Influence of the ester block polymerization degree on the structure and properties of ester-ether-amide block terpolymers

Rokicka, Joanna; Janik, Jolanta; Schmidt, Beata; Wilpiszewska, Katarzyna

doi:10.14314/polimery.2024.2.1

Artykuł - szczegóły

Tytuł artykułu

Influence of the ester block polymerization degree on the structure and properties of ester-ether-amide block terpolymers

Autorzy

Rokicka Joanna , Janik Jolanta , Schmidt Beata , Wilpiszewska Katarzyna

Treść / Zawartość

Pełne teksty:

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Identyfikatory

DOI

10.14314/polimery.2024.2.1

Warianty tytułu

Wpływ stopnia polimeryzacji bloku estrowego na strukturę oraz właściwości blokowych terpolimerów estrowo-eterowo-amidowych

Języki publikacji

Abstrakty

New multi-block thermoplastic elastomers (TPEEA) were obtained, consisting of a crystalline amide block (domains), an amorphous ether block (continuous phase) and an ester block with a variable degree of polymerization, which acts as a compatibilizer. The presence of large interfacial areas was observed. It was found that ester blocks with a molecular weight <600 g/mol mix with other blocks, modifying the phases that constitute them and stabilizing the micro- and nanophase structure of the entire system. Short ester blocks act as nucleation precursors, and in the hard phase they have plasticizing properties.

Otrzymano nowe wieloblokowe elastomery termoplastyczne (TPEEA), składające się z krystalicznego bloku amidowego (domeny), amorficznego bloku eterowego (faza ciągła) oraz bloku estrowego o zmiennym stopniu polimeryzacji, który pełni funkcję kompatybilizatora. Zaobserwowano obecność dużych obszarów międzyfazowych. Stwierdzono, że bloki estrowe o masie cząsteczkowej <600 g/mol mieszają się z innymi blokami, modyfikując tworzące je fazy i stabilizując strukturę mikro- i nanofazową całego układu. Krótkie bloki estrowe pełnią funkcję prekursorów zarodkowania, a w fazie twardej mają właściwości uplastyczniające.

Słowa kluczowe

thermoplastic elastomers phase structure block copolymers

elastomery termoplastyczne struktura fazowa kopolimery blokowe

Wydawca

Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej

Czasopismo

Polimery

Rocznik

2024

Tom

Vol. 69, nr 2

Strony

75--85

Opis fizyczny

Bibliogr. 57 poz., rys., tab., wykr.

Twórcy

autor

Rokicka Joanna

joanna.rokicka@zut.edu.pl

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0002-2003-6372

autor

Janik Jolanta

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0002-8094-8509

autor

Schmidt Beata

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0001-6274-2278

autor

Wilpiszewska Katarzyna

Department of Organic Chemical Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland.

https://orcid.org/0000-0003-2756-3471

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Bibliografia

Identyfikator YADDA

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