Adsorption of resorcinol onto synthetic calcium phosphate compounds: Kinetic, isotherm, and thermodynamic studies

• Autorzy: El Bakri Abdellatif , Ferraa Nouhaila , Lachheb Abdelah , Bennani-Ziatini Mounia

Identyfikatory

DOI

10.12912/27197050/195952

• Języki publikacji: EN

Abstrakty

EN

Using batch adsorption methods, this work examines the adsorption behavior of resorcinol onto two artificial calcium phosphate compounds, tricalcium phosphate apatite (PTCa) and octocalcium phosphate apatite (OCPa). The study is to assess these materials’ adsorption capacities and investigate the impacts of important parameters like pH, temperature, starting concentration, and adsorbent dosage. When both the Freundlich and Langmuir isotherm models were used, the Langmuir model fit the data better, suggesting monolayer adsorption. PTCa and OCPa were shown to have maximal adsorption capabilities of 13.27 mg/g and 5.05 mg/g, respectively. According to kinetic studies, the adsorption process exhibits pseudo-second-order kinetics, which points to chemisorption. The adsorption is exothermic and spontaneous, driven by physical interactions including van der Waals forces and hydrogen bonds, according to thermodynamic considerations. The study comes to the conclusion that PTCa and OCPa, with their high adsorption capacities and advantageous thermodynamic and kinetic properties, are attractive materials for the elimination of resorcinol from aqueous solutions.

Słowa kluczowe

EN

OCPa; PTCa; adsorption equilibrium; thermodynamics; resorcinol

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2025
• Tom: Vol. 26, iss. 1
• Strony: 257--271
• Opis fizyczny: Bibliogr. 47 poz., rys., tab.

Twórcy

autor

El Bakri Abdellatif

• Laboratory of Organic Chemistry, catalysis and environment, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PB. 133-14050 Kenitra, Morocco.

• https://orcid.org/0009-0004-7962-2845

autor

Ferraa Nouhaila

• Laboratory of Organic Chemistry, catalysis and environment, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PB. 133-14050 Kenitra, Morocco.

• https://orcid.org/0000-0003-1817-7798

autor

Lachheb Abdelah

• Laboratory of Organic Chemistry, catalysis and environment, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PB. 133-14050 Kenitra, Morocco.

autor

Bennani-Ziatini Mounia

• Laboratory of Organic Chemistry, catalysis and environment, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PB. 133-14050 Kenitra, Morocco.

• https://orcid.org/0009-0001-8443-8506

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