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Magnesium hydroxide recovery from magnesia waste by calcinations and hydration processes

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, hydration behavior of the magnesia waste, supplied from the electrostatic bag house of the sintering unit of MAS Company, Eskisehir-Turkey was studied to find out re-usability of the material as a source of magnesium hydroxide (Mg(OH)2) production. According to chemical and crystalline phase analyses, MgO content of the sample was determined as 49.9 wt% and consists of mainly raw magnesite (MgCO3), sintered magnesia-periclase (MgO) and small amount of serpentine (lizardite) phases. In hydration process, the reactivity of magnesium oxide determines the rate and extent of hydration of the sample. Therefore, the waste samples both calcined and uncalcined forms were hydrated in water and the efficiencies were compared according to sample source. The hydration experiments were carried out at temperatures ranging from 30 C and 80 C to evaluate the influence of temperature on particle morphology and surface areas of the products. The efficiency of the hydration was evaluated by using thermogravimetric (TG) and scanning electron microscopy (SEM) analyses. The test results suggest that the magnesia waste could be used as a source material for production of magnesium hydroxide.
Rocznik
Strony
233--245
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
autor
  • Eskisehir Osmangazi University, Mining Engineering Department, Eskisehir-Turkey
autor
  • Bursa Technical University, Chemical Engineering Department, Bursa-Turkey
Bibliografia
  • 1. APHANE M.E., 2007, The hydration of magnesium oxide with different reactivities by water and magnesium acetate. M.Sc. Thesis, University of South Africa
  • 2. BEALL G.W., DURAIA M.E., TANTAWY F., AL-HAZMI, F., AL-GHAMDI A.A., 2013, Rapid fabrication of nanostructured magnesium hydroxide and hydromagnesite via microwave assisted technique, Powder Technol., 234, 26-31.
  • 3. BIRCHAL V.S., ROCHA S.D.F., CIMINELLI, V.S.T., 2000, The effect of magnesite calcination conditions on magnesia hydration, Minerals Engineering, 13, 1629-1633
  • 4. BIRCHAL V.S., ROCHA S.D.F., MANSUR M.B., CIMINELLI V.S.T., 2001, A simplified mechanistic analysis of magnesia hydration, Can. J. Chem. Eng., 79, 507-511.
  • 5. CLIMENT W.J., CORMA A., IBORRA S., MIFSUD M., 2007, MgO nanoparticle-based multifunctional catalysts in the cascade reaction allows the green synthesis of anti-inflammatory agents, J. Catal., 247, 223-230.
  • 6. DONG C., CAIRNEY J., SUN Q., MADDAN O.L., HE G., DENG Y., 2010, Investigation of Mg(OH)2 nanoparticles as an actibacterial agent, J. Nanopart. Res., 12, 2101-2109.
  • 7. DONG C.X., SONG D., CAIRNEY J., MADDAN O.L., HE G., DENG Y., 2011, Antibacterial study of Mg(OH)2 nanoplatelets, Mater. Res. Bull., 46, 576-582.
  • 8. FERNÁNDEZ A.I., HAURIE, L., FORMOSA, J., CHIMENOS, J.M., ANTUNES, M., VELASCO, J.I., 2009, Characterization of poly(ethylene-co-vinyl acetate) (EVA) filled with low grade magnesium hydroxide, Polym. Degrad. Stabil., 94, 57-60.
  • 9. FERNANDEZ A. S., GOMEZ-VİLLALBA, L.S., MİLOSEVİC O., FORTA R., RABANAL M.E., 2014, Synthesis and morpho-structural characterization of nanostructured magnesium hydroxide obtained by a hydrothermal method, Ceramics International, 40, 12285-12292.
  • 10. FILIPPOU D., KATIFORIS, N., PAPASSIOPI, N., ADAM, K., 1999, On the of magnesia hydration in magnesium acetate solutions, J. Chem. Technol. Biotechnol., 74, 322-328.
  • 11. FORMOSA J., CHIMENOS J.M., LACASTA A.M., HAURIE L., 2011, Thermal study of low-grade magnesium hydroxide used as fire retardant and in passive fire protection, Thermochimica Acta, 515, 43-50.
