2/g. Accordingly, IAC was investigated as an oxidation catalyst to degrade methylene blue (MB) by H2O2. At pH 3.0, 800 ppm H2O2, and 0.10 g/L IAC, 95.3% of MB (200 ppm) was removed after 30 min of adsorption and 60 min of oxidation. Altogether, iron-containing activated carbon from fallen leaves of tropical almonds proved its potential for robust methylene blue degradation by H2O2.
Rocznik
Strony
54--61
Opis fizyczny
Bibliogr. 37 poz., rys.
Twórcy
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
  • Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
  • Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam
Bibliografia
  • 1. Ko T.-F., Weng Y.-M., Lin S.-B. and Chiou R.Y.Y. 2003. Antimutagenicity of supercritical CO2 extracts of Terminalia catappa leaves and cytotoxicity of the extracts to human hepatoma cells. Journal of Agricultural and Food Chemistry, 51(12), 3564–3567.
  • 2. Vinturelle R., Cabral T.d.S., Oliveira P.C.O. d., Salles J.P., Faria J.V., Teixeira G.P., Faria R.X., Veloso M.C.C., Romeiro G.A. and Chagas E.F. d. 2024. Slow pyrolysis of Terminalia catappa L. municipal solid waste and the use of the aqueous fraction produced for bovine mastitis control. Biochemistry and Biophysics Reports, 38, 101704.
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  • 5. Oyeleye S.I., Adebayo A.A., Ogunsuyi O.B., Dada F.A. and Oboh G. 2017. Phenolic profile and enzyme inhibitory activities of almond (Terminalia catappa) leaf and stem bark. International Journal of Food Properties, 20(3), 2810–2821.
  • 6. Madhavan K., Rukayadi Y. and Abdul-Mutalib N.A. 2023. Controlling vegetative cells and spores growth of Bacillus spp. using ethanolic Ketapang (Terminalia catappa L.) leaf extract. Heliyon, 9(8), e18749.
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  • 18. Wang N., Zheng T., Zhang G. and Wang P. 2016. A review on Fenton-like processes for organic wastewater treatment. Journal of Environmental Chemical Engineering, 4(1), 762–787.
  • 19. Hussain S., Aneggi E. and Goi D. 2021. Catalytic activity of metals in heterogeneous Fenton-like oxidation of wastewater contaminants: a review. Environmental Chemistry Letters, 19(3), 2405–2424.
  • 20. Liang L., Cheng L., Zhang Y., Wang Q., Wu Q., Xue Y. and Meng X. 2020. Efficiency and mechanisms of rhodamine B degradation in Fenton-like systems based on zero-valent iron. RSC Advances, 10(48), 28509–28515.
  • 21. Conde-Cid M., Paíga P., Moreira M.M., Albergaria J.T., Álvarez-Rodríguez E., Arias-Estévez M. and Delerue-Matos C. 2021. Sulfadiazine removal using green zero-valent iron nanoparticles: A low-cost and eco-friendly alternative technology for water remediation. Environmental Research, 198, 110451.
  • 22. Zha S., Cheng Y., Gao Y., Chen Z., Megharaj M. and Naidu R. 2014. Nanoscale zero-valent iron as a catalyst for heterogeneous Fenton oxidation of amoxicillin. Chemical Engineering Journal, 255, 141–148.
  • 23. Xie S., Su J., Zhao J., Yang H. and Qian H. 2022. An amorphous zero-valent iron decorated by Fe3 O4 significantly improves the Fenton-like reaction. Journal of Alloys and Compounds, 929, 167306.
  • 24. Xia J., Shen Y., Zhang H., Hu X., Mian M. M. and Zhang W.-H. 2022. Synthesis of magnetic nZVI@ biochar catalyst from acid precipitated black liquor and Fenton sludge and its application for Fentonlike removal of rhodamine B dye. Industrial Crops and Products, 187, 115449.
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  • 28. Do T.V.T., Bui Q.L.N., Nguyen H.M., Lam H.H., Tran-Thuy T.-M., Nguyen L.Q., Ngo D.T.H. and Nguyen D.V. 2022. One-pot fabrication of magnetic biochar by FeCl3-activation of lotus seedpod and its catalytic activity towards degradation of Orange G. Mater. Res. Express, 9, 105601.
  • 29. Nguyen H.M., Truong T.B., Nguyen H.-H.T., Tran P.T., Tran-Thuy T.-M., Nguyen L.Q. and Nguyen D.V. 2023. Catalytic ozonation of Ponceau 4R using multifunctional magnetic biochar prepared from rubber seed shell. Journal of Ecological Engineering, 24(12), 143–151.
  • 30. Nguyen H.M., Tran A.T., Nguyen D.N.L., Lam H.H., Tran-Thuy T.-M., Nguyen L.Q., Le T.X. and Nguyen D.V. 2023. One-pot fabrication of zero-valent iron-embedded activated carbon from rosemary distillation residues for malachite green removal. Mater. Res. Express, 10(8), 085603.
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  • 32. Xu L. and Wang J. 2011. A heterogeneous Fentonlike system with nanoparticulate zero-valent iron for removal of 4-chloro-3-methyl phenol. Journal of Hazardous Materials, 186(1), 256–264.
  • 33. Wang L., Yang J., Li Y., Lv J. and Zou J. 2016. Removal of chlorpheniramine in a nanoscale zerovalent iron induced heterogeneous Fenton system: Influencing factors and degradation intermediates. Chemical Engineering Journal, 284, 1058–1067.
  • 34. Huang T., Zhang G., Zhang N., Ye J. and Lu P. 2018. Fe0-H2 O2 for advanced treatment of citric acid wastewater: Detailed study of catalyst after several times use. Chemical Engineering Journal, 336, 233–240.
  • 35. Segura Y., Martínez F. and Melero J.A. 2013. Effective pharmaceutical wastewater degradation by Fenton oxidation with zero-valent iron. Applied Catalysis B: Environmental, 136–137, 64–69.
  • 36. Zhang M.-h., Dong H., Zhao L., Wang D.-x. and Meng D. 2019. A review on Fenton process for organic wastewater treatment based on optimization perspective. Science of The Total Environment, 670, 110–121.
  • 37. Lv X., Ma Y., Li Y. and Yang Q. 2020. Heterogeneous Fenton-like catalytic degradation of 2,4-dichlorophenoxyacetic acid by nano-scale zero-valent iron assembled on magnetite nanoparticles. Water, 12(10), 2909.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2bdb1cb7-fbe4-48b0-bf67-f367b003208c
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