PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Powiadomienia systemowe
  • Sesja wygasła!
  • Sesja wygasła!
  • Sesja wygasła!
Tytuł artykułu

Selective nickel-iron separation from atmospheric leach liquor of a lateritic nickel ore using the para-goethite method

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The presence of iron in pregnant leach solutions (PLS) is a common problem, and is generally removed using jarosite, goethite, hematite or para-goethite precipitation methods. Although these methods are successfully applied, significant amounts of nickel can be lost. In this study, iron precipitation was performed on a PLS obtained from agitation leaching of a lateritic nickel ore under atmospheric conditions using the para-goethite method. The PLS contained 2.62 g/dm3 Ni, 54.28 g/dm3 Fe and 0.14 g/dm3 Co. During the precipitation tests the effect of pH, time, temperature, and metal concentration were investigated. The influence of the key points, temperature and metal concentration, on nickel loss was explained in reference to SEM and XRD analyses. Ultimately, selective nickel and iron separation was achieved with complete iron precipitation and only 1.2% Ni loss.
Rocznik
Strony
212--226
Opis fizyczny
Bibliogr. 54 poz., rys., tab.
Twórcy
autor
  • Istanbul Technical University, Mining Faculty, Mineral Processing Engineering Department, Istanbul, Turkey
autor
  • Istanbul Technical University, Mining Faculty, Mineral Processing Engineering Department, Istanbul, Turkey
Bibliografia
  • AGATZINI-LEONARDOU S., TSAKIRIDIS P.E., OUSTADAKIS P., KARIDAKIS T. and KATSIAPI A. 2009, Hydrometallurgical process for the separation and recovery of nickel from sulphate heap leach liquor of nickeliferrous laterite ores, Minerals Engineering 22, 1181–1192.
  • ALLEN R.W., HAIGH C.J. and HAMDORF C.J., 1970, An improved method of removing dissolved ferric iron from iron-bearing solution, Australian Patent No. 424, 095.
  • ARREGI V., GORDON A.R. and STEINVEIT G., 1980, The jarosite process––past, present and future, In: Cigan, J.M., Mackey, T.S., OKeefe, T.J. (Eds.), Lead–Zinc–Tin80, TMS–AIME World Symposium on Metallurgy and Environment Control, Warrendale, PA, pp. 97–123.
  • BABCAN J., 1971, Synthesis of jarosite—KFe3(SO4)2(OH)6, Geol. Zb. 22 (2), 299–304.
  • BASTURKCU H. and ACARKAN N., 2016, Leaching behaviour of a Turkish lateritic ore in the presence of additives, Physicochem. Probl. Miner. Process. 52(1), 112−123.
  • BEUKES J.P., GIESEKKE E.W. and ELLIOT W. 2000, Nickel retention by goethite and hematite, Minerals Engineering, 13(14-15), 1573-1579.
  • BISWAS R.K. and BEGUM D.A., 1998, Solvent extraction of Fe3+ from chloride solution by D2EHPA in kerosene, Hydrometallurgy 50, 153–168.
  • BODSON F.J.J., 1972, Recovery of zinc values from zinc plant residue, US Patent No. 3,652, 264.
  • BOXAL J.M. and JAMES S.E., 1986, Experience with the goethite process at National Zinc, In: Dutrizac, J.E., Monhemius, A.J. (Eds.), Iron Control in Hydrometallurgy. Ellis Horwood, Chichester, UK, pp. 676–686.
  • BUBAN K.R., COLLINS M.J. and MASTERS I.M., 1999, Iron control in zinc pressure leach processes, J. Met., 51 (12), 23–25.
  • CARVALHO-E-SILVA M.L., RAMOS A.Y., TOLENTINO H.C.N., ENZWEILER J., NETTO S.M., ALVES M.D.C.M., 2003, Incorporation of Ni into natural goethite: an investigation by X-ray absorption spectroscopy, American Mineralogist, 88, 876–882.
  • CHANG Y., ZHAI X., LI, B. and FU Y. 2010, Removal of iron from acidic leach liquor of lateritic nickel ore by goethite precipitate, Hydrometallurgy, 101, 84–87.
  • CHEN T.T. and CABRI L.J., 1986, Mineralogical overview of iron control in hydrometallurgical processing, In: Dutrizac, J.E., Monhemius, A.J. (Eds.), Iron Control in Hydrometallurgy. Ellis Horwood, England, pp. 19– 55.
  • CORNELL R.M. and SCHWERTMANN U., 1996, The Iron Oxides. Structure, Properties, Reactions, Occurrence and Uses, VCH Verslagsgesellschaft, Weinheim.