  • 12. GAO C., ZHANG W., LI H., LANG L., AND XU Z., 2008, Controllable Fabrication of Mesoporous MgO with Various Morphologies and Their Absorption Performance for Toxic Pollutants in Water, Crystal Growth Design, 8, 3785-3790.
  • 13. GULKOVA D., SOLCOVA O., ZDRAZIL M., 2004, Preparation of MgO catalytic support in shaped mesoporous high surface area form, Microp. Mesop. Mater., 76, 137-149.
  • 14. HENRIST C., MATHIEU J.-P., VOGELS C., RULMONT A., CLOOTS R., 2003, Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution, Journal of Crystal Growth, 249, 321-330.
  • 15. KİTAMURA A., ONİZUKA O., AND TANAKA K., 1969, Hydration characteristics of magnesia, Taikabutsu Overseas, 16, 3-11.
  • 16. LI X., SHI T., CHANG P., HU H., XIE J., LIU Y., 2014, Preparation of magnesium hydroxide flame retardant from light calcined powder by ammonia circulation method, Powder Technol., 260, 98-104.
  • 17. MARYŠKA M. & BLÁHA, J., 1997, Hydration kinetics of magnesium oxide, part 3 - hydration rate of MgO in terms of temperature and time of its firing, Ceramics -Silikaty, 41, 121-123.
  • 18. PAN X., WANG Y., CHEN Z., PAN D., CHENG Y., LIU Z., LIN Z., GUAN X., 2013, Investigation of antibacterial activity and related mechanism of a series of nano-Mg(OH)2,
  • 19. ACS Appl. Mater. Interfaces, 5, 1137-1142.
  • 20. PILARSKA A. WYSOKOWSKI M., MARKIEWICZ E., JESIONOWSKI T., 2013, Synthesis of magnesium hydroxide and its calcinates by a precipitation method with the use of magnesium sulfate and poly(ethylene glycols), Powder Technology, 235, 148-157.
  • 21. PILARSKA A., LINDA I., WYSOKOWSKI M., PAUKSZTA D., JESIONOWSKI T., 2012, Synthesis of Mg(OH)2 from magnesium salts and NH4OH by direct functionalisation with poly(ethylene glycols, Physicochem. Probl. Miner. Process. 48(2), 631-643.
  • 22. QIANG W., CHUNHONG L., MİNG G., LİNGNA S., CHANGWEN H., 2014, Hydrothermal synthesis of hexagonal magnesium hydroxide nanoflakes, Mater. Res. Bull., 51, 35-39.
  • 23. ROCHA S. DF, MANSUR M. B. AND CIMINELLI V. ST., 2004, Kinetics and mechanistic analysis of caustic magnesia hydration, J. Chem. Technol. Biot., 79, 816-821
  • 24. SHAND M.A., 2006, The chemistry and technology of magnesia, A John Wiley & Sons, Inc. Publication, New Jersey US.
  • 25. STRYDOM C. A. VAN DER MERWE E.M & APHANE, M. E., 2005, The effect of calcining conditions on the rehydration of dead burnt magnesium oxide using magnesium acetate as a hydrating agent, J. Therm. Anal. Cal., 80, (3), 659-662.
  • 26. THOMAS J. J., MUSSO S., PRESTİNİ I., 2014, Kinetics and activation energy of magnesium oxide hydration, J. Am. Ceram. Soc., 97, 275-282.
  • 27. THORP H.W., GILPIN, WC., 1949, Chemical engineering problems in the sea water magnesia process, Proceedings of the society of chemical industry, Society of Chemical Industry, London , UK, 31, 46-48.
  • 28. VAN DER MERWE E. M. & STRYDOM C. A., 2006, Hydration of medium reactive magnesium oxide using hydration agents, Journal of Thermal Analysis and Calorimetry, 84, 467-471.
  • 29. YU J. C., XU, A., ZHANG, L., SONG R., WU, L., 2004, Synthesis and Characterization of Porous Magnesium Hydroxide and Oxide Nanoplates, J. Phys. Chem. B, 108, 64-74.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-289b7a73-2a9f-4ffe-bc0e-fdb8c81fd3b6
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