Influence of the ester block polymerization degree on the structure and properties of ester-ether-amide block terpolymers

Rokicka, Joanna; Janik, Jolanta; Schmidt, Beata; Wilpiszewska, Katarzyna

doi:10.14314/polimery.2024.2.1

Artykuł - szczegóły

Tytuł artykułu

Influence of the ester block polymerization degree on the structure and properties of ester-ether-amide block terpolymers

Autorzy

Rokicka Joanna , Janik Jolanta , Schmidt Beata , Wilpiszewska Katarzyna

Treść / Zawartość

Pełne teksty:

Pobierz

Identyfikatory

DOI

10.14314/polimery.2024.2.1

Warianty tytułu

Wpływ stopnia polimeryzacji bloku estrowego na strukturę oraz właściwości blokowych terpolimerów estrowo-eterowo-amidowych

Języki publikacji

Abstrakty

New multi-block thermoplastic elastomers (TPEEA) were obtained, consisting of a crystalline amide block (domains), an amorphous ether block (continuous phase) and an ester block with a variable degree of polymerization, which acts as a compatibilizer. The presence of large interfacial areas was observed. It was found that ester blocks with a molecular weight <600 g/mol mix with other blocks, modifying the phases that constitute them and stabilizing the micro- and nanophase structure of the entire system. Short ester blocks act as nucleation precursors, and in the hard phase they have plasticizing properties.

Otrzymano nowe wieloblokowe elastomery termoplastyczne (TPEEA), składające się z krystalicznego bloku amidowego (domeny), amorficznego bloku eterowego (faza ciągła) oraz bloku estrowego o zmiennym stopniu polimeryzacji, który pełni funkcję kompatybilizatora. Zaobserwowano obecność dużych obszarów międzyfazowych. Stwierdzono, że bloki estrowe o masie cząsteczkowej <600 g/mol mieszają się z innymi blokami, modyfikując tworzące je fazy i stabilizując strukturę mikro- i nanofazową całego układu. Krótkie bloki estrowe pełnią funkcję prekursorów zarodkowania, a w fazie twardej mają właściwości uplastyczniające.

Słowa kluczowe

thermoplastic elastomers phase structure block copolymers

elastomery termoplastyczne struktura fazowa kopolimery blokowe

Wydawca

Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej

Czasopismo

Polimery

Rocznik

2024

Tom

Vol. 69, nr 2

Strony

75--85

Opis fizyczny

Bibliogr. 56 poz., rys., tab., wykr.

