Catalytic Ozonation of Ponceau 4R Using Multifunctional Magnetic Biochar Prepared from Rubber Seed Shell

• Autorzy: Nguyen Hung Minh , Truong Tram Thi Bao , Nguyen Hong-Hue Thi , Tran Phong Thanh , Tran-Thuy Tuyet-Mai , Nguyen Long Quang , Nguyen Dung Van

Identyfikatory

DOI

10.12911/22998993/172919

• Języki publikacji: EN

Abstrakty

EN

Herein, abundant and underutilized rubber seed shell (RSS) was valorized for one-pot production of multifunctional magnetic biochar (MBC) through one-pot FeCl₃ activation. Fe₃O₄ and Fe⁰ crystals were formed in MBC, providing a saturation magnetization of 6.83 emu/g. In addition, the material had a specific surface area of 378 m²/g and a total pore volume of 0.22 cm³/g. MBC was subsequently explored for catalytic ozonation of Ponceau 4R (P4R). As a result, MBC enhanced P4R ozonation in a broad pH range of 3.0–9.0. At pH 5.8, the pseudo-first-order rate constant of P4R decolorization with MBC improved by 50% compared to that without MBC. Summarily, RSS-derived MBC is a potential catalyst for enhanced ozonation of Ponceau 4R thanks to its low cost, eco-friendliness, relative effectiveness, and magnetic separability.

Słowa kluczowe

EN

rubber seed shell; magnetic biochar; one-pot strategy; catalytic ozonation; Ponceau 4R

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 12
• Strony: 143--151
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Nguyen Hung Minh

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

• https://orcid.org/0009-0001-5927-4634

autor

Truong Tram Thi Bao

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

autor

Nguyen Hong-Hue Thi

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

• https://orcid.org/0000-0001-8564-5024

autor

Tran Phong Thanh

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

autor

Tran-Thuy Tuyet-Mai

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

• https://orcid.org/0000-0001-8072-7362

autor

Nguyen Long Quang

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

• https://orcid.org/0000-0002-7383-1361

autor

Nguyen Dung Van

• Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam
• Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam

