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This research focused on using coriander seeds as low cost adsorbent to remove heavy metals ions such as lead, zinc, and nickel from wastewater. Different parameters were studied to obtain the best results, such as pH, contact time, adsorbent dosage, concentration of initial metals and agitation speed. The highest results were obtained at pH 6, 105 min contact time, 1 g/100 ml dosage, 50 mg/l initial concentration of metal ions and 200 rpm agitation speed at temperature 25 ± 2 °C, which were 95.926%, 89.799% and 79.255% for lead, zinc and nickel ions, respectively. The results were also categorized as the Langmuir and Freundlich models, and found that the Freundlich isotherm fit the experimental data better than the Langmuir isotherm. The pseudo-second order was shown to have a high degree of fitness based on kinetic data. The adsorbent was characterized using a variety of techniques, including Fourier transform infrared spectroscopy (FTIR), Field Emission Scanning Electron Microscope (FESEM).
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
158--168
Opis fizyczny
Bibliogr. 34 poz., rys., tab.
Twórcy
autor
- Department of Environmental Engineering, College of Engineering, Mustansiriyah University, Baghdad, Iraq
autor
- Department of Environmental Engineering, College of Engineering, Mustansiriyah University, Baghdad, Iraq
Bibliografia
- 1. Abdou SaidA., Reda R.M., and Abd El-Hady H.M. 2021. Overview of herbal biomedicines with special reference to coriander (Coriandrum sativum) as new alternative trend for the development of aquaculture. Egyptian Journal of Aquatic Biology and Fisheries, 25 (2), 539–550.
- 2. Al-Obaidy A.M.J., Al-Janabi Z.Z. and Al-Mashhady A.A.M. 2016. Distribution of some heavy metals in sediments and water in Tigris River. Journal of Global Ecology and Environment, 4 (3), 140–146.
- 3. Amin M.T., Alazba A.A. and Amin M.N. 2017. Absorption behaviours of copper, lead, and arsenic in aqueous solution using date palm fibres and orange peel: kinetics and thermodynamics. Polish Journal of Environmental Studies, 26 (3), 543–557.
- 4. Anna B.,Kleopas M., Constantine S., Anestis F. andMaria B.2015. Adsorption of Cd (II), Cu (II), Ni (II) and Pb (II) onto natural bentonite: study in monoand multi-metal systems. Environmental Earth Sciences, 73 (9), 5435–5444.
- 5. Chatterjee S., Sivareddy I. and De S. 2017. Adsorptive removal of potentially toxic metals (cadmium, copper, nickel and zinc) by chemically treated laterite: single and multicomponent batch and column study. Journal of Environmental Chemical Engineering, 5 (4), 3273–3289.
- 6. Edathil A.A., Shittu I., Zain H.J., Banat F. and Abu haija M. 2018. Novel magnetic coffee waste nanocomposite as effective bioadsorbent for Pb (II) removal from aqueous solutions. Journal of Environmental Chemical Engineering, 6 (2), 2390–2400.
- 7. Elabbas S., Mandi L., Berrekhis F., Pons M.N., Leclerc J.P. and Ouazzani N. 2016. Removal of Cr (III) from chrome tanning wastewater by adsorption using two natural carbonaceous materials: eggshell and powdered marble. Journal of environmental management, 166, 589–595.
- 8. El Naggar A.M.A., Ali M.M., Abedl Maksoud S.A., Taha M.H., Morshedy A.S. and Elzoghby A. 2019. Waste generated bio-char supported co-nanoparticles of nickel and cobalt oxides for efficient adsorption of uranium and organic pollutants from industrial phosphoric acid. Journal of Radioanalytical and Nuclear Chemistry, 320(3), 741–755.
- 9. Ergüvenerler F., Targan Ş. and Tirtom V.N. 2020. Removal of lead from aqueous solutions by low cost and waste biosorbents (lemon, bean and artichoke shells). Water Science and Technology, 81(1), 159–169.
- 10. Faisal A. A. H.,Kassim W. M. S., and Hussein T. K. 2011. Influence of clay lens on migration of light non aqueous phase liquid in unsaturated zone,Journal of Environmental Engineering, 137 (1), 9–14.
- 11. Foroughi-DahrM., Abolghasemi H., Esmaili M., Shojamoradi A. and Fatoorehchi H. 2015. Adsorption characteristics of congo red from aqueous solution onto tea waste. Chemical Engineering Communications, 202 (2), 181–193.
- 12. Hussein T. K. and Jasim N. A. 2019. Removal of crystal violet and methylene blue from synthetic industrial wastewater using fennel seed as an adsorbent. Journal of Engineering Science and Technology, 14(5), 2947–2963.
- 13. Jia Y., Zhang Y., Fu J., Yuan L., Li Z., Liu C., Zhao D. and Wang X. 2019. A novel magnetic biochar/MgFe-layered double hydroxides composite removing Pb+2 from aqueous solution: isotherms, kinetics and thermodynamics. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 567(20), 278–287.
- 14. Kavand M., Kaghazchi T. and Soleimani M. 2014. Optimization of parameters for competitive adsorption of heavy metal ions (Pb+2, Ni+2, Cd+2) onto activated carbon. Korean journal of chemical engineering, 31 (4), 692–700.
- 15. Kumar M. R. and Bilal B. 2018. Removal of congo red from dye wastewater using adsorption. International Journal of Engineering and Techniques, 4 (1), 18–27.
