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The leaching of low grade zinc oxide mining tailings by organic acid as a leaching agent was investigated. Zinc was extracted successfully from sample by citric acid leaching. The effects of solid-to- liquid ratio, acid concentration, reaction time, temperature and ore particle size on the leaching efficiency were studied. The results obtained showed that particle sizes and reaction time had not any significant effect on the leaching recovery of zinc from smithsonite in the sizes range of 40-350 μm. Under conditions: temperature of 80ºC, reaction time of 60 min, citric acid concentration of 0.5 mol/L, and solid to liquid ratio of 1:10, 82% of zinc could be recovered.
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547--555
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- Department of Mining and Metallurgical Engineering, Amirkabir University of Technolog., Tehran, Iran
autor
- IranianAcademic Center for Education, Culture and Research(ACECR), Branch of Amirkabir, Iran
autor
- Department of Mining and Metallurgical Engineering, Amirkabir University of Technolog., Tehran, Iran
Bibliografia
- 1. BAYRAK B., LACIN O., SARAC H., 2010, Kinetic study on the leaching of calcined magnesite in gluconic acid solutions. Industrial and Engineering Chemistry, 16, 479–484.
- 2. BURGSTALLER W., STRASSER H., WOBKING H., SCHINNER F., 1992, Solubilization of zinc oxide from filter dust with Penicillium simplicissimum: bioreactor leaching and stoichiometry. Environ Sci Technol, 26(2), 340–346.
- 3. CASTRO I., FIETTO J., VIEIRA R., TRO´PIA M., CAMPOS L., PANIAGO E., BRANDAO R., 2000, Bioleaching of zinc and nickel from silicates using Aspergillus niger cultures. Hydrometallurgy, 57, 39–49.
- 4. CHEN A., ZHAO Z. W., JIA X., LONG S., HUO G., CHEN X., 2009, Alkaline leaching Zn and its concomitant metals from refractory hemimorphite zinc oxide ore. Hydrometallurgy, 97, 228–232.
- 5. CUN-XIONG L., HONG-SHENG X., ZHI-GAN D., XING-BIN L., MING-TIN L., CHANG W., 2010, Pressure leaching of zinc silicate ore in sulfuric acid medium. Transaction of Nonferrous Metals So-ciety of China, 20, 918-923.
- 6. EJTEMAEI M., IRANNAJAD M., 2008, Recovery of Zinc Oxide Minerals from Angooran Mining Tail-ings by Flotation. MSc Thesis, Amirkabir University of Technology (Tehran Polytechnic), Iran.
- 7. EJTEMAEI M., IRANNAJAD M., GHARABAGHI M., 2011, Influence of important factors on flotation of zinc oxide mineral using cationic, anionic and mixed (cationic/anionic) collectors. Minerals Engi-neering,24.1402-1408.
- 8. ESPIARI S., RASHCHI F., SADRNEZHAAD S., 2006, Hydrometallurgical treatment of tailings with high zinc content. Hydrometallurgy,82, 54–62.
- 9. HE S., WANG J., YAN J., 2010, Pressure leaching of high silica Pb–Zn oxide ore in sulfuric acid me-dium. Hydrometallurgy, 104, 235–240.
- 10. HURSIT M., LACIN O., SARAC H., 2009, Dissolution kinetics of smithsonite ore as an alternative zinc source with an organic leach reagent. Taiwan Institute of Chemical Engineers, 97, 6–12.
- 11. IRANNAJAD M., EJTEMAEI M., GHARABAGHI M., 2009. The effect of reagents on selective flota-tion of smithsonite–calcite–quartz. Minerals Engineering, 22, 766–771.
- 12. JONES M., 1987. Applied mineralogy: a quantitative approach. Graham & Trotman, London, p. 22.
- 13. JU S., MOTANG T., SHENGHAI Y., YINGNIAN L., 2005, Dissolution kinetics of smithsonite ore in ammonium chloride solution. Hydrometallurgy, 80, 67–74.
- 14. MESHKINI M., IRANNAJAD M., 2011 a, Zinc Recovery from Angoran Mining Tailing by Biohydro-metallurgical Method. MSc Thesis, Amirkabir University of Technology (Tehran Polytechnic), Iran.
- 15. MESHKINI M., IRANNAJAD M., AZADMEHR A., ABASI ROHALLAHI A., 2011 b, Extraction of Zinc from Low Grade Zinc Oxide Ores using Bacteria. Second National Conference of Applied Mi-crobiology. Tehran, Iran.
- 16. ONAL G., BULUT G., GUL A., KANGAL O., Perek K., Arslan F., 2005, Flotation of Aladag oxide lead–zinc ores. Minerals Engineering, 18, 279–282.
- 17. PAPAGIANNI M., MATTEY M., KRISTIANSEN B., 1999, The influence of glucose concentration on citric acid production and morphology of Aspergillus niger in batch and culture. Enzyme and Micro-bial Technology, 25, 710-717.
- 18. QING L., YOU-CAI Z., GUO-DONG Z., 2010, Thermodynamics of Zn(II)-NaOH-H2O system. Shang-hai Univ, 14(5), 332–336.
- 19. SANKPAL N., JOSHI A., KULKARNI B., 2001, Citric acid production by Aspergillus niger immobi-lized on cellulose microfibrils: influence of morphology and fermenter conditions on productivity. Process Biochemistry, 36, 1129–1139.
- 20. SANTOS F. M., PINA P. S., PORCARO R., OLIVEIRA A. V., SILVA C. A., LEÃO V. A., 2010, The kinetics of zinc silicate leaching in sodium hydroxide. Hydrometallurgy, 102, 43–49.
- 21. SCHINNER F., BURGSTALLER W., 1989, Extraction of Zinc from Industrial Waste by a Penicillium sp. Applied and Enviromental Microbiology, 55, 1153–1156.
- 22. XU H., WEI C., LI C., FAN G., DENG Z., LI M., LI X., 2010, Sulfuric acid leaching of zinc silicate ore under pressure. Hydrometallurgy, 105, 186–190.
- 23. ZHAO Y., STANFORTH R., 2000, Production of Zn powder by alkaline treatment of smithsonite Zn–Pb ores. Hydrometallurgy, 56, 237–249.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-231df6a2-11e5-4937-ac8d-da3aaf787f51