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In this work, the important scientific and technical problem of creating multifunctional composite materials for shipbuilding and ocean engineering was solved. The work aimed to study the thermal deformation processes of sintering glass microspheres to obtain lightweight glass composites with a cellular structure that provides positive buoyancy and sound insulation properties. For this purpose, glass microspheres of Na2O‒SiO2 and Na2O‒B2O3‒SiO2 composition with a dispersion of 10 to 60 μm were used as raw materials. They were sintered to form a closed, porous structure. The theoretical substantiation of technological parameters is based on the concepts of solid state and glassy state chemistry and physicochemical concepts of glass softening processes. The process of hot-pressing glass microspheres without plasticisers and additives was investigated. The author’s own laboratory equipment was used for the experiments. The sintering intensity was determined from the results of shrinkage processes; the kinetic shrinkage curves were constructed in semilogarithmic coordinates. The glass composite samples were examined by optical and electron microscopy. As a criterion, the storage of spherical microspheres under the influence of simultaneous heating to 700 °C with the application of pressure in the range of 0,5 to 1,5 MPa was chosen. It was established that the formation of a predominantly closed-porous structure of glass composites with a density of 350...600 kg/m3 occurs by the mechanisms of viscous glass phase flow through liquefaction processes in the walls of microspheres. At the same time, shrinkage processes in the linear direction reach up to 50%. The acoustic properties were investigated by measuring the differences in sound pressure levels in octave frequency bands using a Kundt pipe. The water absorption of the glass composite samples was determined at hydrostatic pressures up to 20 MPa. The research results were compared with the characteristics of analogue composites, such as syntactic foams and foam glass. The developed materials can be used in the design and manufacture of technical equipment for research and maintenance of underwater infrastructure. The prospects for further research are related to the feasibility study and marketing research on implementing the developed glass composites.
Czasopismo
Rocznik
Tom
Strony
174--180
Opis fizyczny
Bibliogr. 23 poz., rys.
Twórcy
autor
- Department of Information Control Systems and Technologies Admiral Makarov National University of Shipbuilding, Mykolaiv, Ukraine
autor
- Department of Information Control Systems and Technologies Admiral Makarov National University of Shipbuilding, Mykolaiv, Ukraine
autor
- Kherson Branch of the Admiral Makarov National University of Shipbuilding, Kherson, Ukraine
Bibliografia
- 1. Transporting Oil by Sea. In Planète Energies. January 14, 2015, https://www.planete-energies.com/en/media/article/ transporting-oil-sea.
- 2. B.Wetzel. Oil in Motion: How Crude Oil Transportation Works. In Breakthrough group. November 1, 2019, https://www.breakthroughfuel.com/blog/ oil-in-motion-visibility-into-crude-oil-transportation/.
- 3. V. Kobolev. The Black Sea’s oil and gas potential: the reality and prospects of drilling a unique ultra-deep well on Zmiiny Island. In Mining of Mineral Deposits 2017. November 1, 2017. Retrieved from https://oil-gas.com.ua.
- 4. O. Lukin, I. Gafych, G. Goncharov, V. Makogon and T. Prygarina. ‘Hydrocarbon potential in entrails of the earth of Ukraine and main trend of its development’, Mineral Resources of Ukraine, vol. 11, no. 4, pp. 28 – 38, 2020, doi. org/10.31996/mru.2020.4.28-38.
- 5. Offshore Oil and Gas. In Planete Energies. November 8, 2015, https://www.planete-energies.com/en/media/article/ offshore-oil-and-gas-production.
- 6. M. Xinhua, X. Jun. ‘The progress and prospects of shale gas exploration and development in southern Sichuan Basin. SW China - Petroleum exploration and development’, Online English edition of the Chinese language journal. vol. 45, no. 1, 2018, doi.org/10.1016/S1876-3804(18)30018-1.
- 7. G. Zhang, H. Qu, G. Chen, C. Zhao, F. Zhang, H. Yang, Z. Zhao and M. Ma. ‘Giant discoveries of oil and gas fields in global deep waters in the past 40 years and the prospect of exploration’, Natural Gas Geoscience, vol. 28, no. 4, pp. 1 – 28, 2019, doi: 10.1016/j.jnggs.2019.03.002.
