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Evaluation of Potassium Perchlorate as a Burning Rate Modifier in Composite Propellant Formulations

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The burning rate of a solid composite propellant is one of its most important ballistic properties. To achieve a specified burning rate, transition metal oxides are used as burning rate modifiers. However, addition of transition metal oxides creates inertness in the composition. To avoid such inertness, an attempt has been made to incorporate potassium perchlorate (KP) as a burning rate modifier by partially replacing ammonium perchlorate (AP), up to the 10% level, and the composition was then studied in detail for its mechanical, thermal and ballistic properties. The data revealed that no change occurred in the case of the mechanical properties, however, the thermal stability decreased as the KP content was increased. The burning rate data revealed that on incorporation of 10% KP, there was an enhancement in the burning rate of up to 35% in comparison to the original composite propellant formulation, but beyond this no enhancement in burning rate was observed, indicating that the optimum content for KP in the composition had been reached.
Rocznik
Strony
231--245
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
autor
  • High Energy Materials Research Laboratory, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Pune-411021, India
autor
  • High Energy Materials Research Laboratory, Pune-411021, India
  • Bhattacharya
Bibliografia
  • [1] Oberth A.E., Bruenner R.S., Polyurethane-based Propellants, in: Propellants, Manufacturing, Hazards and Testing, (Boyers C., Klager K., Eds.), American Chemical Society, Washington D.C., 1969, pp. 84-121; ISBN 9780841200890.
  • [2] Sayles D.C., Ala H., Solid Propellant Compositions and Method of Modifying Propellant Burning Rate Using Ferrocene Derivatives, US patent 3447981, 1969.
  • [3] Kishore K., Sunitha M.R. Effect of Transition Metal Oxide on Decomposition and Deflagration of Composite Solid Propellant System: A Survey, AIAA J., 1979, 17, 1118-1125.
  • [4] Bowker M., Practicalities: What is a Catalyst, in: The Basics and Application of Heterogeneous Catalysis, Oxford University Press, New York, 1998, pp. 32-62; ISBN 9780198559580.
  • [5] Boggs T.L., Zurn D.E., Cordes H.F., Covino J., Combustion of Ammonium Perchlorate and Various Inorganic Additive, J. Propul. Power, 1988, 4, 27-40.
  • [6] Singh G., Pandey D.K., Studies on Energetic Compounds. Part 36: Evaluation of Transition Metal Salts of NTO as Burning Rate Modifiers for HTPB-AN Composite Solid Propellants, Combust. Flame, 2003, 135(1-2), 145-150.
  • [7] Gore G.M., Bhatewara R.G., Tipare K.R., Nazare A.N., Asthana S.N., Studies on Ferrocene Polyglycol Oligomer − Burning Rate Modifier for Composite Propellants, J. Propul. Power, 2004, 20(4), 758-760.
  • [8] Saravanakumar D., Sengottuvelan N., Narayanan V., Kandaswamy M., Varghese T.L., Burning Rate Enhancement of a High Energy Rocket Composite Solid Propellant Based on Ferrocene Grafted Hydroxyl-terminated Polybutadiene Binder, J. Appl. Polym. Sci., 2011, 119(5), 2517-2524.
  • [9] Bogs T.L., Kraeutle K.J., Zurn D.E., Decomposition, Pyrolysis, and Deflagration of Pure and Isomorphously Doped Ammonium Perchlorate, AIAA J., 1972, 10(1), 15-16.
  • [10] Ishitha K., Ramakrishna P.A., Enhancing Composite Solid Propellant Burning Rates with Potassium Doped Ammonium Perchlorate − Part I, J. Propul. Power, 2014, 30(2), 277-284.
  • [11] Ishitha K., Ramakrishna P. A., Enhancing Composite Solid Propellant Burning Rates with Potassium Doped Ammonium Perchlorate − Part 2, J. Propul. Power, 2014, 30(4), 876-882.
  • [12] Seetharamacharyulu D., Verneker V.R.P., Mallya R.M., Combustion and Thermal Decomposition of a Binary Oxidiser System: Ammonium Perchlorate − Potassium Perchlorate, Combust. Sci. Technol., 1981, 27, 19-30.
  • [13] Dey A., Sikder A.K., Talawar M.B., Chottopadhyay S., Towards New Directions in Oxidizers/Energetic Fillers for Composite Propellants: an Overview, Cent. Eur. J. Energ. Mater., 2015, 12(2), 377-399.
  • [14] Dickinson L.A., Capener E.L.R., Kier J., Research on Unstable Combustion in Solid Propellant Rockets, Air Force Office of Scientific Research Washington, D.C. 20333, AD612178, 1965.
  • [15] Adicoff A., Ayres W.M., Hills M.E., McBride W.R., Modified Ammonium Perchlorate Incorporating Potassium, Permanganate, and Dichromate Dopants (u), Research Department, Naval Weapon Center, AD 518421, 1971.
  • [16] Gupta G., Jawale L., Mehilal, Bhattacharya B., Various Methods for the Determination of the Burning Rates of Solid Propellants − An Overview, Cent. Eur. J. Energ. Mater., 2015, 12(3), 593-620.
  • [17] Jawale L.S., Dey C., Mehilal, Gupta M., Bhattacharya B., Effect of Experiment Environment on Calorimetric Value of Composite Solid Propellants, Def. Sci. J., 2013, 63(5), 467-472.
  • [18] Beckstead M.W., Derr R.L., Price C.F., The Combustion of Solid Monopropellants and Composite Propellants, 13th Symp. (Int.) on Combustion, The Combustion Institute, Pittsburgh, Russia, 1971, 1047-56.
  • [19] Klager K., Zimmerman G.A., Steady Burning Rate and Affecting Factors: Experimental Results, in: Nonsteady Burning and Combustion Stability of Solid Propellants, (Luca L.D., Price E., Summerfield M., Eds.), Progress in Astronautics and Aeronautics, Washington, D.C., 1992, Vol. 143, pp. 59-105; ISBN 1-56347-014-4.
  • [20] Determination of Potassium Perchlorate Content, J.S.S. 6810-58:2000, Revision No. 2.
  • [21] Sutton P.G., Biblarz O., Solid Propellant Rocket Fundamentals, in: Rocket Propulsion Elements, John Wiley & Sons, New York, 2000, pp. 417-473; ISBN 0471326429.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1f404871-c21e-48cf-8eef-5248ffc05fd9
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