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Studies on Tungsten Based High Density Cast Polymer Bonded Explosive (PBX) Formulations

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Aluminized melt-cast TNT and PBX (cast/pressed) based compositions have been widely studied and used in different warheads for various applications,such as air blast, underwater blast, thermobaric effects, etc. Tungsten (W) based cast PBX formulations are the least reported in the literature. We have partially replaced RDX or HMX in the control PBX formulation with 15 to 25% W powder and investigated the effect of this on the ease of processing, density, sensitivity, mechanical properties and explosive performance. The viscosity was improved from 9 to 3 kPoise, and the density by about 12 to 25% on the addition of W powder to the PBX formulations. The sensitivity to impact for the RDX/Wand HMX/W based PBX formulations was improved by 12 to 37%. The reinforcing effect of the W powder caused an increase in hardness (Shore A) by 16 to 45%. A decreasing trend in the velocity of detonation (VOD) was observed because of the replacement of the nitramine content (RDX/HMX) with W powder. The approximate detonation pressure of RDX/W/HTPB (65/20/15), roughly calculated by the Kamlet-Jacobs method, is better than the other tungsten based formulations investigated.
Słowa kluczowe
EN
tungsten   RDX   HMX   HTPB   PBX  
Rocznik
Strony
497--506
Opis fizyczny
Bibliogr. 26 poz., tab.
Twórcy
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
Bibliografia
  • [1] Anderson E., Explosives, Ch. 2, in: Tactical Missile Warheads (Progress in Astronautics and Aeronautics), (Carleone J., Ed.), Vol. 155, AIAA, Washington, 1993, ISBN 9781563470677.
  • [2] Urbański T., Chemistry and Technology of Explosives, Vol. 3, Pergamon Press, Oxford-London-Edinburgh-New York-Toronto-Sydney-Paris -Braunschweig, 1967, ISBN 9780080104010.
  • [3] Vadhe P.P., Pawar R.B., Sinha R.K., Asthana S.N., Subhananda Rao A., Cast Aluminized Explosives (Review), Combust., Explos. Shock Waves (Engl. Transl.), 2008, 44, 461-467.
  • [4] Antic G., Dzingalasevic V., Characteristics of Cast PBX with Aluminium, Sci.-Tech. Rev., 2006, LVI (3-4), 52-58.
  • [5] Maranda A., Lipińska K., Lipiński M., Analysis of Double Base Propellant Influence on Detonation Process of Ammonals, Cent. Eur. J. Energ. Mater., 2010, 7(2), 145-159.
  • [6] Hou C., Geng X., An Ch., Wang J., Xu W., Li X., Preparation of Al Nanoparticles and Their Influence on the Thermal Decomposition of RDX, Cent. Eur. J. Energ. Mater., 2013, 10(1), 123-133.
  • [7] Li S., Jiang Z., Yu S., Thermal Decomposition of HMX Influenced by Nano-metal Powders in High Energy Fuel, Fuel Chemistry Division Preprints, 2002, 47(2), 596.
  • [8] Gibbs T.R., Popolato A., LASL Explosive Property Data, University of California Press, Berkeley-Loos Angeles-London, Part-II, Section 3, 234-289, 1980.
  • [9] Anderson P.A., Cook P., Davis A., Mychajlonka K., Mileham M., Silicon Fuel in High Performance Explosives, Propellants Explos. Pyrotech., 2014, 39, 74-78.
  • [10] Chan M.L., Meyers G.W., Advanced Thermobaric Explosives Compositions, US Patent 6 995 732 B1, 2005.
  • [11] Sezaki T., Date S., Satoh J., Study on the Effects of Addition of Boron Particles to RDX-Based PBX Regarding Prevention of Neumann Effect, Mater. Sci. Forum, 2004, 465-466, 195-200.
  • [12] Kanel G.I., Utkin A.V., Razorenov S.V., Rate of the Energy Release in High Explosives Containing Nano-size Boron Particles, Cent. Eur. J. Energ. Mater., 2009, 6(1), 15-30.
  • [13] Imperiali R., Explosives, US Patent 41913, 1912.
  • [14] Weinland C.E., High Impulse Explosive Containing Tungsten, US Patent 3528864, 1970.
  • [15] Spencer A.F., Parsons G.H., High Density Tungsten-loaded Castable Explosive, US Patent 5910638, 1999.
  • [16] Goldstein S., Mader C.L., Detonation in Tungsten-loaded HMX, 8th Symposium (Int.) on Detonation, Albuquerque, NM, 1985, S-024.
  • [17] Mishra V.S., Bhagat A.K.L., Vadali S.R., Sign V.K., Wasnik R.D., Ashtana S.N., Effect of Tungsten on Aluminized Melt Cast High Explosives Formulations, Cent. Eur. J. Energ. Mater., 2012, 9(2), 147-154.
  • [18] Kato H., Murata K., Itoh S., Kato Y., Application of Overdriven Detonation in High Density Explosive to Shaped Charge, 23rd Int. Symposium on Ballistics, Tarragona, Spain, 2007, 223-230.
  • [19] Hollands R.E., Murray I.E.P., Cast Explosive Composition, US Patent 0168306 A1, 2011.
  • [20] Akhavan J., The Chemistry of Explosives, Ch. 5 and 6, Royal Society of Chemistry, 1998, ISBN 9780854045631.
  • [21] Kamlet M.J., Jacobs S.J., Chemistry of Detonations I. A Simple Method for Calculating Detonations of C-H-N-O Explosives, J. Chem. Phys., 1968, 48, 23-35.
  • [22] Cook M.A., The Science of High Explosives, American Chemical Society Monograph Series, Reinhold Publishing Corpn., New York, USA, 1958, ISBN 9780278922839.
  • [23] http://shodhganga.inflibnet.ac.in/bitstream/10603/7518/10/10_chapter%204.pdf (accessed 08 June 2014).
  • [24] Lassner E., Schubert W.D., Tungsten: Properties, Chemistry, Technology of the Element, Alloys and Chemical Compound, Ch. 1, Kluwer Academic/Plenum Publishers, 1999, ISBN 0306450534.
  • [25] Wang Y., Zhang J., Su H., Li S., Zhang S., Pang S., A Simple Method for the Prediction of the Detonation Performances of Metal-containing Explosives, J. Phys. Chem. A, 2014, 118(25), 4575-4581.
  • [26] Persson P.A., Chiapetta R.F., Shock Waves and Detonations, Explosive Performance, Ch. 4, Proc. NIXT’94-Pretoria, 1994, 517-566.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2386efa4-ec26-45c7-8712-a84eaf7d1a5f
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