- 8. Transportation of oil. In Energy Education. June 2014, https:// energyeducation.ca/encyclopedia/ Transportation_of_oil.
- 9. A. Bahadori. Thermal Insulation Handbook for the Oil, Gas, and Petrochemical Industries. 1st Edition, School of Environment, Science & Engineering, Southern Cross University, Lismore, NSW, Australia, 2014. doi.org/10.1016/ C2013-0-13424-1.
- 10. Deep-sea mining for rare metals will destroy ecosystems, say scientists. In The Guardian, March 2023, https://www. theguardian.com/environment/2023/mar/26/deep-seamining- for-rare-metals-will-destroy-ecosystems-sayscientists.
- 11. С. В. Копійка, І. О. Захарова та О. Г. Єгоров. ‘Обґрунтування раціональної конструкції блоків плавучості підводних апаратів’ (S. Kopiyka, I. Zakharova and A. Egorov. ‘Substantiation of the rational design of buoyancy blocks of under-water vehicles’), Збірник наукових праць Національного університету кораблебудування. vol. 5, no. 2, pp. 28 – 32, 2017, doi. org/10.15589/jnn20170204.
- 12. V. Kumar. ‘Buoyancy materials for marine instrumentation”, National Institute of Oceanography, Goa, India, 2015, doi. org/10.13140/RG.2.1.2228.4964.
- 13. G. J. Meyer. Low-density polyurethane foam for subsea buoyancy systems. In Sea technology. August 5, 2015, https://sea-technology.com/feature-article-low-densitypolyurethane-foam-for-subsea-buoyancy-systems.
- 14. D. Choqueuse, P. Davies, D. Perreux, L.Sohier and J-Y Cognard. ‘Mechanical behaviour of syntactic foams for deep sea thermally insulated pipeline’, Applied Mechanics and Materials, vol. 24 - 25, pp. 97 – 102, 2010, doi.org/10.4028/ www.scientific.net/AMM.24-25.97.
- 15. Н. Соломонюк. Удосконалення конструкції підводного апарату блоками плавучості підвищеної теплостійкості. (N. Solomoniuk. Improvement of the underwater vehicle design by increased heat resistance buoyancy blocks) Ph.D. thesis, Admiral Makarov National University of Shipbuilding, Ukraine, 2012.
- 16. L. Smart and E. Moore. Solid state chemistry. In Taylor & Francis Group. 2005, https://www.uobabylon.edu.iq/ eprints/publication_10_10256_250.pdf.
- 17. J. Dyre. ’Colloquium: The glass transition and elastic models of glass-forming liquids’, American Physical Society, 2006, doi.org/10.1103/RevModPhys.78.953.
- 18. Y. Kazymyrenko, ‘Installation for manufacturing of powdered products’. Utility model patent of Ukraine UA01414197, December 30, 2014.
- 19. W. Sikorski. Acoustic Emission - Research and Applications. InTech, pp.225, 2013.
- 20. Flexible cellular polymeric materials - Polyurethane foam for laminate use — Specification, ISO 6915:2019, 04 - 2020. Available: https://www.iso.org/ru/standard/77358.html.
- 21. Rigid cellular plastics. Thermal insulation products for buildings. Specifications. ISO 4898:2018, 03-2018.
- 22. W. Wong-Ng. ‘Phase Equilibria and Crystallography of Ceramic Oxides’, Journal of Research of the National Institute of Standards and Technology. 2011, doi. org/10.6028/jres.106.059.
- 23. J. Safarian, G. Tranell and M. Tangstad. ‘Thermodynamic and kinetic behaviour of B and Na through the contact of B-doped silicon with Na2O-SiO2 slags’, Metallurgical and Materials Transactions. 2013, doi.org/10.1007/ s11663-013-9823-y.
Uwagi
PL
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-25dda67f-df96-4213-aef5-806bf21019a4