Twórcy

autor

Rokicka Joanna

joanna.rokicka@zut.edu.pl

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0002-2003-6372

autor

Janik Jolanta

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0002-8094-8509

autor

Schmidt Beata

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0001-6274-2278

autor

Wilpiszewska Katarzyna

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0003-2756-3471

Bibliografia

[1] Holden G.: “Thermoplastic Elastomers. Encyclopedia of Polymer Science and Technology”, John Wiley & Sons, Hoboken 2010, p. 465.
[2] Naskar K., Babu R.R.: “Thermoplastic Elastomers (TPEs) and Thermoplastic Vulcanizates (TPVs)” in “Encyclopedia of Polymeric Nanomaterials” (editor Kobayashi S., Müllen K.), Springer, Berlin 2001, p. 2517. https://doi.org/10.1007/978-3-642-29648-2_310
[3] Aiswarya S., Pratiksha A., Banerjee S.S: European Polymer Journal 2022, 181, 111658. https://doi.org/10.1016/j.eurpolymj.2022.111658
[4] Holden G.: “Thermoplastic Elastomers” in “Rubber Technology” (editor Morton M.), Springer, Boston 1987, p. 465. https://doi.org/10.1007/978-1-4615-7823-9_16
[5] Drobny J.G.: “Handbook of Thermoplastic Elastomers”, William Andrew Inc., Norwich 2014, p. 1.
[6] De S.K., Bhowmick A.K.: “Introduction to Thermoplastic Elastomers” in ”Thermoplastic Elastomers from Rubber-Plastic Blends”, Ellis Horwood, New York 1990, p. 13.
[7] Rader Ch.R., Abdou-Sabet S.: “Two-Phase Elastomeric Alloys” in” Thermoplastic Elastomers from Rubber- Plastic Blends” (editor De S.K., Bhowmick A.K.), Ellis Horwood, New York 1990, p. 159.
[8] Grady B.P., Cooper S.L., Robertson Ch.G.: ”Thermoplastic Elastomers” in ”Science and Technology of Rubber” (editor Mark J.E., Erman B., Eirich F.R.), Academic Press, San Diego, New York 2013, p. 591. https://doi.org/10.1016/B978-0-12-394584-6.00013-3
[9] Rzymski W.M., Radush H.J.: Polimery 2002, 47(4), 229.
[10] Steube M., Johann T., Barent R.D. et al.: Progress in Polymer Science 2022, 124, 101488. https://doi.org/10.1016/j.progpolymsci.2021.101488
[11] Basu D., Banerjee S.S., Debnath S.Ch. et al.: Polymer 2023, 212, 123309. https://doi.org/10.1016/j.polymer.2020.123309
[12] Mark J.E., Erman B., Roland M.: “The science and technology of rubber”, Elsevier Academic Press, Amsterdam, Boston 2013, p. 591. https://doi.org/10.1016/B978-0-12-394584-6.00013-3
[13] McKeen L.W.: “Thermoplastic Elastomers” in “Fatigue and tribological properties of plastics and elastomers”, William Andrew, Oxford 2016, p. 245. https://doi.org/10.1016/B978-0-08-096450-8.00010-7
[14] Fakirov S.: “Poly(Ether Ester) Thermoplastic Elatomers: Phase and Deformation Behavior on the Nano- and Microlevel” in “Handbook of Condensation Thermoplastic Elastomers”, Wiley‐VCH, Weinheim 2005, p. 167. https://doi.org/10.1002/3527606610.ch6
[15] Ukielski R.: Polymer 2000, 41(5), 1893. https://doi.org/10.1016/S0032-3861(99)00304-3
[16] Leibler L.: Macromolecules 1980, 13(6), 1602. https://doi.org/10.1021/ma60078a047
[17] Desper R.C., Bryne C.A., Li Y. et al.: Macromolecules 1995, 28(12), 4213. https://doi.org/10.1021/ma00116a024
[18] Koberstein J.T., Russel T.P.: Macromolecules 1986, 19(3), 714. https://doi.org/10.1021/ma00157a039
[19] Elwell M.J., Ryan A.J., Gruenbauer H.J.M. et al.: Macromolecules 1996, 29(8), 2960. https://doi.org/10.1021/ma9511208
[20] van der Schuur M.J., van der Heide E., Feijen J. et al.: Polymer 2004, 48(8), 2721. https://doi.org/10.1016/j.polymer.2004.02.016
[21] van der Schuur M.J., de Boer J., Gaymans R.J.: Polymer 2005, 46(22), 9243. https://doi.org/10.1016/j.polymer.2005.07.041
[22] van der Schuur M.J., Gaymans R.J.: Journal of Polymer Science Part A: Polymer Chemistry 2006, 44(16), 4769. https://doi.org/10.1002/pola.21587
[23] Ramon J., Saez V., Gomes F. et al.: Macromolecular Symposia 2018, 380(1), 1800065. https://doi.org/10.1002/masy.201800065
[24] Xiao R.Z., Zeng, Z.W., Zhou, G.L. et al.: International Journal of Nanomedicine 2010, 5, 1057. https://doi.org/10.2147/IJN.S14912
[25] Nguyen T.H., Petchsuk A., Tangboriboonrat P. et al.: Advanced Materials Research 2010, 93–94, 198. https://doi.org/10.4028/AMR.93-94.198
