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Tytuł artykułu

Problems of Protection of Urban Areas from Radionuclides Strontium-90 and Caesium-137 after Technological Disasters

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The methods of decontamination of radionuclides from soils are considered. The literature focuses on fixing radionuclides in soils and creating geochemical barriers that it is prevent the spread of pollution. The main disadvantage of these methods is excluding the possibility of building a territory. It is needed to clean up the area to the sanitary and hygienic requirements for further use and then it is desirable to fix the residual activity. The conducted analysis of forms of radionuclides fixation in soils and mechanics of this fixation, therewith revealed that Cs-137 fixed more strongly on mineral components of soil, than Sr-90, which is mainly in the acid-soluble and exchangeable form, and, as a consequence, passes into the liquid phase during soil deactivation more easily. Contaminated soil deactivation in the urbanized territory is possible by washing it by ferric chloride solution at a concentration 0.02–0.05 M and with an equimolar addition of an ammonium chloride. Therewith, most efficient methods, which use in-situ conditions, are heap and convection leaching technologies with treatment degree, which is not less than 80%. At the same time, the most efficient methods which use in-situ conditions are heap and the convection leaching. The hardware-technological scheme of a convection leaching is presented. It is worth to note that ammonium salts additions slightly rise coefficient of treatment from Sr-90. Because ammonium salts are inexpensive, their additions allow to obtain significant economic benefits due to decreasing ferric chloride consumption, which is more valuable, and waste water volume reduction.
Rocznik
Strony
97--103
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
  • Saint Petersburg Mining University, Department of General and Physical Chemistry, 21st Line 2, 199106 Saint Petersburg, Russia
autor
  • Saint Petersburg Mining University, Department of General and Physical Chemistry, 21st Line 2, 199106 Saint Petersburg, Russia
autor
  • Saint Petersburg Mining University, Department of General and Physical Chemistry, 21st Line 2, 199106 Saint Petersburg, Russia
autor
  • Saint Petersburg Mining University, Department of General and Physical Chemistry, 21st Line 2, 199106 Saint Petersburg, Russia
Bibliografia
  • 1. Ambashta R., Sillanpää M. Membrane purification in radioactive waste management: a short review. Journal of Environmental Radioactivity,105,76–84.
  • 2. Bondar Yu.I., Zabrodsky V.N. 2001. Sorbtsiya ionnykh form 90Sr i 137Cs razlichnymi tipami pochv (Sorption of the ionic forms of 90Sr and 137Cs by different types of soils). Radiokhimiya, 43 (6), 566–568.
  • 3. Chirkst D.E., Litvinova T.E., Cheremisina O.V., Streleckaja M.I. 2001. Opytnaja tehnologija dezaktivacii gruntov, zagrjaznennyh radionuklidom Sr-90 / D (Experienced technology of decontamination of soils contaminated by radionuclide Sr-90). Radiohimija, 43(5), 475–478.
  • 4. Chirkst D.E., Litvinova T.E., Cheremisina O.V. 2002. Povedenie 137Cs v processe dezaktivacii grunta 5-go kvartala Vasil’evskogo ostrova (The behavior of 137Cs in the process of decontamination of the soil of the 5th quarter of Vasilievsky island). Radiohimija, 44( 4), 378–381.
  • 5. Choppin G., Liljenzin J-O., Rydberg J. 2002. Behavior of Radionuclides in the Environment. Radiochemistry and Nuclear Chemistry (Third Edition), 22, 642–673.
  • 6. Chuveleva E.A., Firsova L.A. Et al. Radiokhimiya, 1996, 38 (6), 554–557.
  • 7. Dibrov I.A. 2000. Opytnaja tehnologija ochistki gruntov ot zagrjaznenija radionuklidami((Experienced technology of cleaning soil from pollution by radionuclides). Jekologija i razvitie stran Baltijskogo regiona. 121 – 126.
  • 8. Grivé M., Duro L., Colàs E., Giffaut E. 2015. Thermodynamic data selection applied to radionuclides and chemotoxic elements: An overview of the ThermoChimie-TDB. Applied Geochemistry, 55, 85–94.
