High-temperature and mechanochemical synthesis of Sm 5VO 10 and its unknown properties

• Autorzy: Kwiatkowski Kamil , Piz Mateusz , Filipek Elżbieta

Identyfikatory

DOI

10.24425/cpe.2023.147403

• Konferencja: 24th Polish Conference of Chemical and Process Engineering, 13-16 June 2023, Szczecin, Poland. Guest editor: Prof. Rafał Rakoczy
• Języki publikacji: EN

Abstrakty

EN

In the presented work, the conditions of the high-temperature and mechanochemical method for the synthesis of compound Sm 5VO 10 and their influence on its physicochemical properties were studied. The following methods were used for the study: X-ray powder diffraction (XRD), differential thermal analysis (DTA), infrared spectroscopy (FTIR), ultraviolet and visible light spectroscopy (UV–VIS–DRS), scanning electron microscopy (SEM-EDX), and laser beam diffraction spectrometry (LDS). Based on the results, it was determined that the compound Sm 5VO 10 is thermally stable in air atmospheres up to 1475 °C, crystallises in a monoclinic system, and its structure is made up of oxygen VO 4 and SmO 8 polyhedra. The estimated energy gap value for nanometric, mechanochemically obtained Sm 5VO 10 was about 3.20 eV, and for the microcrystalline, obtained with the high-temperature method, was about 2.75 eV. The established physicochemical characterisation of Sm 5VO 10 initially showed that the compound could find potential applications, e.g. as a photocatalyst for water purification or as a component of new optoelectronic materials.

Słowa kluczowe

EN

high temperature and mechanochemical synthesis; Sm5VO10 compound; thermal stability; XRD; semiconductor

PL

synteza wysokotemperaturowa; synteza mechanochemiczna; związek Sm5VO10; stabilność termiczna; XRD; Półprzewodnik

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering : New Frontiers
• Rocznik: 2023
• Tom: Vol. 44, nr 4
• Strony: art. no. e44
• Opis fizyczny: Bibliogr. 29 poz., rys., tab., wykr.

Twórcy

autor

Kwiatkowski Kamil

• West Pomeranian University of Technology in Szczecin, Faculty of Chemical Technology and Engineering, Piastów 42, 71-065 Szczecin, Poland

• https://orcid.org/0000-0003-4693-7563

autor

Piz Mateusz

• West Pomeranian University of Technology in Szczecin, Faculty of Chemical Technology and Engineering, Piastów 42, 71-065 Szczecin, Poland

• https://orcid.org/0000-0003-4856-9223

autor

Filipek Elżbieta

• West Pomeranian University of Technology in Szczecin, Faculty of Chemical Technology and Engineering, Piastów 42, 71-065 Szczecin, Poland

• https://orcid.org/0000-0002-7115-2613

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025)