• https://orcid.org/0000-0003-1325-5726

Bibliografia

• 1. Bedia, J., Monsalvo, V.M., Rodriguez, J.J. and Mohedano, A.F. 2017. Iron catalysts by chemical activation of sewage sludge with FeCl3 for CWPO. Chemical Engineering Journal, 318, 224–230.
• 2. Bhattacharjee, A., Bhowmik, M., Paul, C., Das Chowdhury, B. and Debnath, B. 2021. Rubber tree seed utilization for green energy, revenue generation and sustainable development– A comprehensive review. Industrial Crops and Products, 174, 114186.
• 3. Borhan, A., Yusup, S., Lim, J.W. and Show, P.L. 2019. Characterization and modelling studies of activated carbon produced from rubber-seed shell using KOH for CO2 adsorption. Processes, 7(11), 855.
• 4. Devi, P. and Saroha, A.K. 2014. Synthesis of the magnetic biochar composites for use as an adsorbent for the removal of pentachlorophenol from the effluent. Bioresource Technology, 169, 525–531.
• 5. Do, T.V.T., Bui, Q.L.N., Nguyen, H.M., Lam, H.H., Tran-Thuy, T.-M., Nguyen, L.Q., Ngo, D.T.H. and Nguyen, D.V. 2022. One-pot fabrication of magnetic biochar by FeCl3-activation of lotus seedpod and its catalytic activity towards degradation of Orange G. Materials Research Express, 9, #105601.
• 6. Feng, Z., Yuan, R., Wang, F., Chen, Z., Zhou, B. and Chen, H. 2021. Preparation of magnetic biochar and its application in catalytic degradation of organic pollutants: A review. Science of The Total Environment, 765, #142673.
• 7. Frisbie, S.H., Mitchell, E.J., Dustin, H., Maynard, D.M. and Sarkar, B. 2012. World health organization discontinues its drinking-water guideline for manganese. Environmental Health Perspectives, 120(6), 775–778.
• 8. Ji, Y., Pan, Z., Yuan, D. and Lai, B. 2018. Advanced treatment of the antibiotic production wastewater by ozone/zero-valent iron process. CLEAN – Soil, Air, Water, 46(3), #1700666.
• 9. Jiles, D.C. 2003. Recent advances and future directions in magnetic materials. Acta Materialia, 51(19), 5907–5939.
• 10. Kishimoto, N. and Ueno, S. 2012. Catalytic effect of several iron species on ozonation. Journal of Water and Environment Technology, 10(2), 205–215.
• 11. Kujawska, J. 2023. Content of heavy metals in various biochar and assessment environmental risk. Journal of Ecological Engineering, 24(8), 287–295.
• 12. Li, X., Wang, C., Zhang, J., Liu, J., Liu, B. and Chen, G. 2020. Preparation and application of magnetic biochar in water treatment: A critical review. Science of The Total Environment, 711, #134847.
• 13. Nguyen, D.V., Nguyen, H.M., Bui, Q.L.N., Do, T.V.T., Lam, H.H., Tran-Thuy, T.-M. and Nguyen, L.Q. 2023. Magnetic activated carbon from ZnCl2 and FeCl3 coactivation of lotus seedpod: One-pot preparation, characterization, and catalytic activity towards robust degradation of acid orange 10. Bioinorganic Chemistry and Applications, 2023, #3848456.
• 14. Nguyen, H.M., Tran, A.T., Nguyen, D.N.L., Lam, H.H., Tran-Thuy, T.-M., Nguyen, L.Q., Le, T.X. and Nguyen, D.V. 2023. One-pot fabrication of zero-valent iron-embedded activated carbon from rosemary distillation residues for malachite green removal. Materials Research Express, 10(8), #085603.
• 15. Nguyen, L.T.K., Nguyen, L.Q., Nguyen, H.M., Nguyen, T.M., Lam, H.H., Tran-Thuy, T.-M. and Nguyen, D.V. 2023. Simple one-step synthesis of nipa frond-derived magnetic porous carbon for decolorization of acid yellow 23. Journal of Chemistry, 2023, #5447693.
• 16. Niedziński, T., Łabętowicz, J., Stępień, W. and Pęczek, T. 2023. Analysis of the use of biochar from organic waste pyrolysis in agriculture and environmental protection. Journal of Ecological Engineering, 24(4), 85–98.
• 17. Pera-Titus, M., Garcı́ a-Molina, V., Baños, M.A., Giménez, J. and Esplugas, S. 2004. Degradation of chlorophenols by means of advanced oxidation processes: a general review. Applied Catalysis B: Environmental, 47(4), 219–256.
• 18. Qi, D., Zhou, J., Xie, G. and Wu, Z. 2016. Optimizing tapping-tree density of rubber (Hevea brasiliensis) plantations in South China. Small-scale Forestry, 15(1), 61–72.
• 19. Qu, J., Shi, J., Wang, Y., Tong, H., Zhu, Y., Xu, L., Wang, Y., Zhang, B., Tao, Y., Dai, X., Zhang, H. and Zhang, Y. 2022. Applications of functionalized magnetic biochar in environmental remediation: A review. Journal of Hazardous Materials, 434, #128841.
• 20. Rong, X., Xie, M., Kong, L., Natarajan, V., Ma, L. and Zhan, J. 2019. The magnetic biochar derived from banana peels as a persulfate activator for organic contaminants degradation. Chemical Engineering Journal, 372, 294–303.
• 21. Shin, J., Lee, Y.-G., Kwak, J., Kim, S., Lee, S.-H., Park, Y., Lee, S.-D. and Chon, K. 2021. Adsorption of radioactive strontium by pristine and magnetic biochars derived from spent coffee grounds. Journal of Environmental Chemical Engineering, 9(2), #105119.
• 22. Sun, K. and Jiang, J.C. 2010. Preparation and characterization of activated carbon from rubber-seed shell by physical activation with steam. Biomass and Bioenergy, 34(4), 539–544.
• 23. Thines, K.R., Abdullah, E.C., Mubarak, N.M. and Ruthiraan, M. 2017. Synthesis of magnetic biochar from agricultural waste biomass to enhancing route for waste water and polymer application: A review. Renewable and Sustainable Energy Reviews, 67, 257–276.
• 24. Tomin, O. and Yazdani, M.R. 2022. Production and characterization of porous magnetic biochar: before and after phosphate adsorption insights. Journal of Porous Materials, 29(3), 849–859.
• 25. Tran-Thuy, T.-M., Tran, T.-P. and Nguyen, D.V. 2023. Cobalt-doped cryptomelane: Surface-tailored oxygen defects and efficiently catalytic ozonation of p-nitrophenol. Topics in Catalysis, 66(1), 289–296.
• 26. Wang, B., Zhang, H., Wang, F., Xiong, X., Tian, K., Sun, Y. and Yu, T. 2019. Application of heterogeneous catalytic ozonation for refractory organics in wastewater. Catalysts, 9(3), 241.
• 27. Wang, J. and Chen, H. 2020. Catalytic ozonation for water and wastewater treatment: Recent advances and perspective. Science of The Total Environment, 704, #135249.
• 28. Xiang, W., Zhang, X., Chen, J., Zou, W., He, F., Hu, X., Tsang, D.C.W., Ok, Y.S. and Gao, B. 2020. Biochar technology in wastewater treatment: A critical review. Chemosphere, 252, #126539.
• 29. Xu, Z., Zhou, Y., Sun, Z., Zhang, D., Huang, Y., Gu, S. and Chen, W. 2020. Understanding reactions and pore-forming mechanisms between waste cotton woven and FeCl3 during the synthesis of magnetic activated carbon. Chemosphere, 241, #125120.
• 30. Yi, Y., Huang, Z., Lu, B., Xian, J., Tsang, E.P., Cheng, W., Fang, J. and Fang, Z. 2020. Magnetic biochar for environmental remediation: A review. Bioresource Technology, 298, #122468.
• 31. Yu, J., Xiao, K., Yang, J., Yu, W., Pei, K., Zhu, Y., Wang, J., Liang, S., Hu, J., Hou, H. and Liu, B. 2019. Enhanced sludge dewaterability and pathogen inactivation by synergistic effects of zero-valent iron and ozonation. ACS Sustainable Chemistry & Engineering, 7(1), 324–331.
• 32. Zhao, Q., Xu, T., Song, X., Nie, S., Choi, S.-E. and Si, C. 2021. Preparation and application in water treatment of magnetic biochar. Frontiers in Bioengineering and Biotechnology, 9, #769667.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).