Electrochemical behavior and conductivity measurements of electropolymerized selenophene-based copolymers

Alakhras, F.

doi:10.1515/msp-2015-0007

Artykuł - szczegóły

Tytuł artykułu

Electrochemical behavior and conductivity measurements of electropolymerized selenophene-based copolymers

Autorzy

Alakhras F.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

DOI

10.1515/msp-2015-0007

Warianty tytułu

Języki publikacji

Abstrakty

Electrochemical copolymerization of selenophene and thiophene was performed at a constant electrode potential. The obtained homopolymer films and copolymers were studied and characterized with cyclic voltammetry and conductivity measurements, from which conductivity values around 13.35 S cm^-1 were determined. The influence of the applied electropolymerization potential and the monomer feed ratio of selenophene and thiophene on the copolymers properties was investigated. The obtained copolymers showed good stability of the redox activity in an acetonitrile-based electrolyte solution. At higher polymerization potentials and at higher concentrations of thiophene in the feed, more thiophene units were incorporated into the copolymer chain. The conductivities of the copolymers were between those of homopolymers, implying that oxidation of both monomers was possible and the copolymer chains might accordingly be composed of both selenophene and thiophene units.

Słowa kluczowe

electropolymerization intrinsically conducting polymers polythiophene polyselenophene

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2015

Tom

Vol. 33, No. 1

Strony

25--35

Opis fizyczny

Bibliogr. 63 poz., rys., tab.

Twórcy

autor

Alakhras F.

falakhras@ud.edu.sa

Department of Chemistry, College of Science, University of Dammam 31441 Dammam, Saudia Arabia

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-1df973ac-6bb6-444d-975d-955fa944d406