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Effect of calcinated magnesite on rheology of bentonite suspensions. Magnesia-bentonite interaction

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, the effect of calcination temperature and time on the structure of calcinated magnesite was investigated. In addition, the effect of calcinated magnesite on rheology when added into bentonite suspension was also examined. Electrokinetic, rheological and stabilization studies including coagulation and gelation tests were performed to explain the mechanism of viscosity increase in bentonite suspension upon addition of the calcinated products. FTIR, SEM, BET analyses and rheological data were used to determine the transition degree of MgCO3 to MgO, and evaluate the structure of MgO and bentonite suspensions. The results from this study showed that specific surface area (SSA) and mean pore radius (MPR) values for the calcinated products were directly affected by the calcination temperature and time. According to the ignition loss and transition ratio from MgCO3 to MgO of the calcinated samples, it was found that the calcination was completed above 800 oC. In order to obtain a bentonite suspension with higher viscosity, interaction of the sufficient amount of MgO particles with bentonite particles were necessary. Based on these results, the formation of gelation and heterocoagulation between MgO and bentonite particles were found to be responsible for these effects.
Słowa kluczowe
Rocznik
Strony
453--466
Opis fizyczny
Bibliogr. 26 poz., rys., tab.
Twórcy
autor
  • University of Istanbul, Engineering Faculty, Mining Engineering Department, Avcilar, Istanbul, Turkey
autor
  • Istanbul Technical University, Faculty of Mines, Mineral Processing Engineering Department, 34469, Maslak, Istanbul, Turkey
autor
  • Istanbul Technical University, Faculty of Mines, Mineral Processing Engineering Department, 34469, Maslak, Istanbul, Turkey
Bibliografia
  • 1. ABEND S., LAGALY G., 2000, Sol-gel transitions of sodium montmorillonite dispersions, Appl. Clay Sci. 16: 201.
  • 2. AKBULUT A., 1996, Bentonite. MTA Publications 32 Ankara (in Turkish).
  • 3. ALTHER G.R., 1986, The effect of the exchangeable cations on the physico-chemical properties of Wyoming bentonites. Appl. Clay Sci., 1:273.
  • 4. APHANE M.E., 2007, The hydration of magnesium oxide with different reactivities by water and magnesium acetate, MSc Thesis, University of South Africa.
  • 5. ARAMEND M.A., BORAU V., JIMENEZ C., MARINAS J.M., RUIZ J.R., URBANO F.J., 2003, Influence of the preparation method on the structural and surface properties of various magnesium oxides and their catalytic activity in the Meerwein–Ponndorf–Verley reaction, Appl Catalysis A: General, 244, 207–215
  • 6. BOYLU F., CINKU K., ESENLI F., CELIK M.S., 2010, The separation efficiency of Na-bentonite by hydrocyclone and characterization of hydrocyclone products, Int. J. Miner Process 94(3–4): 196.
  • 7. BOYLU F., HOJIYEV R., ERSEVER G., ULCAY Y., CELIK M.S., 2012, Production of ultrapure bentonite clays through centrifugation techniques, Sep. Sci. Technol. 47: 842.
  • 8. CINKU K., 2008, Investigation of Production of water based thickeners from activated bentonite suspensions, PhD thesis, University of Istanbul, Istanbul, 296 (in Turkish).
  • 9. ERDOGAN B., DEMIRCI Ş., 1996, Activation of some Turkish bentonites to improve their drilling fluid Properties, Appl. Clay Sci. 10: 401.
  • 10. FLATT R.J., HOUST Y.F., BOWEN P., HOFMANN H., WIDMER J., SULSER V., MAEDER U., BÜRGE T.A., SIKA A.G., 1997, Adsorption of Superplasticizers on Model Powders: Temperature Dependence, Effect On Zeta Potential And Role Of Chemical Structure, Proceedings of the 10th International Congress on the Chemistry of Cement, 3 (editor: H.J. Justness) paper 3iii002.
  • 11. GENCE N., OZBAY N., YEREL S., 2006, Statistical relationship between electrokinetic potential and pH of magnesite and dolomite minerals, Science and Eng. J of Fırat Univ., 3: 397.
  • 12. KARAGUZEL C., CETINEL T., BOYLU F., CINKU K., CELIK M.S., 2010, Activation of (Na, Ca)-bentonites with soda and MgO and their utilization as drilling mud, Appl. Clay Sci. 48: 398.
  • 13. KARAKAS F., PYRGIOTAKIS G., CELIK M.S., MOUDGIL, BRIJ M., 2011, Na-bentonite and MgO Mixture as a Thickening Agent for Water-Based Paints, Kona Powder and Particle Journal 29
  • 14. LAGALY G., ZIESMER S., 2003, Colloid chemistry of clay minerals: the coagulation of montmorillonite dispersions, Adv. in Coll. and Interf. Sci., 100-102: 105.
  • 15. LIU B., THOMAS P.S, RAY A.S., GUERBOIS J.P., 2007, A TG analysis of the effect of calcination conditions on the properties of reactive magnesia, J. Therm. Anal Calorim. 88: 145.
  • 16. OBUT A., GIRGIN I., 2005, The effect of Mg, Pb and Mn ions on gelling properties of bentonite suspensions, Madencilik, 44 (2): 17 (in Turkish).
  • 17. RAO A.S., 1987, Effect of pH on the suspension stability of alumina, titania and their mixtures, Ceram. Int. 13: 233.
  • 18. RAO A.S., 1988a, Electrophoretic mobility of alumina, titania and their mixutures in aqueous dispersions, Ceram. Int. 14: 71.
  • 19. RAO A.S., 1988b, Effects of surface active agents on the electrokinetic and rheological behavior mobility of alumina and titania slips, Ceram. Int. 14: 141.
  • 20. RYNKOWSKI J.M., DOBROSZ-GOMEZ I., 2009, Ceria-Zirconia Supported Gold Catalysts, Annales Univesitatis Maria Curie-Sklodowska Lublin-Polonia, 14 AA: 197.
  • 21. SABAH E., MART U., CINAR M., CELIK M.S., 2007, Zeta potentials of sepiolite suspensions in concentrated monovalent electrolytes, Sep. Sci. Technol. 42 (10): 227.
  • 22. SASAKI K., QIU X., HOSOMOMI Y., MORIYAMA S., HIRAJIMA T., 2013, Effect of natural dolomite calcination temperature on sorption of borate onto calcinated products, Microporous and Mesoporous Materials 171, 1–8.
  • 23. TARI G., FERREIRA J.M.F., LYCKFELDT O., 1997, Influence of magnesia on colloidal processing of Alumina, Journal of European Ceramic Society 17: 1341.
  • 24. TOMBACZ E., SZEKERES M., 2004, Colloidal behavior of aqueous montmorillonite suspensions: the specific role of pH in the presence of indifferent electrolytes, Appl. Clay Sci. 27: 75.
  • 25. VAN OLPHEN H., 1963, An introduction to Clay Colloid Chemistry, Interscience, New York.
  • 26. VAN OLPHEN H., 1977, An Introduction to Clay Colloid Chemistry, John Wiley and Sons, New York.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2496b5fa-c38c-4c08-a65a-0017ae1eaecb
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