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Influence of inorganic additives on morphology of electrospun fibres

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: This paper describes the effect of inorganic additives and operating parameters of an electrospinning process on electrospun fiber diameters and morphology. Design/methodology/approach: Application of different solvents and process parameters impact characteristics of the micro and nanofibers made of PEO and also PVA with CuOAc. Findings: The results show that the three parameters (volumetric charge density, distance from nozzle to collector, and viscosity) have the most significant effect on the electrospun fiber morphology. The nano- and microfibers produced were characterized by scanning electron microscopy as well as with use of image analyzing tool DigitalMicrograph. Changes in length of stream and volatility of the solvent influence the shape of the fibres and internal solution load. The resulting fibre shape shows that for shorter distances the process was unstable, and the morphology of the filaments from a longer distance shows the gradual stabilization and indicates optimal process parameters. Practical implications: Based on the research carried out it is clear that micro and nanofiber characteristics vary widely depending on prepared solutions and process parameters. Originality/value: It was confirmed that inorganic additives, solvent type and process parameters have an effect on morphological aspects of produced micro and nanofibres.
Rocznik
Strony
64--71
Opis fizyczny
Bibliogr. 11 poz., rys., tab
Twórcy
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
Bibliografia
  • [1] D. Li, Y. Xia; Electrospinning of Nanofibers: Reinveenting the Wheel, Advenced Materials 16/14 (2004) 1151-1170.
  • [2] R.W. Kelsall, I.W. Hamley, M. Geoghegan, Nanotechnologies, PWN; Warsaw, 2009 (in Polish).
  • [3] U. Stolarczyk, K. Stolarczyk, Chemical industry 86 (2007) 797-799.
  • [4] T. Toivo Kodas, J. Mark Hampden-Smith, The Chemistry of Metal CVD, 1994.
  • [5] S. Megelski, J.S. Stephens, D.B. Chase, J.F. Rabolt, Micro-and nanostructured surface morphology on electrospun polymer fibres, Macromolecules 35 (2002) 8456-8466.
  • [6] M. Bognitzki,H. Hou, M. Ishaque, T. Fresk, M. Hellwig, C. Schwarte, A. Scharper, J.H. Wendorff, A. Greiner, Polymer, metal and hybryd nano-and mesotubes by coating degradable polymer template fibres (TUFT Process), Advanced Materials 12 (2000) 637-640.
  • [7] H. Hou, Z. Jun, A.Reuning, A. Schaper, J.W. Wendorff, A. Gringer, Poly(p-Xylylene) nanotubes by coating and removal of ultrathin polymer template fibres, Makromolecules 35 (2002) 2429-2431.
  • [8] D. Li, G. Ouyang, J.T. McCann, Y. Xia, Collecting electrospun nanofibres with patterned electrodesm, Nano Letters 5 (2005) 913-916.
  • [9] Z. Sun, E. Zussman, A.L. Yarin et al., Compound coreshell polymer nanofibres by co-electrospinning, Advenced Materials 15 (2003) 1929-1932.
  • [10] L.A. Dobrzański, B. Nieradka, M. Macek, W. Matysiak, Influence of the electrospinning parameters on the morphology of composite nanofibers, Archives of Materials Science and Engineering 69/1 (2014) 32-37.
  • [11] L.A. Dobrzański, A. Hudecki, Structure, geometrical characteristics and properties of biodegradable micro- and polycaprolactone nanofibers, Archives of Materials Science and Engineering 70/1 (2014) 5-13.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-20ec0f4b-e8d0-4eb1-967c-5cea2fd93384
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