  • CORNELL R.M. and SCHWERTMANN U., 2003, The iron oxides: structure, properties, reactions, occurrences and uses, Wiley-VCH GmbH and Co. KGaA, Weinheim.
  • CUBEDDU F., PIASENTIN M., REILLY F., MEREGALLI L. and TOLOMIO M., 1996, The Paragoethite process at the Enirisorse–Porto Vesme plant, In: Dutrizac, J.E., Harris, G.B. (Eds.), Proceedings of the Second International Symposium on Iron Control in Hydrometallurgy. Canadian Institue of Mining,Metallurgy and Petroleum, Ottawa, pp. 147–161.
  • DEMOPOULOS G.P. and GEFVERT D.L., 1984, Iron (III) removal from base metals electrolyte solutions by solvent extraction, Hydrometallurgy, 12, 299–315.
  • DUTRIZAC J.E., 1980, The physical chemistry of iron precipitation in the zinc industry, In: Cigan, J.M., Mackey, T.S., OKeefe, T.J. (Eds.), Lead–Zinc–Tin80, TMS–AIME World Symposium on Metallurgy and Environment Control, Warrendale, PA, pp. 532–563.
  • DYER L., SU B. and ASSELIN E., 2012, Cobalt loss due to iron precipitation in ammoniacal carbonate solutions, Hydrometallurgy, 125–126, 144–147.
  • FULLER C.C., DAVIS J. A. and WAYCHUNAS G.A., 1993, Surface chemistry of ferrihydrite: Part II. Kinetics of arsenate adsorption and coprecipitation, Geochim. Cosmochim. Acta, 57, 2271-2282.
  • HAIGH C. and WOOD J., 1972, Jarosite process boosts zinc, World Min. (September), 34–38.
  • HARVEY D., 2000, Modern Analytical Chemistry, McGraw-Hill.
  • HOCHELLA M.F., Jr., KASAMA T., PUTNIS A., PUTNIS C., MOORE J.N., 2005, Environmentally important, poorly crystalline Fe/Mn hydrous oxides: Ferrihydrite and a vernadite-like mineral from a massive acid mine drainage system, American Mineralogist, 90, 718-724.
  • HOH Y., WANG J. and MA T., 1983, Solvent extraction separation study of Fe(III) and Zn(II) from aqueous solutions with D2EHPA and D2EHPA mixed with TBP in hydrocarbon diluents, In: Proceedings of ISEC’ 83.
  • ISMAEL M.R.C. and CARVALHO J.M.R. 2003, Iron recovery from sulphate leach liquors in zinc hydrometallurgy, Minerals Engineering, 16, 31–39.
  • JAMBOR J.L. and DUTRIZAC J.E., 1998, Occurrence and constitution of natural and synthetic ferrihydrite, a widespread iron oxyhydroxide, Chemical Reviews, (7), 2549–2585.
  • LOAN M., ST PIERRE T.G., PARKISNON G.M., NEWMAN O.M.G. and FARROW J.B., 2002, Identifying nanoscale ferrihydrite in hydrometallurgical residues, Journal of Metals, 54 (12), 40–43.
  • LOAN M., NEWMAN O.M.G., COOPER R.M.G., FARROW J.B. and PARKISNON G.M, 2006, Defining the Paragoethite process for iron removal in zinc hydrometallurgy, Hydrometallurgy, 81, 104–129.
  • LUPI C. and PILONE D., 2000, Reductive stripping in vacuum of Fe(III) from D2EHPA, Hydrometallurgy, 57 (3), 201–207.
  • MANCEAU P.H. and DRITIS V.A., 1993, Local structure of ferrihydrite and feroxyhite by EXAFS spectrometer, Clay Minerals, 28, 165-184.
  • MCCRISTAL T.G. and MANNING J., 1998, Conversion of the Pasminco Hobart smelter to para-goethite. In: Dutrizac, J.E., Gonzales, J.A., Bolton, G.L., Hancock, P. (Eds.), Zinc and Lead Processing. The Metallurgical Society of CIM, Montreal, Canada, pp. 439– 453.
  • MCDONALD R.G. and WHITTINGTON B.I., 2008, Atmospheric acid leaching of nickel laterites review: Part I sulphuric acid technologies, Hydrometallurgy, 91, 35–55.
  • MEALEY M., 1973, Hydrometallurgy plays a big role in Japan's new zinc smelter, Eng. Min. J., 174, 82–84.
  • MEYER E.H.O., HOWARD G., HEAGLE R. and BECK R.D., 1996, Iron control and removal at the Zinc Corporation of South Africa. In: Dutrizac, J.E., Harris, G.B. (Eds.), Iron control and Disposal. Canadian Institute of Mining, Metallurgy & Petroleum, Montreal, Canada, pp. 163-182.
