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Studies of colored varieties of Brazilian quartz produced by gamma radiation

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Języki publikacji
EN
Abstrakty
EN
Quartz occurs in Brazil mainly in two geological environments, called pegmatitic and hydrothermal. The quartz of hydrothermal origin occurs mainly in geodes in the basaltic rocks of the Parana Basin and the quartz formed in fracture systems of the Espinhaço Range. Quartz of pegmatitic origin forms often the core of pegmatites. The detailed mechanism of color center formation of these two types of quartz will be investigated by spectroscopic and chemical analysis. Until yet, it can be shown that due to chemical differences of the nature of mineral forming fluids, the two types behave differently. All quartz contains mainly traces of iron, aluminum, lithium and some amounts of water. The quartz of hydrothermal origin incorporated much structurally bound water, and despite some similarities with the chemical composition of pegmatitic quartz, this high water content is the reason for the formation of silanol radicals, giving green color to the quartz. The main difference in chemical composition of pegmatitic quartz is the presence of higher amounts of Al and Li, responsible for the brownish and yellowish colors formed by irradiation.
Czasopismo
Rocznik
Strony
469--474
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
Bibliografia
  • 1. Aines RD, Rossman GR (1986) Relationship between radiation damage and trace water in zircon, quartz and topaz. Am Mineral 71:1186–1193
  • 2. Bachheimer JP (2000) Comparative NIR and IR examination of natural, synthetic and irradiated synthetic quartz. Eur J Mineral 12:975–986
  • 3. Cannas C, Casu M, Musinu A, Piccaluga G (2005) 29 Si CPMAS and near-IR study of sol-gel microporous sílica with tunable surface area. J Non-Cryst Solids 351:3476–3482
  • 4. Chaves MLSC, Brito W, Favacho-Silva MD (1999) Typology of the gemmological quartz deposits from Minas Gerais and adjacents regions. In: Proc of the VII Geology Symposium of West-Center and X Geology Symposium of Minas Gerais State, Brazil, SBG, 42
  • 5. Guzzo PL (1992) Characterization of the structures impurities and defects centers related to Al and OH in natural quartz. Dissertation Mechanical Engineering Department, Campinas University
  • 6. Guzzo PL, Iwasaki F, Iwasaki H (1997) Al-related centers in relation to α-irradiation. Phys Chem Miner 24:254–263
  • 7. Hebert LB, Rossman GR (2008) Greenish quartz from the Thunder Bay Amethyst Mine Panorama, Thunder Bay, Ontario, Canada. Can Mineral 46:111–124
  • 8. Iwasaki F, Iwasaki H (1993) Impurity species in synthetic and Brazilian natural quartz. Jpn J Appl Phys 32:893–901
  • 9. Iwasaki H, Iwasaki F, Oliveira VAR et al. (1991) Impurity contents characterization of Brazilian quartz lascas. Jpn J Appl Phys 30;7:1489–1495
  • 10. Kaiser P (1974) Drawing-induced coloration in vitreous silica fibers. JOSA 64:475–481
  • 11. Laudise RA, Barnes RL (1988) Perfection of quartz and its connection to crystal growth. IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control 35:277–286
  • 12. McClure SF, Kane RE, Sturman N (2010) Gemstone enhancement and its detection in the 2000s. Gems & Gemology 46:218–240
  • 13. McLaren AC, Pitkehtly DR (1982) The twinning microstructure and growth of amethyst quartz. Phys Chem Miner 8:121–135
  • 14. Nunes EHM (2005) Investigation of color formation in quartz from São José da Safira (MG). M Sc dissertation, Nuclear Technology Development Center – CDTN, BH, Brazil
  • 15. Nunes EHM, Lameiras FS (2005) The optical absorption of gamma irradiated and heat-treated natural quartz. Mater Res 8:305–308
  • 16. Rela PR, Calvo WAP, Napolitano CM et al. (2005) Qualification program of a small size continous run multipurpose gamma irradiation of Cobalt-60. International Nuclear Atlantic Conference, INAC 2005, Santos, Brazil, 38/7-2/8/2005, ABEN
  • 17. Rossman GR (1994) Colored varities of the silica minerals. Rev Mineral 29:433–467
  • 18. Sahl R (2011) Defect-related luminescence in silico dioxide network: A review. In: Basu S (ed) Crystalline silicon – properties and uses. InTech, Rijeka, Croatia, pp 136–172
  • 19. Schultz-Güttler RA (2006) Blau-Quarze aus Minas Gerais. Z Dt Gemmolog Ges 55:135–136
  • 20. Schultz-Güttler RA, Henn U, Milisenda CC (2008) Grüne Quarze-Farbursachen und Behandlung. Gemmologie 57;1:61–71
  • 21. Trindade NM, Rubo RA, Saeki MJ, Scalvi RFM (2006) The optical absorption of thermally treated amethyst. Vacuum Appl Braz J 25:59–63
  • 22. Yamagishi H, Nakashima S, Ito Y (1997) High temperature infrared spectra of hydrous microcrystalline quartz. Phys Chem Miner 24:66–74
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1e0e2b1d-a2e4-45a8-b942-536d2a5e19c5
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