Solid-solid intercalation and optical properties of VO-8-hydroxyquinoline decoration of layered silicate magadiite

• Autorzy: Zhang Y.

Identyfikatory

DOI

10.1515/msp-2018-0023

• Języki publikacji: EN

Abstrakty

EN

Coordination of vanadyl (VO²⁺) ions with 8-hydroxyquinoline (8Hq) in the interlayer space of layered silicate magadiite (mag) was realized by solid-solid intercalation. Composition, structure and morphology of this compound were studied by X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The obtained results indicate that the basal spacing of decorated mag increased after intercalation and suggest that VO-8Hq decorated into the interlayer of mag (VO-mag-8Hq) was successfully synthesized for the first time. Optical properties of VO-mag-8Hq were studied by ultraviolet-visible (UV-Vis) and photoluminescence spectroscopy (PL). The findings reveal that VO-8Hq complexes in the interlayer space exhibit extraordinary fluorescence properties and the confined space of mag influences the optical properties of VO-8Hq complexes.

Słowa kluczowe

EN

magadiite; decoration; composite materials; multilayer structure; luminescence

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2018
• Tom: Vol. 36, No. 1
• Strony: 134--140
• Opis fizyczny: Bibliogr. 42 poz., rys., tab.

Twórcy

autor

Zhang Y.

• School of Chemistry, Dalian University of Technology, Dalian 116024, PR China

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).