Lewis acids immobilized in ionic liquid – application for the acetal synthesis

• Autorzy: Janus E.
• Języki publikacji: EN

Abstrakty

EN

Catalytic systems composed of metal chloride (InCl3, ScCl3, YCl3, YbCl3, LaCl3, BiCl3, ZnCl3 and CuCl3) and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)-imide, [C1C4Pyrr][NTf2] as ionic liquid were prepared. Catalytic activity of all the systems were compared in acetalization reaction between cyclohexanone and triethyl orthoformate. 1,1-Diethoxycyclohexane were formed with high yield and the selectivity at 0°C within 5 minutes. Selected metal chlorides immobilized in ionic liquid were recycled 5 times without a decrease in their activities.

Słowa kluczowe

EN

acetal formation; ionic liquid; Lewis acid; 1,1-diethoxycyclohexane

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2013
• Tom: Vol. 15, nr 3
• Strony: 78--80
• Opis fizyczny: Bibliogr.14 poz., wykr., wz.

Twórcy

autor

Janus E.

• West Pomeranian University of Technology, Szczecin, Department of Chemical Organic Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Bibliografia

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