  • 9. Konoplev A.V., Comans R.N.J., Hilton J. 1996. The Radiolodical Consequences of the Chernobyl Accident, 121–135.
  • 10. Kuznecov V.A., Generalova V.A. 2000. Issledovanie sorbcionnyh svojstv gidroksidov zheleza, marganca, titana, aljuminija i kremnija po otnosheniju k Sr-90 i Cs-137 (Study of sorption properties of the hydroxides of iron, manganese, titanium, aluminum and silicon in relation to Sr-90 and Cs-137). Radiohimija, 42( 2), 154–157.
  • 11. Lisin S.K., Simirskaya G.P., Simirsky Yu.N., Rodionov Yu.F., Shubko V.М. 1993. Formy nakhozhdeniya Cs-137 i Sr-90 v pochvakh Bryanskoj oblasti (Forms of the presence of Cs-137 and Sr- 90 in the soils of the Bryansk region). Radiatsiya i risk, 3, 129–132.
  • 12. Mao X, Jiang R., Yu J. 2015. Use of surfactants for the remediation of contaminated soils: A review. Journal of Hazardous Materials, 285, 419–435.
  • 13. Martjushov V.V., Spirin D.A., Bazilev V.V., Fedorova T.A. 1995. Sostojanie radionuklidov v pochvah Vostochno-Ural’skogo radioaktivnogo sleda (The state of radionuclides in soils of the Eastern-Urals radioactive trace). Jekologija, 2, 110–113.
  • 14. Newsome L., Morris K., Lloyd J.R. 2014. The biogeochemistry and bioremediation of uranium and other priority radionuclides. Chemical Geology, 363, 164–184.
  • 15. Pavlotskaya F.I. 1974. Migratsiya radioaktivnykh produktov global’nykh vypadenij v pochvakh (Migration of radioactive products of global fallout in soils). Moscow: Atomizdat
  • 16. Rogozin Yu.M. Et al. Radiokhimiya, 1993, 35(2), 149–153.
  • 17. Sawhney B.L. 1972. Selective sorpsion and fixation of cations by clay minerals: a review. Clays and Clay Minerals, 20, 93–100.
  • 18. Shi C., Fernández-Jiménez A. 2006. Stabilization/solidification of hazardous and radioactive wastes with alkali-activated cements. ournal of Hazardous Materials, 137(3), 1656–1663.
  • 19. Sawhney B.L.1972. Selective sorpsion and fixation of cations by clay minerals: a review. Clays and Clay Minerals, 20, 93–100.
  • 20. Titlyanova A.A.1964. Pochvovedenie, 12, 88–94.
  • 21. Varshal G.M., Koshheeva N.Ja., Veljuhanova T.K., Chhetija D.N., Tjutjunnik O.A., Grinevskaja Zh.M. 1996. Sorbcija tjazhelyh metallov i izotopnyh nositelej dolgozhivushhih radionuklidov na G.K.: Soobshhenie 1. Sorbcija cezija (I), stroncija(II), cerija (III), rutenija (IV) na guminovoj kislote (Sorption of heavy metals and isotopic carriers of long-lived radionuclides.) Geohimija, 11, 1107–1112.
  • 22. Virchenko E.P., Agapkina G.I. 1993. Radionuklidorganicheskie soedinenija v pochvah zony vlijanija ChAJeS (Radionuclide-organic compounds in the soils of the zone of influence of Chernobyl). Pochvovedenie, 1, 13–17.
  • 23. Zaharova E.V., Kajmin E.P., Darskaja E.N., Menjajlo K.A., Zubkov A.A. 2001. Rol’ fiziko-himicheskih processov pri dolgovremennom hranenii zhidkih RAO v glubinnyh plastah-kollektorah (The role of physico-chemical processes during long-term storage of liquid waste in deep reservoirs). Radiohimija, 43(4), 213–221.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-258672f6-4c6c-4374-a6a6-f6cd652192de
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