- 16. Mahanty S., Chatterjee S., Ghosh S., Tudu P., Gaine T., Bakshi M., Das S., Das P., Bhattacharyya S., Bandyopadhyay S. and Chaudhuri P. 2020. Synergistic approach towards the sustainable management of heavy metals in wastewater using mycosynthesized iron oxide nanoparticles: biofabrication, adsorptive dynamics and chemometric modeling study. Journal of Water Process Engineering, 37, 101–426.
- 17. Malakahmad A., Tan S. and Yavari S.2016. Valorization of wasted black tea as a low-cost adsorbent for nickel and zinc removal from aqueous solution. Journal of Chemistry, Article ID 5680983, 1–8
- 18. Mohammed A.A., Abed F.I. and Al-Musawi T.J. 2016. Biosorption of Pb (II) from aqueous solution by spent black tea leaves and separation by flotation. Desalination and Water Treatment, 57 (5), 2028–2039.
- 19. Mohammed N.M.S. and Salim H.A.M. 2017. Adsorption of Cr (Vi) ion from aqueous solutions by solid waste of potato peels. Science Journal of University of Zakho, 5 (3), 254–258.
- 20. Mohan S.M. 2014. Simultaneous adsorption and biodegradation process in a SBR for treating wastewater containing heavy metals. Journal of Environmental Engineering, 140 (4), 4014008.
- 21. Parmar K. 2013. Removal of cadmium from aqueous solution using cobalt silicate precipitation tube (CoSPT) as adsorbent. International journal of Science Invention Today, 2 (3), 204–215.
- 22. Qassim F.M. 2013. Removal of heavy metal from water by sorptive flotation. M. Sc. Thesis, Baghdad University, Iraq.
- 23. Osińska M. 2017. Removal of lead (II), copper (II), cobalt (II) and nickel (II) ions from aqueous solutions using carbon gels. Journal of Sol-gel Science and Technology, 81 (3), 678–692.
- 24. Ouass A., Ismi I., Elaidi H., Lebkiri A., Cherkaoui M. andRifi E.H. 2017. Mathematical modeling of the adsorption of trivalent chromium by the sodium polyacrylate beads. Journal of Material and Environmental Sciences, 8, 3448–3456.
- 25.Ramesh S.T., Rameshbabu N., Gandhimathi R., Kumar M.S. and Nidheesh P.V. 2013. Adsorptive removal of Pb (II) from aqueous solution using nano-sized hydroxyapatite. Applied Water Science, 3(1), 105–113.
- 26. Rao R.A.K. and Kashifuddin M. 2012. Adsorption properties of coriander seed powder (Coriandrum sativum): extraction and pre-concentration of Pb (II), Cu (II) and Zn (II) ions from aqueous solution. Adsorption Science and Technology, 30(2), 127–146.
- 27. Ray J., Jana S., Bhanja S.K. and Tripathy T. 2018. Efficient removal of Co(II), Ni(II), and Zn(II) metal ions from binary and ternary solutions using a pH responsive bifunctional graft copolymer. Colloid and Polymer Science, 296 (8), 1275–1291.
- 28.Rodiguez M.H., Yperman J., Carleer R., Maggen J., Dadi D., G ryglewicz G., Bruggen B.V.D., Hernandez J.F. andCalvis A.O. 2018. Adsorption of Ni (II) on spent coffee and coffee husk based activated carbon. Journal of Environmental Chemical Engineering, 6 (1), 1161–1170.
- 29. Vafajoo L., Cheraghi R., Dabbagh R. and Mckay G. 2018. Removal of cobalt (II) ions from aqueous solutions utilizing the pre-treated 2-Hypnea Valentiae algae: Equilibrium, thermodynamic, and dynamic studies. Chemical Engineering Journal, 331, 39–47.
- 30. Yadav V.K., Ali D., Khan S.H ., Gnanamoorthy G., ChoudharyN., Yadav K.K., Thai V.N., Hussain S. A. and Manhrdas S. 2020. Synthesis and characterization of amorphous iron oxide nanoparticles by the sonochemical method and their application for the remediation of heavy metals from wastewater. Nanomaterials, 10 (8), 15–51.
- 31. Wang G., Zhang S., Yao P., Chen Y., Xu X., Li T., and Gong G. 2018. Removal of Pb(II) from aqueous solutions by Phytolacca americana L. biomass as a low cost biosorbent. Arabian Journal of Chemistry, 11, 99–110.
- 32. Zeković Z. Kaplan M., Pavlic B., Olgun E.O., Vladic J., Canli O. and Vidovic S. 2016. Chemical characterization of polyphenols and volatile fraction of coriander (Coriandrum sativum L.) extracts obtained by subcritical water extraction. Industrial Crops and Products, 87, 54–63.
- 33. Zhi-Liang C., Jain-Qiang Z., Ling H., Zhi-Hui Y., Zho-Jun L. and Min-Chao L. 2019. Removal of Cd and Pb with biochar made from dairy manure at low temperature. Journal of Integrative Agriculture, 18(1), 201–210.
- 34. Zhou X., Yaochi L., Jianjun Z., Jing G., Jialin R. and Fang Z. 2018. Efficient removal of lead from aqueous solution by urea-functionalized magnetic biochar: Preparation, characterization and mechanism study. Journal of the Taiwan Institute of Chemical Engineers, 91, 457–467.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-25028e0e-62be-41c7-aaca-02a6c949a76c