Changes of isotopic composition in gases emitted from wastewater treatment plant - preliminary study

• Autorzy: Stelmach W. , Szarlip P. , Trembaczowski A.

Identyfikatory

DOI

10.2478/eces-2014-0019

Warianty tytułu

PL

Zmiany składu izotopowego gazów emitowanych z oczyszczalni ścieków - badania wstępne

• Języki publikacji: EN

Abstrakty

EN

Investigations of processes occurring during wastewater treatment have progressed beyond the stage of technology. Currently, great numbers of representatives of diverse specialist research apply increasingly sophisticated measurement methods that have not been employed in this field of science. One of the methods is IRMS (Isotope Ratio Mass Spectrometry). Tracking changes in the ratios of biogenic element isotopes is useful in eg identification and monitoring of investigated processes. Since the IRMS technique has hardly been used for investigations of the wastewater treatment process, pilot research should be instigated to determine the isotope ratios occurring naturally in the process. The aim of the study was to determine changes in carbon and nitrogen isotope ratios at the successive stages of the technological line in wastewater treatment plants. The study material comprised: i) suspensions of raw sewage and mixtures of wastewater and activated sludge; ii) gases sampled from the volume of the suspensions; iii) gases sampled from the air above the suspension surface. The research material originated from the facilities of “Hajdow” municipal wastewater treatment plant in Lublin (SE Poland). The samples were analysed for the carbon and nitrogen isotope ratios, and the concentrations of the gases as well as total organic carbon (TOC), inorganic carbon (IC), Kjeldahl nitrogen (KN), dry weight, pH, and Eh were determined. The results obtained suggest that: i) the IRMS technique can be successfully applied in investigations of processes occurring during wastewater treatment; ii) isotope ratios in the carbon and nitrogen compounds (CO2 and N2) both in the suspensions and gases contained therein and in the air above them differ from each other and change at the different stages of the treatment process; iii) further research is indispensable in order to identify processes responsible for fractionation of carbon and nitrogen isotopes.

PL

Badania procesów zachodzących w trakcie oczyszczania ścieków dawno wyszły już poza fazę technologiczną. Obecnie zaobserwować można coraz większe grono przedstawicieli różnych specjalności wykorzystujących do badań coraz bardziej wyszukane metody pomiarowe, które do tej pory nie były wykorzystywane w tym obszarze. Jedną z takich metod jest IRMS (Isotope Ratio Mass Spectrometry). Śledzenie zmian stosunków izotopów pierwiastków biogenicznych jest przydane m.in. w identyfikacji i monitorowaniu badanych procesów. Ponieważ technika IRMS praktycznie nie była do tej pory wykorzystywana do badania procesu oczyszczania ścieków, dlatego niezbędne są pilotażowe badania pozwalające na wyznaczenie naturalnie występujących stosunków izotopowych w tym procesie. Celem pracy było określenie zmian stosunków izotopów węgla i azotu na wybranych stopniach ciągu technologicznego oczyszczalni ścieków. Materiał badawczy obejmował: i) zawiesiny ścieków surowych i mieszaniny ścieków i osadu czynnego, ii) próby gazów z objętości zawiesin; iii) próby gazów z powietrza sponad powierzchni zawiesin. Materiał badawczy pochodzi z miejskiej oczyszczalni ścieków „Hajdów” w Lublinie (SE Polska). Próbki analizowano pod kątem stosunków izotopów stabilnych węgla i azotu, stężeń gazów oraz zawartości całkowitego węgla organicznego (TOC), węgla nieorganicznego (IC), azotu Kjeldahla (KN), suchej masy, pH i Eh. Uzyskane wyniki sugerują, że: i) technika IRMS może być z powodzeniem stosowana w badaniach procesów zachodzących podczas oczyszczania ścieków, ii) stosunki izotopowe w związkach węgla i azotu (CO2 i N2), zarówno w zawiesinach, jak i w zawartych w nich gazach oraz w powietrzu nad zawiesiną, różnią się od siebie i zmieniają się na różnych etapach procesu obróbki, iii), niezbędne są dalsze badania w celu określenia procesów odpowiedzialnych za frakcjonowania izotopów węgla i azotu.

Słowa kluczowe

EN

IRMS; stable isotopes; wastewater; activated sludge; gas emission

PL

IRMS; izotopy stabilne; ścieki; osad czynny; emisja gazów

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. S
• Rocznik: 2014
• Tom: Vol. 21, nr 2
• Strony: 245--254
• Opis fizyczny: Bibliogr. 42 poz., wykr.

Twórcy

autor

Stelmach W.

• Institue of Agrophysics, Polish Academy of Science, ul. Doświadczalna 4, 20-290 Lublin, Poland

autor

Szarlip P.

• Institue of Agrophysics, Polish Academy of Science, ul. Doświadczalna 4, 20-290 Lublin, Poland

autor

Trembaczowski A.

• Institue of Agrophysics, Polish Academy of Science, ul. Doświadczalna 4, 20-290 Lublin, Poland
• Mass Spectrometry Laboratory, Institute of Physics, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 1, 20-031 Lublin, Poland

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