Dicyanovinyl end-capped 9,10-bis (phenylethynyl) anthracenes for organic solar cells

• Autorzy: Danel K. S. , Michalski O. , Usatenko Z. , Sanetra J. , Nowak E. M.

Identyfikatory

DOI

10.4467/2353737XCT.18.004.7955

Warianty tytułu

PL

9,10-bis (fenyloetynolo) antraceny z peryferyjnymi grupami dicyjanowinylowymi dla ogniw słonecznych

• Języki publikacji: EN

Abstrakty

EN

A series of 9,10-bis(phenylethynyl)anthracene dicyanovinyl end-capped derivatives have been used in bulk heterojunction (BHJ) photovoltaic cells prepared by the solution process. The compounds were excessively decorated with moieties enhancing solubility to avoid spontaneous crystallisations in the blends. The topology of the dyes is of the acceptor-donor-acceptor (A-D-A) type. The quantum chemical calculations were done at the B3LYP/6-31G(d) level of theory and HOMO-LUMO levels were calculated. The solar cells’ configuration was as follows: ITO/PEDOT:PSS/P3HT(P3OT)dyes/Al and parameters characterising them, open-circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF) and power conversion efficiency (PCE) are presented. Anthracene based A-D-A molecules showed photovoltaic activity with an average power conversion efficiencies (PCE) of 2.7%.

PL

Zsyntetyzowano grupę związków na osnowie 9,10-bis(fenyloetynylo)antracenu z peryferyjnymi grupami eletrono-akceptorowymi typu dicyjanowinylenu. Związki zmodyfikowano grupami funkcyjnymi zwiększającymi ich rozpuszczalność i utrudniającymi krystalizację. Przygotowano komórki fotowoltaiczne o strukturze objętościowej metodą wirową. Obliczenia kwantowo-chemiczne przeprowadzono przy funkcjonale B3LYP na poziomie 6-31G(d) i wyliczono energię poziomów elektronowych HOMOLUMO. Opisane ogniwa scharakteryzowano podając następujące parametry: sprawność urządzenia (PCE), współczynnik wypełnienia (FF), napięcie rozwarcia (Voc) i prąd zwarcia (Jsc). Skonstruowane urządzenie o konfiguracji: ITO/PEDOT:PSS/P3HT(P3OT)barwnik/Al osiągnęło sprawność 2.7%.

Słowa kluczowe

EN

anthracene; BPEA; solar cells; donor-acceptor systems; bulk-heterojunction cells

PL

antracen; BPEA; ogniwa słoneczne; układy donorowo-akceptorowe; komórki objętościowe

• Wydawca: Wydawnictwo Politechniki Krakowskiej im. Tadeusza Kościuszki
• Czasopismo: Technical Transactions
• Rocznik: 2018
• Tom: Vol. 115, iss. 1
• Strony: 47--59
• Opis fizyczny: Bibliogr. 48 poz., wz., tab., wykr.

Twórcy

autor

Danel K. S.

• Institute of Chemistry, Agricultural University

autor

Michalski O.

• Institute of Chemistry, Agricultural University

autor

Usatenko Z.

• Institute of Physics, Cracow University of Technology

autor

Sanetra J.

• Institute of Physics, Cracow University of Technology

autor

Nowak E. M.

• Faculty of Materials Science and Ceramics, AGH University of Science and Technology

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Uwagi

EN

KD and OM would like to thank for the financial support from the basic funding of the University of Agriculture in Krakow DS-3711/ICh/17.

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).