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The pre-concentration of electrode material of spent lithium-ion battery has great significance on the resource utilization and environmental protection. The feasibility of separation of graphite and LiCoO2 based on density difference using the enhanced gravity concentrator was verified in this paper. Combustion characteristics of LiCoO2 and graphite were used to propose a simple evaluation index of separation efficiency. Separation tests were carried out to specify the influence of operating parameters on the separation efficiency. Moreover, the effect of particle size on the separation performance was studied. Combustion characteristics results showed that mass loss of graphite was much greater than that of LiCoO2. Thus, mass loss were used to evaluate the purity of product. Effective separation of graphite and LiCoO2 was achieved by the enhanced centrifugal separator. Separation results showed that increasing centrifugal force decreased the overflow yield and increased the graphite content of the overflow stream. In addition, yield of overflow grew an increase in fluidization water pressure, while the purity of graphite in overflow decreased. The effect of particle size on the separation efficiency was also significant, the separation efficiency decreased with the decreasing of particle size.
Rocznik
Tom
Strony
293--299
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
- Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu, China
- College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
autor
- Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu, China
autor
- Advanced Analysis and Computation Center, China University of Mining and Technology, Xuzhou 221116, China
autor
- Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu, China
autor
- Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu, China
Bibliografia
- BAHGAT, M., FARGHALY, FE., BASIR, SMA., FOUAD, OA., 2007. Synthesis, characterization and magnetic properties of microcrystalline lithium cobalt ferrite from spent lithium-ion batteries. J Mater Process Tech, 183(1), 117-121.
- BATALOVIĆ, V., 2011. Centrifugal separator, the new technical solution, application in mineral processing. Int J Miner Process, 100(3-4), 86-95.
- CHEN, X., FAN, B., XU, L., ZHOU, T., KONG, J., 2016. An atom-economic process for the recovery of high value-added metals from spent lithium-ion batteries. J Clean Prod, 112, 3562-3570.
- CHEN, X., XU, B., ZHOU, T., LIU, D., HU, H., FAN, S., 2015. Separation and recovery of metal values from leaching liquor of mixed-type of spent lithium-ion batteries. Sep Purif Technol, 144, 197-205.
- EL-MIDANY, AA., IBRAHIM, SS., 2011. Does calcite content affect its separation from celestite by Falcon concentrator?. Powder Technol, 213(1-3), 41-47.
- GEORGI-MASCHLER, T., FRIEDRICH, B., WEYHE, R., HEEGN, H., RUTZ, M., 2012. Development of a recycling process for Li-ion batteries. J Power Sources, 207, 173-182.
- GRATZ, E., SA, Q., APELIAN, D., WANG, Y., 2014. A closed loop process for recycling spent lithium ion batteries. J Power Sources, 262, 255-262.
- GRANATA, G., PAGNANELLI, F., MOSCARDINI, E., 2012. Simultaneous recycling of nickel metal hydride, lithium ion and primary lithium batteries: Accomplishment of European Guidelines by optimizing mechanical pre-treatment and solvent extraction operations. J Power Sources, 212, 205-211.
- GREENWOOD, M., LANGLOIS, R., WATERS, KE., 2013. The potential for dry processing using a Knelson Concentrator. Miner Eng., 45, 44-46.
- JOULIÉ, M., LAUCOURNET, R., BILLY, E., 2014. Hydrometallurgical process for the recovery of high value metals from spent lithium nickel cobalt aluminum oxide based lithium-ion batteries. J Power Sources, 247, 551-555.
- LIU, Q., CUI, Z., ETSELL, TH., 2006. Pre-concentration and residual bitumen removal from Athabasca oilsands froth treatment tailings by a Falcon centrifugal concentrator. Int J Miner Process, 78(4), 220-230.
- MESHRAM, P., PANDEY, BD., MANKHAND, TR., 2015. Hydrometallurgical processing of spent lithium ion batteries (LIBs) in the presence of a reducing agent with emphasis on kinetics of leaching. Chem Eng J, 281, 418-427.
- SUN, L., QIU, K., 2011. Vacuum pyrolysis and hydrometallurgical process for the recovery of valuable metals from spent lithium-ion batteries. J Hazard Mater, 194, 378-384.
- TAO Y, LUO Z, ZHAO Y, TAO D., 2006. Experimental Research on Desulfurization of Fine Coal Using an Enhanced Centrifugal Gravity Separator. Journal of China University of Mining and Technology, 16(4), 399-403.
- USLU, T., SAHINOGLU, E., YAVUZ, M., 2012. Desulphurization and deashing of oxidized fine coal by Knelson concentrator. Fuel Process Technol, 101, 94-100.
- WANG, M., ZHANG, C., ZHANG, F., 2016. An environmental benign process for cobalt and lithium recovery from spent lithium-ion batteries by mechanochemical approach. Waste Manage, 51, 239-244.
- XIN, Y., GUO, X., CHEN, S., WANG, J., WU, F., XIN, B., 2016. Bioleaching of valuable metals Li, Co, Ni and Mn from spent electric vehicle Li-ion batteries for the purpose of recovery. J Clean Prod, 116, 249-258.
- ZHANG, T., HE, Y., GE, L., FU, R., ZHANG, X., HUANG, Y., 2013. Characteristics of wet and dry crushing methods in the recycling process of spent lithium-ion batteries. J Power Sources, 240, 766-771.
- ZHANG, T., HE, Y., WANG, F., GE, L., ZHU, X., LI, H., 2014a. Chemical and process mineralogical characterizations of spent lithium-ion batteries: An approach by multi-analytical techniques. Waste Manage, 34(6), 1051-1058.
- ZHANG, T., HE, Y., WANG, F., LI, H., DUAN, C., WU, C., 2014b. Surface analysis of cobalt-enriched crushed products of spent lithium-ion batteries by X-ray photoelectron spectroscopy. Sep Purif Technol, 138, 21-27
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1cb1ab99-cb39-46d0-a847-7fd8523a6dc0