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In this paper, an electro-kinetic technique was applied to remove chromium from contaminated soil. This technique is appropriate for the soils with low permeability. Various experiments were carried out under different operating conditions, including various purging solutions. Garlic peels powder (GPP) was used in this study as a cheap adsorbent substance to avert the flow of reverse osmosis, which may affect the removal percentage. The results proved that the removal percentage increased as the pH of the purging solutions decreased. The first three experiments were performed with purging solution at pH of 4, 6, and 8 respectively. The highest removal percentage was 66.3% at pH of 4 compared to the other two experiments at pH of 6 and 8, where the removal percentages were 53.3% and 49.7%, respectively. This paper showed that the percentage of chromium removal decreased along with the voltage. The removal percentage at 1.5 V/cm was 66.3%, while at 1 V/cm was 61%. Garlic peels powder (GPP) is considered as an effective adsorbent material to avert the reverse osmosis flow. Therefore, the use of this material in this study will give a new impression on the application of these products as an absorbent medium.
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252--259
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- Environment Engineering Department, Al-Mustansiriyah University, Baghdad, Iraq
autor
- Water Resources Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
autor
- Environment Engineering Department, Al-Mustansiriyah University, Baghdad, Iraq
Bibliografia
- 1. Acar, Y.B., and Alshawabkeh, A.N. 1993. Principles of electro kinetic remediation. Environ SciTechnol, 27(13), 2638-2647
- 2. Ali, S.M., Khalid, A.R., & Majid, R.M. 2014. The removal of Zinc, Chromium and Nickel from industrial waste water using Corn cobs. Iraqi Journal of Science, 55(1), 123-131.
- 3. Ayad. A.F, Ibtiha. T.R., 2015. Enhancement Solution to Improve Remediation of Soil Contaminated with Lead by Electrical Field. Journal of Engineering, 21(11).
- 4. Bellu, S. et al. 2008. Removal of chromium (VI) and chromium (III) from aqueous solution by grainless stalk of corn. Sep Sci Technol, 43, 3200–3220.
- 5. Duan, Q. N., Lee, J. C., Liu, Y. S., Chen, H. & Hu, H. Y. 2016. Distribution of Heavy Metal Pollution in Surface Soil Samples in China: A Graphical Review. B Environ Contam Tox, 97, 303–309.
- 6. Ferrucci, A.; Vocciante, M.; Bagatin, R.; Ferro, S. 2017. Electrokinetic remediation of soils contaminated by potentially toxic metals: Dedicated analytical tools for assessing the contamination baseline in a complex scenario. J. Environ. Manag, 203, 1163–1168.
- 7. Gallios, G.P. & Vaclavikova, M. 2008. Removal of chromium (VI) from water streams: a thermodynamic study. Environ Chem Lett, 6, 235–240.
- 8. Gao, Y. & Xia, J. 2011. Chromium Contamination Accident in China: Viewing Environment Policy of China. Environ Sci Technol, 45, 8605–8606.
- 9. Hamed and Bhadra. 1997. Influence of current density and pH on electro-kinetics. Journal of Hazardous Materials, 55(1-3), 279-294.
- 10. Kannan, A. & Thambidurai, S. 2008. Removal Of Hexavalent Chromium From Aqueous Solution Using Activated Carbon Derived From Palmyra Palm Fruit Seed. B Chem Soc Ethiopia, 22, 183–196.
- 11. Laith Hamdan. H. 2017. Elimination of zinc from the contaminated soils by electro-kinetic remediation. Journal of Engineering and Sustainable Development, 21(4).
- 12. Laith Hamdan. H, Lubna. A., Serror.A.A., 2021. Application of Batch and Continuous Systems for Removal of Chromium from Simulated Waste Water by Palm Date Fibers as Biological Byproduct. Journal of Green Engineering, 11(2).
- 13. Muthamilselvi P, Karthikeyan R, Kumar BSM. 2016. Adsorption of phenol onto garlic peel: optimization, kinetics, isotherm, and thermodynamic studies. Desalin Water Treat, 57, 2089–2103.
- 14. Srivastava R.K., Tiwari R.P., Bala Ramudu P. 2007. Electro-Kinetic Remediation Study For Cadmium Contaminated Soil. Department of Civil Engineering, Motilal Nehru National Institute of Technology, Allahabad, India, Iran. J. Environ. Health. Sci. Eng.
- 15. Reddy, K., Cameselle, C. 2009. Electrochemical remediation technologies for polluted soils, sediments and groundwater. John Wiley & Sons, Inc.
- 16. Reddy, K.R., Shirani, A.B. 1997. Electro-kinetic remediation of metal contaminated glacial tills. Geotechnical and Geological Engineering, 15, 3-29.
- 17. Rosestolato, D.; Bagatin, R.; Ferro, S. 2015. Electrokinetic remediation of soils polluted by heavy metals (mercury in particular). Chem. Eng. J., 264, 16–23.
- 18. Sharma, H.D. and Reddy, K.R. 2004. Geo environmental Engineering: Site Remediation, Waste Containment, and Emerging Waste Management Technologies, Wiley
- 19. USEPA. 2007. Microwave assisted acid digestion of sediments, sludge, soils, and oils. 3051. USEPA.
- 20. Villacis-Garcia, M., Villalobos, M. & GutierrezRuiz, M. 2015. Optimizing the use of natural and synthetic magnetites with very small amounts of coarse Fe (0) particles for reduction of aqueous Cr (VI). J Hazard Mater, 281, 77–86.
- 21. Virkutyte J, Sillanpaa M, Latostenmaa P. 2002. Soil Washing: The Science of the Total Environment, 289, 97-121.
- 22. Vocciante, M.; Caretta, A.; Bua, L.; Bagatin, R.; Ferro, S. 2016. Enhancements in Electro Kinetic Remediation Technology: Environmental assessment in comparison with other configurations and consolidated solutions. Chem. Eng. J., 289, 123–134.
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Bibliografia
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