[26] Wang Y., Wu H., Wang Z. et al.: Polymers 2019, 11(6), 965. https://doi.org/10.3390/polym11060965
[27] Navarro L., Minari R.J., Vaillard S.E.: RSC Advances, 2019, 9, 482. https://doi.org/10.1039/C8RA09336A
[28] van der Schuur M., Feijen J., Gaymans R.J.: Polymer 2005, 46(13), 4584. https://doi.org/10.1016/j.polymer.2005.02.074
[29] Armstrong S., Freeman B., Hiltner A. et al.: Polymer 2012, 53(6), 1383. https://doi.org/10.1016/j.polymer.2012.01.037
[30] Szymczyk A., Nastalczyk J., Sablong R.J. et al.: Polymers for Advanced Technologies 2011, 22(1), 72. https://doi.org/10.1002/pat.1858
[31] Paszkiewicz S., Szymczyk A., Pawlikowska D. et al.: RSC Advances 2017, 7, 41745. https://doi.org/10.1039/C7RA07172H
[32] Sakurai S., Nokuwa S., Morimoto M. et al.: Polymer 1994, 35(3), 532. https://doi.org/10.1016/0032-3861(94)90507-X
[33] Ercan N., Durmus A.: Journal of Applied Polymer Science 2022, 139(26), e52458. https://doi.org/10.1002/app.52458
[34] Bai L., Hong Z., Wang D. et al.: Polymer 2010, 51(23), 5604. https://doi.org/10.1016/j.polymer.2010.09.038
[35] Jiang J., Tang Q., Pan X. et al.: Polymers 2021, 13(16), 2645. https://doi.org/10.3390/polym13162645
[36] van Hutten P.F., Walch E., Veeken A.H.M. et al.: Polymer 1990, 31(3), 524. https://doi.org/10.1016/0032-3861(90)90397-H
[37] Mahallati P., Arefazar A., Naderi G.: International Polymer Processing 2010, 25(2), 132. https://doi.org/10.3139/217.2311
[38] Zolali A.M., Heshmati V., Favis B.D.: Macromolecules 2017, 50(1), 264. https://doi.org/10.1021/acs.macromol.6b02310
[39] Kucera L.R., Brei M.R., Storey R.F.: Polymer 2013, 54(15), 3796. https://doi.org/10.1016/j.polymer.2013.05.041
[40] Rault J., le Huy H.M.: Journal of Macromolecular Science, Part B 1996, 35, 89. https://doi.org/10.1080/00222349608220376
[41] Rached R., Hoppe S., Jonquieres A. et al.: Journal of Applied Polymer Science 2006, 102(3), 2818. https://doi.org/10.1002/app.24547
[42] Rokicka J., Wilpiszewska K., Janik J. et al.: Materials 2021, 14(24), 7720. https://doi.org/10.3390/ma14247720
[43] Scalfani V.F., Turner, C.H., Rupar P.A. et al.: Journal of Chemical Education 2015, 92(11), 1866. https://doi.org/10.1021/acs.jchemed.5b00375
[44] Tseng Y.C., Darling S.B.: Polymers 2010, 2(4), 470. https://doi.org/10.3390/polym2040470
[45] Botiz I., Darling S.B.: Materials Today 2010, 13(5), 42. https://doi.org/10.1016/S1369-7021(10)70083-3
[46] Ahn J.H., Zin W.C.: Macromolecules 2000, 33(2), 641. https://doi.org/10.1021/ma9912812
[47] Cho J.: Polymer 2016, 97, 589. https://doi.org/10.1016/j.polymer.2016.05.068
[48] Robbins S.W., Beaucage P.A., Sai H. et al.: Science Advances 2016, 2(1), e150111. https://doi.org/10.1126/sciadv.1501119
[49] Xu Z., Lin J., Zhang Q. et al.: Polymer Chemistry 2016, 7, 3783. https://doi.org/10.1039/C6PY00535G
[50] Deng Y., Wei J., Sun Z. et al.: Chemical Society Reviews 2013, 42, 4054. https://doi.org/10.1039/C2CS35426H
[51] Li M., Liu Y., Bansil R.: The Journal of Chemical Physics 2010, 133, 084905. https://doi.org/10.1063/1.3473067
[52] Rokicka J., Ukielski R.: „Synthesis and Properties of Multiblock Terpoly(Ester-Aliphatic-Amide) and Terpoly(Ester-Ether-Amide) Thermoplastic Elastomers with Various Chemical Compositions of Ester Block” in „Thermoplastic Elastomers – Synthesis and Applications” (editor Das Ch.K.), In Tech, London 2014, p. 21. https://doi.org/10.5772/61215
[53] Xie M., Camberlin Y.: Die Makromolekulare Chemie 1986, 187(2), 383. https://doi.org/10.1002/macp.1986.021870218
[54] Stevenson J.C., Cooper S.L.: Macromolecules 1988, 21(5), 1309. https://doi.org/10.1021/ma00183a022
[55] Bornschlegl E., Goldbach G., Meyer K.: “Structure and properties of segmented polyamides” in “Frontiers in Polymer Science. Progress in Colloid and Polymer Science” (Editor Wilke E.), Springer Heidelberg, Berlin 1985, p. 119. https://doi.org/10.1007/BFb0114023
[56] van Krevelen D.W., te Nijehuis K.: “Properties of Polymers”, Elsevier, Amsterdam 2009, p. 129. [57] Ukielski R.: Polimery 1996, 41, 286.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-283fea9a-49c0-4aa2-9d7b-687682a01adb