Carrier recombination in sonochemically synthesized ZnO powders

• Autorzy: Zakirov M. I. , Korotchenkov O. A.

Identyfikatory

DOI

10.1515/msp-2017-0016

• Języki publikacji: EN

Abstrakty

EN

ZnO powders with particle size in the nm to μm range have been fabricated by sonochemical method, utilizing zinc acetate and sodium hydroxide as starting materials. Carrier recombination processes in the powders have been investigated using the photoluminescence, FT-IR and surface photovoltage techniques. It has been shown that the photoluminescence spectra exhibit a number of defect-related emission bands which are typically observed in ZnO lattice and which depend on the sonication time. It has been found that the increase of the stirring time results in a faster decay of the photovoltage transients for times shorter than approximately 5 ms. From the obtained data it has been concluded that the sonication modifies the complicated trapping dynamics from volume to surface defects, whereas the fabrication method itself offers a remarkably convenient means of modifying the relative content of the surface-to-volume defect ratio in powder grains and altering the dynamics of photoexcited carriers.

Słowa kluczowe

EN

ZnO; sonochemical synthesis; surface photovoltage; photoluminescence

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 1
• Strony: 211--216
• Opis fizyczny: Bibliogr. 50 poz., rys., tab.

Twórcy

autor

Zakirov M. I.

• Taras Shevchenko Kiev National University, 64/13 Vladimirskaya St., Kiev, 01601, Ukraine

autor

Korotchenkov O. A.

• Taras Shevchenko Kiev National University, 64/13 Vladimirskaya St., Kiev, 01601, Ukraine

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).