  • ONAZAKI A. and KURAMOCHI S., 1986, The Versatic acid process––a solution in the zinc industry, In: Dutrizac, J.E., Monhemius, A.J. (Eds.), Iron Control in Hydrometallurgy. Ellis Horwood, Chichester, UK, pp. 297–311.
  • PAKARINEN J. and PAATERO E. 2011, Recovery of manganese from iron containing sulfate solutions by precipitation, Minerals Engineering, 24, 1421–1429.
  • PICKERING R.W. and HAIGH C.J., 1970, Treatment of zinc plant residue, US Patent No. 3, 493, 365.
  • PRESTON J.S., 1985, Solvent extraction of metals by carboxylic acids, Hydrometallurgy, 14, 171–188.
  • RITCEY G.M., 2006, Solvent extraction, principles and application to process metallurgy, Vol. 1, 2nd ed. G.M. Ritcey & Associates incorporation, Ottawa.
  • ROPENAC A.V., 1986, Hematite––the solution to a disposal problem––an example from the zinc industry, In: Dutrizac, J.E., Monhemius, A.J. (Eds.), Iron Control in Hydrometallurgy. Ellis Horwood, Chichester, UK, pp. 730–741.
  • SATO T. and NAKAMURA T., 1971, Extraction of iron (III) from sulphuric and hydrochloric acid solutions by di-2(ethylhexyl)phosphoric acid, In: Proceedings of ISEC’ 71, vol. 1. Society of Chemical Industry, London, pp. 238–248.
  • SATO T., NAKAMURA T. and IKENO M., 1985, The extraction of iron (III) from aqueous acid solutions by di(2-ethylhexyl)phosphoric acid, Hydrometallurgy, 15, 209–217.
  • SAJI J., RAO T.P., IYER C.S.P. and REDDY M.L.P., 1998, Extraction of iron(III) from acidic chloride solutions by Cyanex 923, Hydrometallurgy, 49, 289–296.
  • SCOTT J.D., DONYINA D.K.A. and MOULAND J.E., 1986, Iron-the good with the bad––Kidd Creek zinc plant experience, In: Dutrizac, J.E., Monhemius, A.J. (Eds.), Iron Control in Hydrometallurgy. Ellis Horwood, Chichester, UK, pp. 666–675.
  • SCHWERTMANN U. and R. M. CORNELL. 1991, Iron Oxides in the Laboratory, Weinheim: VCH, Weinheim City in Germany, 89-94.
  • SINGH B., SHERMAN D.M., GILKES R.J., WELLS M.A. and MOSSELMANS J.F.W., 2002, Incorporation of Cr, Mn and Ni into goethite (a-FeOOH): mechanism from extended X-ray absorption fine structure spectroscopy, Clay Minerals 37, 639–649.
  • STEINTVEIT G., 1971, Treatment of zinc leach plant residue by the jarosite process, In: Advances in Extractive Metallurgy and Refining. IMM, London, pp. 521–528.
  • TORFS K.J., VLIEGEN J., 1996, The Union Miniere Goethite process: plant practice and future prospects, In: Dutrizac, J.E., Harris, G.B. (Eds.), Iron Control and Disposal. The Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, Canada, pp. 135–146.
  • VAZARLIS H. and NEOU-SYNGGOYNA P., 1984, A study of the leaching of Cu and Zn from Greek copper concentrate. Liquid–liquid extraction for the separation of Cu, Zn and Fe from leach solutions, Hydrometallurgy 12, 365–373.
  • WANG K., LI J., MCDONALD R.G., BROWNER R.E., 2011, The effect of iron precipitation upon nickel losses from synthetic atmospheric nickel laterite leach solutions: statistical analysis and modelling, Hydrometallurgy, 109, 140–152.
  • WANG K., LI J., MCDONALD R.G., BROWNER R.E., 2013, Characterisation of iron-rich precipitates from synthetic atmospheric nickel laterite leach solutions, Minerals Engineering 40, 1–11.
  • WAYCHUNAS G.A., REA B.A., FULLER C.C. and DAVIS J.A., 1993, Surface chemistry of ferrihydrite: Part I. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate, Geochim. Cosmochim. Acta, 57,2251-2269.
  • WELCH A.H., WESTJOHN D.B., HELSEL D.R. and WANTY R.B., 2000, Arsenic in ground water of the United States-- occurrence and geochemistry, Ground Water, 38(4), 589-604.
  • ZHOU T., ZHONG X. and ZHENG L., 1989, Recovering In, Ge, Ga from zinc residues, J. Met., 36–40.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1d33ce7c-2c58-44bc-9df5-db16309bd22b
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.