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Tytuł artykułu

Relative Explosive Strength and Detonation Characteristics of Some Explosive Mixtures Containing Urea and Peroxides

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Several mixtures, based on urea, urea hydrogen peroxide complex (UHP), triacetone triperoxide (TATP) with some inorganic oxidants were studied by means of ballistics mortar with TNT as a reference standard. The detonation pressure, P, detonation velocity, D, detonation heat, Q, and volume of gaseous product at standard temperature and pressure conditions (STP condition) were calculated by the mean of Explo5 V6.3. The relatively high explosive strength of some samples relative to the TNT charge, focuses on the positive influence of hydrogen peroxide presence in these mixtures, with advantage in the form of its complex with urea (i.e. as UHP). This influence connects with hydroxi-radical in the mixture under its initiation (as the first intermediate of this initiation reaction).
Słowa kluczowe
Twórcy
  • University of Pardubice, Faculty of Chemical Technology, Institute of Energetic Materials, 95 Studentská Street, 532 10 Pardubice, Czech Republic
autor
  • University of Pardubice, Faculty of Chemical Technology, Institute of Energetic Materials, 95 Studentská Street, 532 10 Pardubice, Czech Republic
autor
  • Brodarski Institute – Marine Research and Special Technologies, 20 V. Holjevca Avenue, Zagreb 10020, Croatia
autor
  • University of Pardubice, Faculty of Chemical Technology, Institute of Energetic Materials, 95 Studentská Street, 532 10 Pardubice, Czech Republic
Bibliografia
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  • [4] Yin H., G. Wang, F. Du, G. Gong, S. Fan, J. Wang, Z. Zhang, L. Zhang. 1994. “Study on non-TNT rock explosive based on nitrates of urea and ammonia”. Chinese Journal of Energetic Materials (HanNeng CaiLiao) 2(4) : 12-19.
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  • [7] Tamiri Tsippy, Rinat Rozin, Nitay Lemberger, Joseph Almog. 2009. “Urea nitrate, an exeptionally easy-to-make improvised explosive: studies towards trace characterization”. Analytical and Bioanalytical Chemistry 395(2) : 421-428.
  • [8] Matyáš Robert, Jakub Šelešovský. 2009. “Power of TATP based explosives”. Journal of Hazardous Materials 165 : 95-99.
  • [9] Zeman Svatopluk, Waldemar A. Trzciński, Robert Matyáš. 2008. “Some Properties of Explosive Mixtures Containing Peroxides. Part I. Relative Performance and Detonation of Mixtures with Triacetone Triperoxide”. Journal of Hazardous Materials 154 : 192-198.
  • [10] Zeman Svatopluk, Cécile Bartei. 2008. “Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide”. Journal of Hazardous Materials 154 : 199-203.
  • [11] Matyáš Robert, Svatopluk Zeman, Waldemar A. Trzciński, Stanisław Cudziło. 2008. “Detonation Performance of TATP/AN Based Explosives”. Propellants, Explosives, Pyrotechnics 33 : 296-300.
  • [12] Ball C. Matthew, Steven Massey. 1995. “The thermal decomposition of solid urea hydrogen peroxide”. Thermochimica Acta 261 : 95-106.
  • [13] Laha S.C., R. Kumar. 2001. “Selective Epoxidation of Styrene to Styrene Oxide over TS-1 Using Urea–Hydrogen Peroxide as Oxidizing Agent”. Journal of Catalysis 204(1) : 64-70.
  • [14] Li Y., L. Greenwall. 2013. “Safety issues of tooth whitening using peroxide based materials”. British Dent Journal 215 : 29-34.
  • [15] Klopotek A., B. Klopotek, T. Pajer. 1997. “Adducts of hydrogen peroxide with melamine, urea, and polyvinyl-pyrrolidone as modern disinfecting agents“. Pollena: Tłuszcze, Środki Piorące, Kosmetyki 41(5) : 198-202.
  • [16] Suceska Muhamed. 1995. Test Methods for explosives (1st edition). New York, USA: Springer-Verlag.
  • [17] Elbeih Ahmed, Marcela Jungova, Svatopluk Zeman, P. Vavra, Zdenek Akstein. 2012. “Explosive Strength and Impact Sensitivity of Several PBXs Based on Attractive Cyclic Nitramines“. Propellants, Explosives, Pyrotechnics 37 : 329-334.
  • [18] Notice of Czech Mining Authority No. 246/1996 of Law Collect, Establishing more Detailed Conditions for Allowing Explosives, Explosive Objects and Aids into Use, and their Testing, 1966.
  • [19] Hong Zekai, Aamir Farooq, Ethan A. Barbour, David F. Davidson, Ronald K. Hanson. 2009. “Hydrogen Peroxide Decomposition Rate: A Shock Tube Study Using Tunable Laser Absorption of H2O Near 2.5 μm”. Journal of Physical Chemistry A 113(46) : 12919-12925.
Uwagi
EN
This work has been compiled from the paper presented during the 11th International Armament Conference on Scientific Aspects of Armament and Safety Technology, Ryn, Poland, September 19-22, 2016.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1d6657fc-cb6e-4a0a-84ad-b746e6798cc3
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