Selective transport of copper(II) ions across polymer inclusion membrane with aromatic β–diketones as carriers

• Autorzy: Radzymińska-Lenarcik E. , Witt K. , Bożejewicz D.

Identyfikatory

DOI

10.5277/ppmp1868

• Języki publikacji: EN

Abstrakty

EN

The transport of Cu(II) ions from an equimolar mixture of Co(II), Ni(II), and Cu(II) ions as well as from solutions containing only Cu(II) ions in the feed phase through polymer inclusion membranes (PIMs) with aromatic β–diketones as carriers has been investigated. The polymer membranes consisted of polyvinylchloride (PVC) as the support, bis(2-ethylhexyl)adipate (ADO) as plasticizer, and aromatic β–diketones (benzoylacetone (1) and dibenzoylmethane (2)) as ion carriers. The transport selectivity of PIMs with 1 and 2 was: Cu(II) > Co(II) > Ni(II). The highest recovery factors of Cu(II) ions were observed for 1 (94.0%), whereas for Co(II) and Ni(II) the factors were 21.4 and 7.3%, respectively. The Cu(II)/Co(II) and Cu(II)/Ni(II) selectivity coefficients were equal to 8.9 and 33.7 (for 1), 6.4 and 28.3 (for 2), respectively.

Słowa kluczowe

EN

β-diketone; polymer inclusion membrane; metal ions separation; copper(II); cobalt(II); nickel(II)

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2018
• Tom: Vol. 54, iss. 3
• Strony: 741--750
• Opis fizyczny: Bibliogr. 43 poz., rys., tab.

Twórcy

autor

Radzymińska-Lenarcik E.

• Faculty of Chemical Technology and Engineering, UTP University of Sciences and Technology, Seminaryjna 3, PL-85326 Bydgoszcz, Poland

autor

Witt K.

• Faculty of Chemical Technology and Engineering, UTP University of Sciences and Technology, Seminaryjna 3, PL-85326 Bydgoszcz, Poland

autor

Bożejewicz D.

• Faculty of Chemical Technology and Engineering, UTP University of Sciences and Technology, Seminaryjna 3, PL-85326 Bydgoszcz, Poland

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