Silica-Magnetite Composite as an Eco-Friendly Adsorbent for Aqueous Tetracycline Removal – Kinetic and Isotherm Studies

• Autorzy: Karina Sofyatuddin , Perdana Adli Waliul , Prajaputra Vicky , Isnaini Nadia , Nuufus Putri Hayyatun , Bismi Audia

Identyfikatory

DOI

10.12912/27197050/174225

• Języki publikacji: EN

Abstrakty

EN

Silica and magnetite have been recognized as emerging and effective environmentally-friendly pollutant removers. In this study, the effectiveness of silica/magnetite (SM) composites derived from local beach sand were developed and evaluated as an environmentally friendly adsorbent for taking up tetracycline from water. The formation of SM composites was verified through characterization performed using Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), and Scanning Electron Microscope (SEM) analysis. Two key parameters, kinetics and isotherms, were investigated to find the best condition for tetracycline adsorption using SM composites. In the kinetic adsorption studies, the pseudo-first-order, with correlation coefficients (R² > 0.99) higher than those of the pseudo-second-order and Elovich models, was performed to be the best-fitting model due to the close alignment between the experimental and theoretical data. The non-linear Langmuir isotherm model offered the most accurate fit (R² = 0.954, root-mean-square-errors = 1.505) compared to the Freundlich model, signifying that the adsorption process takes place on a uniform surface where the adsorbate is distributed in monolayers. In the present study, the maximum adsorption capacity of tetracycline onto SM composite reached 29.955±4.165 mg/g for 24-hour contact time with an adsorption rate constant of 0.415±0.050 min^-1. In conclusion, the developed environmentally conscious composite demonstrates the potential to be an effective adsorbent with remarkable tetracycline removal properties while also providing valuable insights for further research.

Słowa kluczowe

EN

adsorption; beach sand; degradation; silica magnetite composite; tetracycline

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2024
• Tom: Vol. 25, iss. 1
• Strony: 82--92
• Opis fizyczny: Bibliogr. 29 poz., rys., tab.

Twórcy

autor

Karina Sofyatuddin

• Department of Marine Sciences, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• Research Centre for Marine Sciences and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0009-0005-4508-9023

autor

Perdana Adli Waliul

• Department of Aquaculture, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• Research Centre for Marine Sciences and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0000-0001-8796-4563

autor

Prajaputra Vicky

• Department of Marine Sciences, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• Research Centre for Marine Sciences and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• ARC-PUI PT Nilam Aceh, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0000-0001-8838-9206

autor

Isnaini Nadia

• Research Centre for Marine Sciences and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• ARC-PUI PT Nilam Aceh, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0000-0001-6128-4316

autor

Nuufus Putri Hayyatun

• Department of Marine Sciences, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0009-0009-8492-0704

autor

Bismi Audia

• Department of Marine Sciences, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0009-0001-1640-7417

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).