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Synthesis and characterization of polymer biocomposites with lignin

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A new method of synthesis of polymer biocomposites with lignin using the photopolymerization method has been proposed. Bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BAGDA) was used as a main monomer and 2-ethylhexyl acrylate (EHA) as a reactive diluent. Lignin (L) was applied as an eco-filler. The influence of the increasing lignin content (0; 2.5; 5; 10; 20% w/w) on the properties of the obtained biocomposites was investigated. The chemical structure of biomaterials was investigated by the attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FT-IR) method while the thermal properties were studied by the differential scanning calorimetry (DSC) and thermogravimetric analysis (TG/DTG). Their hardness was measured by the Shore D method. Incorporation of the biopolymer into the structure of polymer composites could be a promising alternative to synthetic materials and would contribute to better lignin utilization. The results of the study are of practical importance in prospective applications of biocomposites with lignin.
Rocznik
Strony
1375--1381
Opis fizyczny
Bibliogr. 23 poz., rys., tab., wykr., wz.
Twórcy
  • Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Polymer Chemistry, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland
  • Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Polymer Chemistry, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland
Bibliografia
  • BORYSIAK, S., KLAPISZEWSKI, Ł., BULA, K., JESIONOWSKI, T., 2016. Nucleationability of advanced functional silica/lignin hybrid fillers in polypropylene composites. J. Therm. Anal. Calorim. 126, 251-262.
  • BULA, K., KLAPISZEWSKI, Ł., JESIONOWSKI, T., 2015. A novel functional silica/lignin hybrid material as a potential bio-based polypropylene filler. Polym. Compos. 36, 913-922.
  • GHOZALI, M., TRIWULANDARI, E., HARYONO, A., YUANITA, E., 2017. Effect of lignin on morphology, biodegradability, mechanical and thermal properties of low linear density polyethylene/lignin biocomposites. IOP Conf. Series: Materials Science and Engineering 223, 012022.
  • GOLISZEK, M., PODKOŚCIELNA, B., SEVASTYANOVA, O., FILA, K., CHABROS, A., PĄCZKOWSKI, P., 2019. Investigation of accelerated aging of lignin-containing polymer materials. Int. J. Biol. Macromol. 123, 910-922.
  • GONZÁLEZ, G., FERNÁNDEZ-FRANCOS, X., SERRA, À., SANGERMANO, M., RAMIS, X., 2015. Environmentally-friendly processing of thermosets by two-stage sequential aza-Michael addition and free-radical polymerization of amine–acrylate mixtures. Polym.Chem. 6, 6987-6997.
  • GRZĄBKA-ZASADZIŃSKA, A., KLAPIZEWSKI, Ł., BORYSIAK, S., JESIONOWSKI, T., 2018. Thermal and mechanical properties of silica–lignin/polylactide composites subjected to biodegradation. Materials 11, 1-14.
  • IKEDA, Y., PHAKKEEREE, T., JUNKONG, P., YOKOHAMA, H., PHINYOCHEEP, P., KITANO, R., KATO, A., 2017. Reinforcing biofiller “lignin” for high performance green natural rubber nanocomposites. RSC Adv. 7, 5222-5231.
  • JIANG, X., OUYANG, Q., LIU, D., HUANG, J., MA, H., CHEN, Y., WANG, X., SUN, W., 2018. Preparation of low-cost carbon fiber precursors from blends of wheat straw lignin and commercial textile-grade polyacrylonitrile (PAN). Holzforschung 72, 727-734.
  • KLAPISZEWSKI, Ł., BULA, K., DOBROWOLSKA, A., CZACZYK, K., JESIONOWSKI, T., 2019. A high-density polyethylene container based on ZnO/lignin dual fillers with potential antimicrobial activity. Polym. Test. 73, 51-59.
  • KLAPISZEWSKI, Ł., MADRAWSKA, M., JESIONOWSKI, T., 2012. Preparation and characterisation of hydrated silica/lignin biocomposites. Physicochem. Probl. Miner. Process. 48, 463-473.
  • KLAPISZEWSKI, Ł., NOWACKA, M., MILCZAREK, G., JESIONOWSKI, T., 2013. Physicochemical and electrokinetic properties of silica/lignin biocomposites. Carbohydr. Polym. 94, 345-355.
  • KLAPISZEWSKI, Ł., TOMASZEWSKA, J., SKÓRCZEWSKA, K., JESIONOWSKI, T., 2017. Preparation and characterization of eco-friendly Mg(OH)₂/lignin hybrid material and its use as a functional filler for poly(vinyl chloride). Polymers 9, 258-276.
  • LORA, J. H., GLASSER, W.G., 2002. Recent industrial applications of lignin: a sustainable alternative to nonrenewable materials. J. Polym. Environ. 10, 39-48.
  • MOHANTY, A.K., MISRA, M., DRZAL, L.T., 2002. Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J. Polym. Environ. 10, 19-26.
  • RAMOS, R. R. F., SIQUEIRA, D. D., WELLEN, R. M. R., LEITE, I. F., GLENN, G. M., MEDEIROS, E. S., 2019. Development of green composites based on polypropylene and corncob agricultural residue. J. Polym. Environ. 27, 1677–1685.
  • SOBIESIAK, M., PODKOŚCIELNA, B., SEVASTYANOVA, O., 2017. Thermal degradation behavior of lignin-modified porous styrene-divinylbenzene and styrene-bisphenol A glycerolate diacrylate copolymer microspheres. J. Anal. Appl. Pyrolysis 123, 364-375.
  • SPIRIDON, I., TANASE, C. E., 2018. Design, characterization and preliminary biological evaluation of new lignin-PLA biocomposites. Int. J. Biol. Macromol. 114, 855-863.
  • STEWART, D., 2008. Lignin as a base material for materials applications: Chemistry, application and economics. Ind. Crop. Prod. 27, 202-207.
  • THAKUR, V. K., THAKUR, M. K., RAGHAVAN, P., KESSLER, M. R., 2014. Progress in green polymer composites from lignin for multifunctional applications: a review. ACS Sustain. Chem. Eng. 2, 1072-1092.
  • THANGAVEL, G., MOHANTY, S., NAYAK, S.K., 2015. A review of the recent developments in biocomposites based on natural fibres and their application perspectives.Compos. Part A Appl. Sci. Manuf. 77, 1-25.
  • UPTON, B. M., KASKO, A. M., 2016. Strategies for the conversion of lignin to high-value polymeric materials: Review and perspective. Chem. Rev. 116, 2275-2306.
  • VANHOLME, R., DEMEDTS, B., MORREEL, K., RALPH, J., BOERJAN, W., 2010. Lignin biosynthesis and structure. Plant Physiol. 153, 895-905.
  • YAGCI, Y., JOCKUSCH, S., TURRO, N.J., 2010. Photoinitiated polymerization: Advances, challenges, and opportunities. Macromolecules 43, 6245-6260
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-26792ef8-dd91-48e3-8efb-e84338d51b13
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