Poly(vinyl chloride)-supported triazoles grafted onto calix[4]arene for chromium ions extraction

• Autorzy: Said Ammar , Dardouri Mokhtar , Ammari Fayçel , Ouerghui Abid , Power Nicholas P. , Meganem Faouzi

Identyfikatory

DOI

10.14314/polimery.2021.11.6

Warianty tytułu

PL

Ekstrakcja jonów chromu z użyciem kaliks[4]arenu modyfikowanego trizolami szczepionego poli(chlorkiem winylu)

• Języki publikacji: EN

Abstrakty

EN

A new suitable material was synthesized using click reaction between dialkynyl-p-tert-butylcalix[4]arene and poly(vinyl chloride) azide (PVC-N3 ). This novel dialkynyl-p-tert-butylcalix[4]arene with triazole groups grafted onto PVC polymer (PVC-0.75CX[4]) has an excellent extraction capability for chromium ions from aqueous solutions. It shows a unique ability to extract chromium (VI) ions from aqueous solutions, thanks to the soft cavity, the presence of π-triazole rings and hydrogen bonds. Cr (VI) ion sorption capacity is 95.5% at pH = 3.

PL

W wyniku reakcji typu click między dialkynylo-p-tert-butylokaliks[4]arenem a azydkiem poli(chlorku winylu) (PVC-N3 ) otrzymano nowy związek − dialykynylo-p-tert-butylokaliks[4]aren z grupami triazolowymi szczepiony na poli(chlorku winylu) (PVC-0.75CX[4]). Wykazuje on wyjątkową zdolność do ekstrakcji jonów chromu(VI) z roztworów wodnych, dzięki sprężystej wnęce, obecności pierścieni π-triazolowych i wiązań wodorowych. Zdolność do sorpcji jonów Cr(VI) wynosi 95,5% przy pH = 3.

Słowa kluczowe

EN

calix[4]arene; poly(vinyl chloride); triazole; chromium(VI) extraction

PL

calix[4]arene; poly(vinyl chloride); triazole; chromium(VI) extraction; kaliks[4]aren; poli(chlorek winylu); ekstrakcja jonów chromu(VI)

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
• Czasopismo: Polimery
• Rocznik: 2021
• Tom: T. 66, nr 11-12
• Strony: 611--618
• Opis fizyczny: Bibliogr. 28 poz, rys. kolor, tab., wykr.

Twórcy

autor

Said Ammar

• University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Organic Chemistry and Applications, Bizerte, 7021 Tunisia
• The Open University, Faculty of Science, School of Life Health & Chemical Sciences, Walton Hall, Milton Keynes MK7 6AA, UK

• https://orcid.org/0000-00030-3541-0854

autor

Dardouri Mokhtar

• University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Organic Chemistry and Applications, Bizerte, 7021 Tunisia

• https://orcid.org/0000-0003-3545-8815

autor

Ammari Fayçel

• University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Organic Chemistry and Applications, Bizerte, 7021 Tunisia

• https://orcid.org/0000-0003-3541-0854

autor

Ouerghui Abid

• University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Organic Chemistry and Applications, Bizerte, 7021 Tunisia
• University of Jendouba, Higher Institute of Biotechnology of Beja, Unit of Functional Physiology and Valorization of Bioresources, Beja, 9000 Tunisia

• https://orcid.org/0000-0001-9419-259X

autor

Power Nicholas P.

• The Open University, Faculty of Science, School of Life Health & Chemical Sciences, Walton Hall, Milton Keynes MK7 6AA, UK

• https://orcid.org/0000-0002-4630-7580

autor

Meganem Faouzi

• University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Organic Chemistry and Applications, Bizerte, 7021 Tunisia

• https://orcid.org/0000-0002-0584-9754

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021)