Mechanisms of electrical conductivity, quantum capacity and negative capacitance effects in InSe (PTHQ) nanohybrid

• Autorzy: Ivashchyshyn Fedir , Maksymych Vitaliy , Calus Dariusz , Klapchuk Myroslava , Baryshnikov Glib , Galagan Rostislav , Litvin Valentina , Chabecki Piotr , Bordun Ihor

Identyfikatory

DOI

10.24425/bpasts.2021.139958

• Języki publikacji: EN

Abstrakty

EN

In this work, we present findings on the syntheses and study of properties of InSe < PTHQ > nanohybrid. The introduction of guest component in GaSe matrix leads to an increase in inhomogeneities, which is clearly confirmed by the strengthening of the low-frequency horizontal branch of Nyquist diagrams. A constant magnetic field counteracts this effect and changes the behavior of the impedance hodograph at low frequencies to the opposite. Illumination leads to a colossal increase in quantum capacitance, which is clearly demonstrated in the Nyquist diagram. For the synthesized InSe < PTHQ > nanohybrid the interesting behavior of the current-voltage characteristic is reported. As a result of studies of the synthesized InSe < PTHQ > nanohybrid the effect of “negative capacity” is observed, the magnitude of which can be controlled by the electric field. Based on the constructed impedance model and proposed N-barrier model, the physical mechanisms of the investigated processes are suggested.

Słowa kluczowe

EN

InSe; intercalation; hierarchical structures; impedance spectroscopy; density of states; negative capacity

PL

struktury hierarchiczne; spektroskopia impedancyjna; ujemna pojemność; gęstość stanów; wtrącenie; InSe

• Wydawca: Polska Akademia Nauk, Wydział IV Nauk Technicznych
• Czasopismo: Bulletin of the Polish Academy of Sciences. Technical Sciences
• Rocznik: 2022
• Tom: Vol. 70, nr 1
• Strony: art. no. e139958
• Opis fizyczny: Bibliogr. 25 poz., rys.

Twórcy

autor

Ivashchyshyn Fedir

• Czestochowa University of Technology, Al. Armii Krajowej 17, Czestochowa, 42-200, Poland

• https://orcid.org/0000-0002-6919-5841

autor

Maksymych Vitaliy

• Lviv Polytechnic National University, Bandera Str. 12, Lviv, 79013, Ukraine

• https://orcid.org/0000-0001-9199-8483

autor

Calus Dariusz

• Czestochowa University of Technology, Al. Armii Krajowej 17, Czestochowa, 42-200, Poland

• https://orcid.org/0000-0003-4224-7020

autor

Klapchuk Myroslava

• Lviv Polytechnic National University, Bandera Str. 12, Lviv, 79013, Ukraine

• https://orcid.org/0000-0003-4826-0824

autor

Baryshnikov Glib

• Bohdan Khmelnytsky National University, blvd. Shevchnko 81, 18031, Cherkasy, Ukraine

• https://orcid.org/0000-0002-0716-3385

autor

Galagan Rostislav

• Bohdan Khmelnytsky National University, blvd. Shevchnko 81, 18031, Cherkasy, Ukraine

• https://orcid.org/0000-0003-1791-8486

autor

Litvin Valentina

• Bohdan Khmelnytsky National University, blvd. Shevchnko 81, 18031, Cherkasy, Ukraine

• https://orcid.org/0000-0003-1236-6344

autor

Chabecki Piotr

• Czestochowa University of Technology, Al. Armii Krajowej 17, Czestochowa, 42-200, Poland

• https://orcid.org/0000-0003-4857-8904

autor

Bordun Ihor

• Czestochowa University of Technology, Al. Armii Krajowej 17, Czestochowa, 42-200, Poland
• Lviv Polytechnic National University, Bandera Str. 12, Lviv, 79013, Ukraine

• https://orcid.org/0000-0001-9386-4702

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