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Abstrakty
Recently, many research efforts have been made to reduce the magnesium content in the phosphate concentrate to meet the requirement for phosphoric acid production and other applications. A bioprocessing technique is among these efforts. However, this paper was devoted to study the use of cellulase enzyme as a new phosphate depressant during fatty acid flotation of a calcareous phosphate rock. The flotation behavior of collophane and dolomite as single minerals using oleic acid as a collector and cellulase enzyme as the phosphate depressant was investigated in details. The results from single mineral flotation tests were discussed based on FTIR and zeta potential measurements to find out the mechanism of cellulase depression of phosphate. The findings from the single minerals tests were used to develop a selective flotation process for recovery of phosphate minerals from the natural phosphate ore. The flotation experiments were carried out to apply this new process using the calcareous phosphate ore. Under the optimum flotation conditions, 0.04% cellulase and 0.5 mM oleic acid, a phosphate concentrate containing 0.89% MgO with a P2O5 recovery of 75% was obtained from the phosphate ore containing 2.2% MgO.
Słowa kluczowe
Rocznik
Tom
Strony
1092--1104
Opis fizyczny
Bibliogr. 41 poz., rys., tab.
Twórcy
autor
- Central Metallurgical R&D Institute, P.O. Box 87, Helwan-El-Tibbin, El-Felezat Street, Cairo, Egypt
autor
- Central Metallurgical R&D Institute, P.O. Box 87, Helwan-El-Tibbin, El-Felezat Street, Cairo, Egypt
autor
- Central Metallurgical R&D Institute, P.O. Box 87, Helwan-El-Tibbin, El-Felezat Street, Cairo, Egypt
Bibliografia
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- ABOUZEID A.Z., NEGM A.T., EL-GILLANI D.A., 2009, Upgrading of calcareous phosphate ores by flotation: Effect of ore characteristics, International Journal of Mineral Processing, 90, 81–89.
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- AHMED Y., ABDEL-KHALEK M.A, FADE, M., MILLER J.D., WISNIEWSKA S., WANG X., 2001, Fatty acid flotation of calcareous phosphate rock using enzymes for a selective separation, Presented at the Engineering Foundation Conference: Beneficiation of Phosphate III, Florida, December 2-7.
- AHMED Y., REHEEM F.H.A., 2012, Some physico-chemical aspects related to the deinking Process using xylenase as a surface modifier, Elixir Applied Chemistry, 48, 9498-9502.
- AL-FARISS T.F., ARAFAT Y., ABD EL-ALEEM F.A.E., EL-MIDANY A.A., 2014, Investigating sodium sulphate as a phosphate depressant in acidic media, Separation and Purification Technology, 124, 163–169.
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- ANTONY A., 2009, Novel technique for the separation of dolomite from phosphate rock, M.Sc. Thesis, University of Florida.
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- DOS SANTOS M.A., SANTANAR C., CAPPONI F., ATAIDE C.H., BARROZO M.A.S., 2012, Influence of the water composition on the selectivity of apatite flotation, Separation Science and Technology, 47(4), 606-612.
- DUBEL J., 1990, Mycobacterium phlei as flocculating agent for mineral suspensions, MMRI report, University of Nevada, Reno, U.S.A.
- EL-MAHDY A.M., EL-MOFTY S.E., ABDEL-KHALEK M.A., ABDEL-KHALEK, N.A., EL-MIDANY A.A., 2013, Bacterially induced phosphate–dolomite separation using amphoteric collector, Separation and Purification Technology, 102, 94–102.
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- PRASAD M., MAJUNDER A.K., RAO T.C., 2000, Reverse flotation of sedimentary calcareous/dolomitic rock phosphate ore-An overview, Minerals and Metallurgical Processing, 17, 1, 49-55.
- PREDALI J.J., 1969, Flotation of carbonates with salt of fatty acids. Role of pH and the akyl chain, Trans IMM, 78, 140c-147c.
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- SIS H., CHANDER S., 2003, Reagents used in the flotation of phosphate ores: a critical review, Minerals Engineering, 16 (7), 577–585.
- SMITH R.W., MIETTINEN M., 2006, Microorganisms in flotation and flocculation: Future technology or laboratory curiosity, Minerals Engineering, 19(6–8), 548–553.
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- SOMASUNDARAN P., 1999, Adsorption of starch and oleate and interaction between them on calcite in aq. Solns., Journal of Colloid and Interface Science, New York, 31, (4), 557.
- VIANA P.R.M., SOUZA H.S., 1988, The use of corn grits as a depressant for the flotation of quartz in hematite ore, In Proceeding of the 2nd Latin- American Congress on Froth Flotation, Development in mineral Processing, 9. Edited by Castro, S.H.F. and Alvarez, J.M., Amsterdam: Elsevier, 233-244.
- WANG X., NGUYEN A.V., MILLER J.D., 2006, Selective attachment and spreading of hydroxamic acid–alcohol collector mixtures in phosphate flotation, International Journal of Mineral Processing, 78 (2), 122–130.
- YASUTAKA K., TAKATO Y., TAKASHI K., KOHSUKE M., HIROMI Y., 2011, Enhancement in adsorption and catalytic activity of enzymes immobilized on phosphorus- and calcium-modified MCM-41, Journal of Physical Chemistry B, 115 (34), 10335–10345.
- ZHENG X., SMITH R.W., 1997, Dolomite depressants in the flotation of apatite and collophane, Minerals Engineering, 10(5), 537-545.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-27236b08-33ab-4f63-9b2b-cd9ab05d6034