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Formowanie włókien chityny metodą rozdmuchu przy zastosowaniu cieczy jonowej jako rozpuszczalnika
Języki publikacji
Abstrakty
Chitin is the second most abundant polysaccharide on the Earth after cellulose, therefore there is a tangible need for finding new environmentally-friendly solvents for the manufacture of useful forms of that polymer. Ionic liquids have been recently proposed as a possible type of solvent for chitin and cellulose. The possibility of the dissolution of chitin of various origin in six selected ionic liquids was investigated. Chitin samples were characterised by the main characteristic properties: degree of N-acetylation (by FTIR spectroscopy), degree of crystallinity (by WAXS), average molecular weight (by the viscometric method) and physical form. The studies performed allowed to find the optimum chitin-ionic liquid system based on 1-btyl-3-methylimidazolium acetate for the manufacture of chitin fibres by the solution blow spinning method. Final products were characterized by the same set of parameters as the initial materials.
Chityna jest drugim po celulozie polisacharydem na Ziemi, dlatego istnieje namacalna potrzeba znalezienia nowych i przyjaznych dla środowiska rozpuszczalników do produkcji użytecznych form tego polimeru. Niedawno ciecze jonowe zostały zaproponowane jako możliwe do zastosowania „zielone” rozpuszczalniki chityny i celulozy. W artykule oceniono możliwość rozpuszczania różnego pochodzenia chityny w sześciu wybranych cieczach jonowych. Próbki chityny zostały scharakteryzowane poprzez następujące właściwości: stopień N-acetylacji (spektroskopia FT IR), stopień krystaliczności (WAXS), średnia masa cząsteczkowa (metoda wiskometryczna). Przeprowadzone badania pozwoliły na znalezienie optymalnego systemu cieczy jonowej do wytworzenia włókien chitynowych metodą rozdmuchu. Produkty końcowe zostały scharakteryzowane poprzez ten sam zestaw parametrów, co początkowe polimery.
Czasopismo
Rocznik
Strony
42--48
Opis fizyczny
Bibliogr. 50 poz., rys., tab.
Twórcy
autor
- Lodz University of Technology, Faculty of Material Technologies and Textile Design, Institute of Material Science of Textiles and Polymer Composites, S. Zeromskiego 116, 90-924 Lodz, Poland
autor
- Poznan Science and Technology Park, Adam Mickiewicz University Foundation, Rubiez 46, 61-612 Poznan, Poland
autor
- Institute of Security Technologies “MORATEX”, M. Sklodowskiej-Curie 3, 90-505 Lodz, Poland
autor
- Lodz University of Technology, Faculty of Material Technologies and Textile Design, Institute of Material Science of Textiles and Polymer Composites, S. Zeromskiego 116, 90-924 Lodz, Poland
autor
- Lodz University of Technology, Faculty of Material Technologies and Textile Design, Institute of Material Science of Textiles and Polymer Composites, S. Zeromskiego 116, 90-924 Lodz, Poland
Bibliografia
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1d34c749-c2d2-453f-b0eb-967e4bca5eb1