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Facile preparation of copper impregnated aluminum pillared montmorillonite: nanoclays for wastewater treatment

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Copper impregnated aluminum pillared montmorillonites (Cu-iAlpill-MMTs) were prepared by adding Cu2+ solution into dried aluminum polyohydroxy cation intercalated montmorillonite using various Cu2+ concentrations, i.e. 4, 7, 10 and 13 wt% and then calcining at 500°C. The Cu-iAlpill-MMTs possessed slit-liked mesopores with pore diameters of 3.3–3.8 nm and ~6–35 nm as observed from the nitrogen adsorption isotherms. The mesopore quantities of Cu-iAlpill-MMTs gradually decreased with the increase of impregnated Cu2+ concentrations. The impregnated CuO occupied not only the interior interlayers, but also the exterior surfaces of Cu-iAlpill-MMTs. The Cu-iAlpill-MMTs with 10 and 13 wt% of impregnated Cu2+ could inhibit the growth of Escherichia coli. The Cu-iAlpill-MMTs effectively acted as the heterogeneous catalyst for removal reactive orange 16 (RO16) in Fenton or photo-Fenton oxidation treatments. The higher impregnated Cu2+ and/or the longer treatment time brought about the higher percentage of RO16 removal.
Rocznik
Strony
553--560
Opis fizyczny
Bibliogr. 23 poz., rys., wykr., tab.
Twórcy
autor
  • Functional Nanostructured Materials Laboratory, College of Nanotechnology, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok 10520, Thailand
  • Functional Nanostructured Materials Laboratory, College of Nanotechnology, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok 10520, Thailand
  • Department of Chemistry, Faculty of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok 10520, Thailand
Bibliografia
  • [1] J. Bovey, F. Kooli, and W. Jones, “Preparation and characterization of Ti-pillared acid-activated clay”, Clays. Miner. 31, 501–506 (1996).
  • [2] J.T. Kloprogge, “Synthesis of smectites and porous pillared clay catalysts: review”, J. Porous. Mater. 5, 5–41 (1998).
  • [3] P. Yuan, H. He, F. Bergaya, D. Wu, Q. Zhou, and J. Zhu, “Synthesis and characterization of delaminated iron-pillared clay with meso-microporous structure”, Microporous. Mesoporous. Mater. 88, 8–15 (2006).
  • [4] H. Guo, X. Jing, L. Zhang, and J. Wang, “Preparation of inorganic-organic pillared montmorillonite using ultrasonic treatment”, J. Mater. Sci. 42, 6951–6955 (2007).
  • [5] P. Tepmatee and P. Siriphannon, “Effect of Preparation Method on Structure and Adsorption Capacity of Aluminium Pillared Montmorillonite”, Mater. Res. Bull. 48, 4856–4866 (2013).
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  • [7] M.A. Vicente, C. Belver, R. Trujillano, M.A. Bañares-Muñoz, V. Rives, S.A. Korili, A. Gil, L.M. Gandía, and J.F. Lambert, “Preparation and characterisation of vanadium catalysts supported over alumina-pillared clays”, Catal. Today. 78, 181–190 (2003).
  • [8] E.G. Garrido-Ramírez, B.K.G. Theng, and M.L. Mora, “Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions-A review”, Appl. Clay. Sci. 47, 182–192 (2010).
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  • [10] J.K. Kim, F. Martinez, and I.S. Metcalfe, “The beneficial role of use of ultrasound in heterogeneous Fenton-like system over supported copper catalysts for degradation of p-chlorophenol”, Catal. Today. 124, 224–231 (2007).
  • [11] S. Xia, L. Hui, Z. Yaobin, Z. Yazhi, and Q. Xie, “Efects of Cu(II) and humic acid on atrazine photodegradation”, J. Environ. Sci. 23(5), 773–777 (2011).
  • [12] S. Zhou, Z. Qian, T. Sun, J. Xu, and C. Xia, “Catalytic wet peroxide oxidation of phenol over Cu–Ni–Al hydrotalcite”, Appl. Clay. Sci. 53, 627–633 (2011).
  • [13] S. Caudo, G. Centi, C. Genovese, and S. Perathoner, “Copper and iron-pillared clay catalysts for the WHPCO of model and real wastewater streams from olive oil milling production”, Appl. Catal. B- Environ. 70, 437–446 (2007).
  • [14] S. Caudo, C. Genovese, S. Perathoner, and G. Centi, “Copper-pillared clays (Cu-PILC) for agro-food wastewater purification with H2O2”, Microporous. Mesoporous. Mater. 107, 46–57 (2008).
  • [15] P. Majzlik, A. Strasky, V. Adam, M. Nemec, L. Trnkova, J. Zehnalek, J. Hubalek, I. Provaznik, and R. Kizek, “Influence of zinc(II) and copper(II) ions on streptomyces bacteria revealed by electrochemistry”, Int. J. Electrochem. Sci. 6, 2171–2191 (2011).
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  • [17] P. Tepmatee and P. Siriphannon, “Nanoporous copper doped aluminium pillared montmorillonite for dye-containing wastewater treatment”, Water. Environ. Res. doi: 10.2175/106143015X14362865227076 (2015).
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  • [19] M.S. Hassan, T. Amna, O-B. Yang, M.H. El-Newehy, S.S. Al-Deyab, and M-S. Khil, “Smart copper oxide nanocrystals: Synthesis, characterization, electrochemical and potent antibacterial activity”, Colloids. Surf. B. 97, 201–206 (2012).
  • [20] F. Haber and J. Weiss, “The catalytic decomposition of hydrogen peroxide by iron salts”, J. Proc. Roy. Soc. London. A. 147, 332–351 (1934).
  • [21] M.N. Timofeeva, S.Ts. Khankhasaeva, E.P. Talsi, V.N. Panchenko, A.V. Golovin, E.Ts. Dashinamzhilova, and S.V. Tsybulya, “The effect of Fe/Cu ratio in the synthesis of mixed Fe, Cu, Al-clays used as catalysts in phenol peroxide oxidation”, Appl. Catal. B: Environ. 90, 618–627 (2009).
  • [22] F.V.F Araujo, L. Yokoyama, L.A.C. Teixeira, and J.C. Campos, “Heterogeneous Fenton process using the mineral hematite for the discolouration of a reactive dye solution”, Braz. J. Chem. Eng. 28, 605–616 (2011).
  • [23] S.S. Kumar, T. Muruganandham, and M.S.M. Jaabir, “Decolourization of Azo dyes in a two-stage process using novel isolate and advanced oxidation with Hydrogen peroxide / HRP system”, Int. J. Curr. Microbiol. App. Sci. 3, 514–522 (2014).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-21cb6740-c6cc-4991-9496-0090c7f64595
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