Polyoxometalate Intercalated MgAl-Layered Double Hydroxide for Degradation of Malachite Green

• Autorzy: Hanifah Yulizah , Mohadi Risfidian , Mardiyanto , Lesbani Aldes

Identyfikatory

DOI

10.12912/27197050/157093

• Języki publikacji: EN

Abstrakty

EN

Improving the selectivity of photocatalysis of LDH pristine (MgAl-LDH) and LDH composite (MgAl-SiW₁₂O₄₀] and MgAl-[PW₁₂O₄₀]) was synthesized and used for degraded malachite green (MG). The effects of the amount of catalyst, pH value, and reaction times on degradation performance were discussed. MG degraded better composites than LDH pristine. The results indicated that MgAl-LDH was successfully synthesized by showing the peak diffractions at angles 10.39°(003), 20.17°(006), and 34.8°(009). Both kinds of attained MgAl-[SiW₁₂O₄₀] and MgAl-[PW₁₂O₄₀] had the typical structure of LDH that proved by appeared diffraction at 2θ angles 7.73°, 28.6°, 35.6° for MgAl-[PW₁₂O₄₀] and at 2θ angles 8.61°, 24.27°, 34.96° and 66.34° for MgAl-[SiW₁₂O₄₀]. The FTIR result indicates materials used for fifth regeneration, which confirmed the LDH composite structure. The photodegradation activity of MG for pristine MgAl LDH (56.1%), composites MgAl-Pw (84.6%) and MgAl-Si (87.8%), respectively. The successful ability of photodegradation process by the percentage of degradation on material LDH-polyoxometalate composite showed the increasing of photodegradation catalytic and the regeneration ability of LDH pristine.

Słowa kluczowe

EN

LDH; layered double hydroxide; polyoxometalate; photocatalytic; malachite green

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2023
• Tom: Vol. 24, iss. 2
• Strony: 109--119
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Hanifah Yulizah

• Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia

• https://orcid.org/0000-0003-4152-5367

autor

Mohadi Risfidian

• Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia
• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia

• https://orcid.org/0000-0003-4974-4329

autor

Mardiyanto

• Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia

• https://orcid.org/0000-0002-2951-4123

autor

Lesbani Aldes

• Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia
• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32, OganIlir 30662, Indonesia

• https://orcid.org/0000-0001-5054-2324

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).