Effect of Nanomaterials on Thermal Stability of 1,3,6,8-Tetranitro Carbazole

• Autorzy: Pourmortazavi S. M. , Rahimi-Nasrabadi M. , Rai H. , Jabbarzadeh Y. , Javidan A.

Identyfikatory

DOI

10.22211/cejem/65140

• Języki publikacji: EN

Abstrakty

EN

1,3,6,8-tetranitro carbazole (TNC) as a secondary explosive is used in composite explosive formulations in order to reduce the sensitivity and increase the stability of the explosive composites. In this work, the thermal stabilities of pure TNC and its nanocomposites prepared via three different nanoparticles were studied by thermal analysis, i.e. differential scanning calorimetery (DSC) and thermogravimetry (TG) techniques. Thermal analysis data revealed that the thermal behavior of pure TNC is significantly different from the nanocomposites studied. Pure TNC decomposed completely during a single step in the temperature range 385-425 °C. However, the addition of nanoparticles to the TNC powder leads to higher thermal stability in comparison with the pure TNC. The decomposition kinetics of TNC and its nanocomposites were studied by non-isothermal DSC at several heating rates. Thermokinetic and thermodynamic parameters corresponding to the thermal decomposition of pure TNC and nanocomposites were computed and compared. The results showed that the addition of nanoparticles to the TNC powder has a considerable effect on the thermal stability of the explosive.

Słowa kluczowe

EN

thermal stability; nanomaterial effect; decomposition kinetics; 1,3,6,8-tetranitro carbazole; energetic material

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 1
• Strony: 201--216
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Pourmortazavi S. M.

• Faculty of Material and Manufacturing Technologies, Malek Ashtar University of Technology, Tehran, Iran

autor

Rahimi-Nasrabadi M.

• Nano Science Center, Imam Hossein University, Tehran, Iran

autor

Rai H.

• Department of Chemistry, Imam Hossein University, Tehran, Iran

autor

Jabbarzadeh Y.

• Faculty of Material and Manufacturing Technologies, Malek Ashtar University of Technology, Tehran, Iran

autor

Javidan A.

• Department of Chemistry, Imam Hossein University, Tehran, Iran

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).